Abstract
Composite materials that contain tetracationic hydrotalcite-like layered double hydroxide and a cobalt-iron spinel phase were prepared by coprecipitation from a solution of a mixture of magnesium, aluminum, cobalt(II), and iron(III) salts followed by hydrothermal treatment. The iron and cobalt contents in the samples were varied within a broad range. The thermal transformations of the prepared composites were examined by high-temperature X-ray diffraction, and the layered hydroxide phase was found to remain when heated up to 300°C. The specific magnetization and magnetic susceptibility of the materials were determined using a vibrating sample magnetometer; a rise in the iron and cobalt contents was found to increase the magnetization up to a certain limit. The obtained samples can be used as magnetic sorbents. The sorption capacity of materials was estimated using Congo red anionic dye as an example.
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REFERENCES
Cavani, F., Trifirò, F., and Vaccari, A., Catal. Today, 1991, vol. 11, p. 173. https://doi.org/10.1016/0920-5861(91)80068-K
Tretyakov, Yu.D., Lukashin, A.V., and Eliseev, A.A., Russ. Chem. Rev., 2004, vol. 73, no. 9, p. 899. https://doi.org/10.1070/RC2004v073n09ABEH000918
Kuljiraseth, J., Wangriya, A., Malones, J.M.C., Klysubun, W., and Jitkarnka, S., Appl. Catal. B: Environmental, 2019, vol. 243, p. 415. https://doi.org/10.1016/j.apcatb.2018.10.073
Kankan, B., Sanchai, K., Jiang, D., Hongrui, L., Tingting, Y., Guorong, C., and Liyi, S., Appl. Catal. B: Environmental, 2019, vol. 252, p. 86. https://doi.org/10.1016/j.apcatb.2019.04.007
Krylova, M.V., Kulikov, A.B., Knyazev, M.I., and Krylova, A.Yu., Chem. Technol. Fuels and Oils, 2008, vol. 44, p. 339. https://doi.org/10.1007/s10553-008-0064-8
Li, Q., Xing, L., Lu, X., Li, N., and Mingxiang, X., Inorg. Chem. Commun., 2015, vol. 52, p. 46. https://doi.org/10.1016/j.inoche.2014.12.014
Fan, G., Li, F., Evans, D.G., and Duan, X., Chem. Soc. Rev., 2014, no. 43, p. 7040. https://doi.org/10.1039/C4CS00160E
Rives, V., del Arco, M., and Martín, C., J. Control. Release, 2013, no. 169, p. 28. https://doi.org/10.1016/j.jconrel.2013.03.034
Lei, C., Zhu, X., Zhu, B., Jiang, C., Le, Y., and Yu, J., J. Hazardous Mater., 2017, vol. 321, p. 801. https://doi.org/10.1016/j.jhazmat.2016.09.070
Goh, K.-H., Lim, T.-T., and Dong, Z., Water Res., 2008, vol. 42, p. 1343. https://doi.org/10.1016/j.watres.2007.10.043
Chuang, Y.H., Tzou, Y.M., Wang, M.K., Liu, C.H., and Chiang, P.N., Ind. Eng. Chem. Res., 2008, vol. 47, p. 3813. https://doi.org/10.1021/ie071508e
Kameda, T., Tsuchiya, Y., Yamazaki, T., and Yoshioka, T., Solid State Sci., 2009, vol. 11, p. 2060. https://doi.org/10.1016/j.solidstatesciences.2009.09.008
Chaara, D., Pavlovic, I., Bruna, F., Ulibarri, M.A., Draoui, K., and Barriga, C., Appl. Clay Sci., 2010, vol. 50, p. 292. https://doi.org/10.1016/j.clay.2010.08.002
Ivanets, A.I., Srivastava, V., Roshchina, M.Yu., Sillanpää, M., Prozorovich, V.G.,and Pankov, V.V., Ceramics Int., vol. 44, no. 8, p. 9097. https://doi.org/10.1016/j.ceramint.2018.02.117
Li, W., Zhang, J., Zhu, W., Qin, P., Zhou, Q., Lu, M., Zhao, W., Zhang, S., and Cai, Z., Talanta, 2020, vol. 208, p. 120440. https://doi.org/10.1016/j.talanta.2019.120440
Ryl’tsova, I., Tarasenko, E., Nestroinaya, O., and Lebedeva, O., Sorbts. Khromatograf. Protses., 2019, vol. 19, no. 3, p. 305. https://doi.org/10.17308/sorpchrom.2019.19/747
Nestroinia, O.V., Ryl’tsova, I.G., Yapryntsev, M.N., and Lebedeva, O.E., Inorg. Mater., 2020, vol. 56, no. 7, p. 747. https://doi.org/10.1134/S0020168520070109
Kanezaki, E., Solid State Ionics, 1998, vol. 106, nos. 3–4, p. 279. https://doi.org/10.1016/S0167-2738(97)00494-3
Radha, A.V., Thomas, G.S., Kamath, P.V., Antonyraj, C.A., and Kannan, S., Bull. Mater. Sci., 2010, vol. 33, no. 3, p. 319. https://doi.org/10.1007/s12034-010-0049-1
Vaysse, C., Guerlou-Demourgues, L., and Delmas, C., Inorg. Chem., 2002, vol. 41, no. 25, p. 6905. https://doi.org/10.1021/ic025542r
Ortiz-Quiñonez, J.-L., Pal, U., and Villanueva, M., ACS Omega, 2018, vol. 3, no. 11, p. 14986. https://doi.org/10.1021/acsomega.8b02229
Frolov, G.I., Bachina, O.I., Zav’yalova, M.M., and Ravochkin, S.I., Tech. Phys., 2008, vol. 53, p. 1059. https://doi.org/10.1134/S1063784208080136
Ho, Y.S. and McKay, G., Process Biochem., 1999, vol. 34, p. 451. https://doi.org/10.1016/S0032-9592(98)00112-5
Giles, C.H., MacEwan, T.H., Nakhwa, S.N., and Smith, D., J. Chem. Soc., 1960, p. 3973. https://doi.org/10.1039/JR9600003973
Funding
The study described here was financially supported by a grant from the Russian Foundation for Basic Research (project no. 18-29-310011 mk). The study was carried out using scientific equipment of “Technologies and Materials” Center for Collective Use at the Belgorod State National Research University.
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Translated from Sovremennye Molekulyarnye Sita. Advanced Molecular Sieves, 2021, Vol. 3, No. 1, pp. 143–148.
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Nestroinaya, O.V., Ryl’tsova, I.G., Tarasenko, E.A. et al. Magnetic Materials Based on Layered Double Hydroxides. Pet. Chem. 61, 388–393 (2021). https://doi.org/10.1134/S096554412103004X
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DOI: https://doi.org/10.1134/S096554412103004X