Abstract
Chrome spinels in carbonate veins of the Onguren Complex, East Siberia, Western Baikal region are predominantly ferrichromite and chrommagnetite (MgO ≤ 0.3 wt %, Mg# ≤ 0.04, Al2O3 ≤ 2.5 wt %; Cr# 0.91–1.00, Fe2+/Fe3+ 0.8–1.4) with a high ZnO content (0.9–4.6 wt %). In the calcite vein, titanian chrome-magnetite is transformed into Cr-bearing titanomagnetite, which decomposes into Ti-depleted magnetite and ilmenite at temperature of 970–1000°С and \({{f}_{{{{{\text{O}}}_{{\text{2}}}}}}}\) approximately of +0.5…+0.7 QFM. In the dolomite vein, ferrichromite and chrome-magnetite grains contain relict cores of subferrialumochromite (Al2O3 10.6–14.4 wt %, Cr# 0.63–0.73, Fe2+/Fe3+ 4.1–5.2, MgO ≤ 0.52 wt %) with elevated ZnO (3.7–5.1 wt %), TiO2 (3.2–4.1 wt %), and MnO (0.6–1.1 wt %). Ferrichromite and chrome-magnetite are formed during the high-temperature (>600°C) metamorphism of the vein. Superimposed deformations under greenschist facies conditions lead to the formation of magnetite rims around chrome-magnetite grains.
Similar content being viewed by others
REFERENCES
Arai, S. and Ishimaru, S., Zincian chromite inclusions in diamonds: possibility of deep recycling origin, J. Mineral. Petrol. Sci., 2011, vol. 106, pp. 85–90.
Arai, S., Okamura, H., Kadoshima, K., Tanaka, C., Suzuki, K., and Ishimary, S., Chemical characteristics of chromian spinel in plutonic rocks: implications for deep magma processes and discrimination of tectonic setting, Island Arc, 2011, vol. 20, pp. 125–137.
Arima, M. and Edgar, A.D., Substitution mechanisms and solubility of titanium in phlogopites from rocks of probable mantle origin, Contrib. Mineral. Petrol., 1981, vol. 77, pp. 288–295.
Barnes, S.J. and Roeder, P.L., The range of spinel compositions in terrestrial mafic and ultramafic rocks, J. Petrol., 2001, vol. 42, no. 12, pp. 2279–2302.
Buddington, A.F. and Lindsley, D.H., Iron-titanium oxide minerals and synthetic equivalents. J. Petrol., 1964, vol. 5, no. 2, pp. 310–357.
Chakhmouradian, A.R., Bohm, C.O., Demeny, A., Reguir, E.P., Hegner, E., Creaser, R.A., Halden, N.M., and Yang, P., “Kimberlite” from Wekusko Lake, Manitoba: Actually a diamond-indicator-bearing dolomite carbonatite, Lithos, 2009, vol. 112S, pp. 347–357.
Donskaya, T.V., Bibikova, E.V., Mazukabzov, A.M., Kozakov, I.K., Gladkochub, D.P., Kirnozova, T.I., Plotkina, Yu.V., and Reznitsky, L.Z., Primorsky complex of granitoids of the Western Baikal Region: geochronology, geodynamic typification, Russ. Geol. Geophys., 2003, vol. 44, no. 10, pp. 1006–1016.
Doroshkevich, A.G., Wall, F., and Ripp, G.S., Calcite-bearing dolomite carbonatite dykes from Veseloe, North Transbaikalia, Russia and possible Cr-rich mantle xenoliths. Mineral. Petrol, 2007, vol. 90, pp. 19–49.
Droop, G.T.R., A general equation for estimating Fe3+ concentrations in ferromagnesian silicates and oxides from microprobe analyses, using stoichiometric criteria, Mineral. Mag., 1987, vol. 51, no. 3, pp. 431–435.
Epstein, E.M., Geologo-petrologicheskaya model i geneicheskie osobennosti rudonosnykh karbonatitovykh kompleksov (Geological and Petrological Model and Genetic Features of Ore-Bearing Carbonatite Complexes), Moscow: Nedra, 1994.
Fanlo, I., Gervilla, F., Colas, V., and Subias, I., Zn-, Mn- and Co-rich chromian spinels from the Bou-Azzer mining district (Morocco): constraints on their relationship with the mineralizing process, Ore Geol. Rev., 2015, vol. 71, pp. 82–98.
Gaspar, J.C. and Wyllie, P.J., Magnetite in the carbonatites from the Jacupiranga Complex, Brazil, Am. Mineral., 1983, vol. 68, pp. 195–213.
Ghiorso, M.S. and Sack, R.O., Fe–Ti oxide geothermometry: thermodynamic formulation and the estimation of intensive variables in silicic magmas, Contrib. Mineral. Petrol., 1991, vol. 108, pp. 485–510.
Gladkochub, D.P., Donskaya, T.V., Ernst, R., Mazukabzov, A.M., Sklyarov, E.V., Pisarevsky, S.A., Wingate, M., and Soderlund, U., Proterozoic basic magmatism of the Siberian Craton: main stages and their geodynamic interpretation, Geotectonics, 2012, vol. 46, no. 4, pp. 273–284.
Henry, D.J., Guidotti, C.V., and Thomson, J.A., The Ti-saturation surface for low-to-medium pressure metapelitic biotites: Implications for geothermometry and Ti-substitution mechanisms. Am. Mineral., 2005, vol. 90, pp. 316–328.
Johan, Z. and Ohnenstetter, D., Zincochromite from the Guaniamo river diamondiferous placers, Venezuela: evidence of its metasomatic origin, Can. Mineral., 2010, vol. 48, pp. 501–514.
