Skip to main content
SpringerLink
Log in

Application of polyethylenimine multi-coated adsorbent for Pd(II) recovery from acidic aqueous solution: batch and fixed-bed column studies

  • Environmental Engineering
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

PEI imilti-coated PSBF (PEI-M-PSBF) wth high adsorption efficiency and good reusability for Pd(II) recovery was prepared by a PEI multi-coating method. The results of FT-IR and FE-SEM showed that the PEI-M-PSBF was successfully prepared. Batch experiments were conducted to study the adsorption/desorption performance of PEI-M-PSBF to Pd(II). The Langmuir and pseudo-second-order models were well suited for the batch experiment isotherm and kinetic data, respectively. The adsorption capacity of Pd(II) by Langmuir model was 327.14 mg/g, and the initial adsorption rate of 3-PEI-PSBF was 37.19mg/g min. As a resut, the increase in amine groups on the PEI-M-PSBF surface through the PEI multi-coating directly influenced the adsorption amount of the biosorbent. The effects of initial concentration, bed column depth, and flow rate were determined in a column system and the breakthrough curves were detected by Thomas model. In addition, the recycle of the adsorbent was examined by multiple time performing adsorption/desorption cycles up to ten times in a fixed-bed column.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C. Ruan, M. Strømme and J. Lindh, Cellulose, 23, 2627 (2016).

    Article  CAS  Google Scholar 

  2. M. H. Morcali and B. Zeytuncu, Int. J. Miner. Process., 137, 52 (2015).

    Article  CAS  Google Scholar 

  3. M. Yamada, M. R. Gandhi and A. Shibayama, Sci. Rep., 8, 1 (2018).

    Article  Google Scholar 

  4. A. Ramesh, H. Hasegawa, W. Sugimoto, T. Maki and K. Ueda, Bioresour. Technol., 99, 3801 (2008).

    Article  CAS  Google Scholar 

  5. M. Fomina and G. M. Gadd, Bioresour. Technol., 160, 3 (2014).

    Article  CAS  Google Scholar 

  6. J. Mao, S. W. Won, K. Viiayaraghavan and Y. S. Yun, Bioresour. Technol., 100, 1463 (2009).

    Article  CAS  Google Scholar 

  7. Y. S. Yun, D. Park, J. M. Park and B. Volesky, Environ. Sci. Technol., 35, 4353 (2001).

    Article  CAS  Google Scholar 

  8. K. Vijayaraghavan and Y. S. Yun, Biotechnol. Adv., 26, 266 (2008).

    Article  CAS  Google Scholar 

  9. C. W. Cho, S. B. Kang, S. Kim, Y. S. Yun and S. W. Won, Chem. Eng. J., 302, 545 (2016).

    Article  CAS  Google Scholar 

  10. F. Beolchini, F. Pagnanelli, L. Toro and F. Vegliò, Hydrometallurgy, 70, 101 (2003).

    Article  CAS  Google Scholar 

  11. C. Sun, G. Song, L. Chen, X. Ren and C. Chen, J. Colloid Interface Sci., 580, 550 (2020).

    Article  CAS  Google Scholar 

  12. F. Zhao, Z. Yang, Z. Wei, R. Spinney, M. Sillanpää, J. Tang, M. Tam and R. Xiao, Chem. Eng. J., 388, 124307 (2020).

    Article  CAS  Google Scholar 

  13. J. Kwame, S. Lin, A. Kumar, Y. Zhao, J. W. Choi, M. H. Song, W. Wei, D. H. Kumar, C. W. Cho and Y. S. Yun, J. Clean. Prod., 252, 119389 (2020).

    Article  Google Scholar 

  14. H. A. Choi, H. N. Park and S. W. Won, J. Environ. Manage., 204, 200 (2017).

    Article  CAS  Google Scholar 

  15. F. Zhao, E. Repo, Y. Song, D. Yin, S. B. Hammouda, L. Chen, S. Kalliola, J. Tang, K. C. Tam and M. Sillanpää, Green Chem., 19, 4816 (2017).

    Article  CAS  Google Scholar 

  16. S. Bo, J. Luo, Q. An, Z. Xiao, H. Wang, W. Cai, S. Zhai and Z. Li, J. Clean. Prod., 250, 119585 (2020).

    Article  CAS  Google Scholar 

  17. A. Shahbazi, H. Younesi and A. Badiei, Chem. Eng. J., 168, 505 (2011).

    Article  CAS  Google Scholar 

  18. S. Kim, Y. E. Choi and Y. S. Yun, J. Hazard. Mater., 313, 29 (2016).

    Article  CAS  Google Scholar 

  19. S. W. Won, J. Park, J. Mao and Y. S. Yun, Bioresour. Technol., 102, 3888 (2011).

    Article  CAS  Google Scholar 

  20. S. W. Won, S. Kim, P. Kotte, A. Lim and Y. S. Yun, J. Hazard. Mater., 263, 391 (2013).

    Article  CAS  Google Scholar 

  21. K. Fytianos, E. Voudrias and E. Kokkalis, Chemosphere, 40, 3 (2000).

    Article  CAS  Google Scholar 

  22. M. R. Gandhi, M. Yamada, Y. Kondo, A. Shibayama and F. Hamada, J. Ind. Eng. Chem., 30, 20 (2015).

    Article  Google Scholar 

  23. T. Vincent, A. Parodi and E. Guibal, React. Funct. Polym., 68, 1159 (2018).

    Article  Google Scholar 

  24. S. Sharma and N. Rajesh, J. Environ. Chem. Eng., 5, 1927 (2017).

    Article  CAS  Google Scholar 

  25. S. Sharma, M. Barathi and N. Rajesh, Chem. Eng. J., 259, 457 (2015).

    Article  CAS  Google Scholar 

  26. S. Örgül and Ü. Atalay, Hydrometallurgy, 67, 71 (2002).

    Article  Google Scholar 

  27. Z. Hubicki, M. Wawrzkiewicz and A. Wołowicz, Chem. Analityczna, 53, 759 (2008).

    CAS  Google Scholar 

Download references

Acknowledgements

This work; supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (2020R1F1A1065937).

Author information

Authors and Affiliations

  1. Department of Ocean System Engineering, Gyeongsang National University, 2 Tongyeonghaean-ro, Tongyeong, Gyeongnam, 53064, Korea

    Su Bin Kang, Zhuo Wang & Sung Wook Won

  2. Department of Marine Environmental Engineering, Gyeongsang National University, 2 Tongyeonghaean-ro, Tongyeong, Gyeongnam, 53064, Korea

    Sung Wook Won

Authors
  1. Su Bin Kang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zhuo Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Sung Wook Won
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Sung Wook Won.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kang, S.B., Wang, Z. & Won, S.W. Application of polyethylenimine multi-coated adsorbent for Pd(II) recovery from acidic aqueous solution: batch and fixed-bed column studies. Korean J. Chem. Eng. 38, 523–530 (2021). https://doi.org/10.1007/s11814-020-0716-x

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-020-0716-x

Keywords

Search

Navigation