Abstract
A graphene (Gr)/Ti6Al4V composite coating was prepared by laser cladding, and the microstructure and the properties were studied. The results showed that an in situ synthesis between Gr and Ti occurred and TiC was formed. The TiC was homogeneously distributed. The α’ acicular martensite was formed at the bottom of the coating during the rapid solidification process, and a good metallurgical bond was formed between the coating and substrate. The TiC and the self-lubrication of Gr improved the wear resistance of coating. And the wear mechanism changed from more serious abrasive and adhesive wear to a mild wear with fine scratches. Meanwhile, severe oxidative wear occurred in the coating and substrate under high-temperature friction and wear. The corrosion resistance of the coating was also improved. The corrosion morphology changed from denudation and pitting to local pitting. The Gr and TiC in the coating effectively preventeds the corrosion.
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References
Banerjee D and Williams J C, Acta Materialia 61 (2013) 844.
Feng S -r, Tang H -b, Zhang S -q, and Wang H -m, T Nonferr Metal Soc 22 (2012) 1667.
Obadele B A, Lepule M L, Andrews A, and Olubambi P A, Tribol Int 78 (2014) 160.
Shoesmith D W, Noël J J, and Annamalai V E, Corrosion of Titanium and Its Alloys. Shreir’s Corrosion (2010) 2042.
Farayibi P K, Folkes J, Clare A, and Oyelola O, Surf Coat Tech 206 (2011) 372.
Huang C, Du L, and Zhang W, J Alloy Compd 479 (2009) 777.
Staszuk M, Pakuła D, Chladek G, Pawlyta M, Pancielejko M, and Czaja P, Vacuum 154 (2018) 272.
Jiang J, Feng C, Qian W, Zhu L, Han S, and Lin H, Mater Chem Phys 199 (2017) 239.
Zhang L, Zhao Z, Bai P, Du W, Li Y, Yang X, and Wang Q, Mater Lett 270 (2020) 127711.
Wang F, Mei J, Jiang H, and Wu X, Mater Sci Eng A 445-446 (2007) 461.
Yanan L, Ronglu S, Wei N, Tiangang Z and Yiwen L, Opt Laser Eng 120 (2019) 84.
Bai H, Li C, and Shi G Q, Adv Mater 23 (2011) 1089.
Wang, Y X, Chou S L, Wexler D, Liu H K, and Dou S X, Chem-Eur J 20 (2014) 9607.
Zhao Z, Bai P, Du W, Liu B, Pan D, Das R, Liu C, Guo Z, Carbon 170 (2020) 302-326.
Li J -f, Zhang L, Xiao J -k, and Zhou K -c, T Nonferr Metal Soc 25 (2015) 3354.
Vahedi F, Zarei-Hanzaki A, Salandari-Rabori A, Abedi H R, Razaghian A, and Minarik P, J Alloy Compd 815 (2020) 152231.
Zhao Z Y, Zhao W J, Bai P K, Wu L Y, and Huo P C, Mater Lett 255 (2019) 126559.
Zhao Z, Bai P, Misra R D K, Dong M, Guan R, Li Y, Zhang J, Tan L, Gao J, Ding T, Du W, and Guo Z, J Alloy Compd 792 (2019) 203.
Zhang J, Chen Z, Wu H, Zhao J, Jiang Z, Surf Coat Tech 358 (2019) 907-912.
Li J, Zhao Z, Bai P, Qu H, Liang M, Liao H, Wu L. Huo P, Materials 12 (2019) 950.
Sun Y, Moroz A, Alrbaey K, J Mater Eng Perform 23 (2014) 518-526.
Xu H, Xing H, Dong A, Du D, Wang D, Huang H, Zhu G, Shu D, Sun B, She H, Lai H, Chen K, Surf Coat Tech 363 (2019) 161-169.
Bolzàn J A, Jàuregui E A, and Arvia A J, Electrochim Acta 8 (1963) 841.
Cai L X, Wang H M, and Wang C M, Surf Coat Tech 182 (2004) 294.
Wang B -b, Wang Z -y, Han W, Wang C, and Ke W, T Nonferr Metal Soc 23 (2013) 1199.
He X, Song R G, Kong D J, Opt Laser Technol 112 (2019) 339-348.
Acknowledgements
The authors would like to thank the National Natural Science Foundation of China (Grant No. 51775521 and U1810112), the China Postdoctoral Science Foundation (2019M661068), the Key Research and Development Project of Shanxi Province (201903D121009), the Natural Science Foundation of Shanxi Province: 201801D221154, the Major Science and Technology Projects of Shanxi Province, China (No. 20181101009, 20181102012), Shanxi Foundation Research Projects for Application (201801D221234), Research Project Supported by Shanxi Scholarship Council of China (2019072).
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Zhang, L., Zhao, Z., Bai, P. et al. Microstructure and Properties of In situ Synthesized TiC/Graphene/Ti6Al4V Composite Coating by Laser Cladding. Trans Indian Inst Met 74, 891–899 (2021). https://doi.org/10.1007/s12666-020-02149-7
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DOI: https://doi.org/10.1007/s12666-020-02149-7