An investigation of physical properties and photovoltaic performance of methylammonium lead-tin iodide (CH₃NH₃Sn₁-xPbxI₃) solar cells

In the past several years, CH₃NH₃PbI₃ perovskite material has been extensively evaluated as an absorber layer of perovskite solar cells due to its excellent structural and optical properties, and greater than 22% conversion efficiency. However, improvement and future commercialization of solar cells based on CH₃NH₃PbI₃ encountered restrictions due to toxicity and instability of the lead element. Recently, studies on properties of lead-free and mixture of lead with other cations perovskite thin films as light absorber materials have been reported. The purpose of this paper was the fabrication of CH₃NH₃Sn₁-xPbxI₃ thin films with different SnI₂ concentrations in ambient condition, and study on the structural, morphological, optical, and photovoltaic performance of the studied solar cells. The X-ray diffraction studies revealed the formation of both CH₃NH₃PbI₃ and CH₃NH₃SnI₃ phases with increasing the Sn concentration, and improvement in crystallinity and morphology was also observed. All perovskite layers had a relatively high absorption coefficient >104 cm⁻¹ in the visible wavelengths, and the bandgap values varied in the range from 1.46 to 1.63 eV. Perovskite solar cells based on these thin films have been fabricated, and device performance was investigated. Results showed that photo-conversion efficiency (PCE) for the pure CH₃NH₃PbI₃sample was 1.20%. With adding SnI₂, PCE was increased to 4.48%.

In this work, the author mixed tin and lead with different percentages in the perovskite thin film. Also, the preparation of these layers and also other layers to fabricate solar cells based on them were conducted in an open and non-glove box environment. Finally, the effect of [Sn/Pb] ratio in the CH₃NH₃Sn₁-xPbxI₃ layers on the structural, morphological, optical, electrical and photovoltaic performance have been investigated.

CH₃NH₃Sn₁-xPbxI₃ (x = 0.0, 0.25, 0.50, 0.75, 1.0) perovskite thin films have been grown by a spin-coating technique. It was found that as tin concentration increases, the X-ray diffraction and FESEM images studies revealed the formation of both CH₃NH₃PbI₃ and CH₃NH₃SnI₃ phases, and improvement in crystallinity, and morphology; all thin films had high absorption coefficient values close to 104 cm⁻¹ in the visible region, and the direct optical bandgap in the layers decreases from 1.63 eV in pure CH₃NH₃SnI₃ to 1.46 eV for CH₃NH₃Sn0.0.25Pb0.75I3 samples; all thin films had p-type conductivity, and mobility and carrier density increased; perovskite solar cells based on these thin films have been fabricated, and device performance was investigated. Results showed that photo-conversion efficiency (PCE) for the pure CH₃NH₃PbI₃sample was 1.20%. With adding SnI2, PCE was increased to 4.48%.

The preparation method seems to be interesting as it is in an ambient environment without the protection of nitrogen or argon gas.