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Unexpected Products of the Reaction of Lappaconitine-Based Nitrone with N,N-Diethylallylamine

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Abstract

The reaction of [3 + 2] cycloaddition of a lappaconitine-based nitrone with N,N-diethylallylamine is accompanied by the formation of two minor products, unusual for the reaction of this type, containing the pyrrole cycle. The structures of the products have been established from the data of 1H and 13C NMR spectra. The mechanism of their formation is proposed.

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ACKNOWLEDGMENTS

This work was performed using equipment of the “Khimiya” Shared Facility Center, Institute of Chemistry, Ufa Federal Research Center, RAS, and the “Agidel’” Regional Shared Facility Center, Ufa Federal Research Center, RAS.

Funding

This work was performed under the State assignment no. АААА–А20–120012090026–9.

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Authors and Affiliations

  1. Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences, 450054, Ufa, Russia

    T. M. Gabbasov, E. M. Tsyrlina &  M. S. Yunusov

Authors
  1. T. M. Gabbasov
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  2. E. M. Tsyrlina
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  3. M. S. Yunusov
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Corresponding author

Correspondence to E. M. Tsyrlina.

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Translated by I. Kudryavtsev

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Gabbasov, T.M., Tsyrlina, E.M. & Yunusov, M.S. Unexpected Products of the Reaction of Lappaconitine-Based Nitrone with N,N-Diethylallylamine. Dokl Chem 495, 175–177 (2020). https://doi.org/10.1134/S0012500820110038

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  • DOI: https://doi.org/10.1134/S0012500820110038

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