Kamenetsky, V.S., Crawford, A.J., and Meffre, S., Factors controlling chemistry of magmatic spinel: an empirical study of associated olivine, Cr-spinel and melt inclusions from primitive rocks, J. Petrol., 2001, vol. 42, no. 4, pp. 655–671.
Kapustin, Yu.L., Mineralogiya karbonatitov (Mineralogy of Carbonatites), Leningrad: Nauka, 1971.
Kukharenko, A.A., Orlova, M.P., Bulakh, A.G., Bagdasarov, E.A., Rimskaya-Korsakova, O.M., Nefedov, E.I., Ilinsky, G.A., Sergeev, A.S., and Abakumova, N.B., Kaledonskii kompleks ul’traosnovnykh, shchelochnykh porod i karbonatitov Kol’skogo poluostrova i Severnoi Karelii (geoogiya, petrologiya, mineralogiya i geokhimoiya) (The Caledonian Complex of Ultrabasic, Alkaline Rocks and Carbonatites of Kola Peninsula and North Karelia (Geology, Petrology, Mineralogy, and Geochemistry), Moscow: Nedra, 1965.
Lee, M.J., Lee, J.I., and Moutte, J., Compositional variation of Fe–Ti oxides from the Sokli complex, northeastern Finland, Geosci. J., 2005, vol. 9, no. 1, pp. 1–13.
Meyer, H.O.A. and Boyd, F.R., Composition and origin of crystalline inclusions in natural diamonds, Geochim. Cosmochim. Acta, 1972, vol. 36, pp. 1255–1273.
Nasir, S., Al-Khirbash, S., Rollinson, H., Al-Harthy, A., Al-Sayigh, A., Al-Lazki, A., Theye, T., Massonne, H.-J., and Belousova, E., Petrogenesis of early cretaceous carbonatite and ultramafic lamprophyres in a diatreme in the Batain Nappes, Eastern Oman continental margin. Contrib. Mineral. Petrol., 2011, vol. 161, pp. 47–74.
Pavlov, N.V., The chemical composition of chrome-spinel in connection with the petrographic composition of rocks in ultrabasic intrusions, Tr. Inst. Geol., Ser. Rud. Mestorozhd., 1949, vol. 103, no. 3, pp. 3–88.
Pozharitskaya, L.K. and Samoilov, V.S., Petrologiya, mineralogiya i geokhimiya karbonatitov Vostochnoi Sibiri (Petrology, Mineralogy, and Geochemistry of Carbonatites of Eastern Siberia) Moscow: Nauka, 1972.
Ripp, G.S., Doroshkevich, A.G., Badmatsyrenov, M.V., and Karmanov, N.S., Mantle (?) xenoliths in the carbonatites of Northern Transbaikalia, Geochem. Int., 2007, vol. 45, no. 6, pp. 538–545.
Savelyeva, V.B., Bazarova, E.P., and Danilov, B.S., New finds of carbonatite-like rocks in the Western Baikal Region, Dokl. Earth Sci., 2014, vol. 459, no. 2, pp. 1483–1487.
Savelyeva, V.B., Demonterova, E.I., Danilova, Yu.V., Bazarova, E.P., Ivanov, A.V., and Kamenetsky, V.S., New carbonatite complex in the Western Baikal Region, Southern Siberian Craton: Mineralogy, Age, Geochemistry, and Petrogenesis, Petrology, 2016, vol. 24, no. 3, pp. 271–302.
Silaev, V.I., Shabalin, V.N., Golubeva, I.I., Khazov, A.F., and Belousova, E.A., About zinc-containing and zinc-rich chromospinelides of the Timan–Ural region. Herald IG Komi Sci. Center UB, 2008, no. 8, pp. 6–16.
Smith, C.B., Haggerty, S.E., Chatterjee, B., Beard, A., and Townend, R., Kimberlite, lamproite, ultramafic lamprophyre, and carbonatite relationships on the Dharwar Craton, India; an example from the Khaderpet pipe, a diamondiferous ultramafic with associated carbonatite intrusion, Lithos, 2013, vol. 182–183, pp. 102–113.
Stoppa, F. and Woolley, A.R., The Italian carbonatites: field occurrence, petrology and regional significance, Mineral. Petrol., 1997, vol. 59, pp. 43–67.
Evolyutsiya yuzhnoi chasti Sibirskogo kratona v dokembrii (The Evolution of the Southern part of the Siberian Craton in Precambrian), Sklyarov, E. V., Eds., Novosibirsk: Sibirsk. Otd. RAS, 2006.
Carbonatites, Tuttle, J. and Gittins, J., Eds., New York: Interscience Publishers, 1966.
Ustinov, V.I. and Rybakov, V.G., On the Lower Proterozoic stratigraphy of the central part of Western Baikal area, In: Stratigrafiya dokembriya regiona Srednei Sibiri (Precambrian Stratigraphy of the Central Siberian Region), Leningrad: Nauka, 1983, pp. 60–65 (in Russian).
Wooley, A.R. and Church, A.A., Extrusive carbonatites: A brief review, Lithos, 2005, vol. 85, pp. 1–14.
Woolley, A.R. and Kempe, D.R.C., Carbonatites: nomenclature, average chemical compositions, and element distribution, In: Carbonatites: Genesis and Evolution, Bell, K., Eds., London: Unwin Hyman, 1989, pp. 1–14.
ACKNOWLEDGMENTS
We are grateful to the anonymous reviewer, whose critical comments substantially improved the manuscript.
Funding
This study has been supported by the Russian Foundation for Basic Researches (project no. 17-05-00819) and Russian Science Foundation (project no. 18-17-00101).
Author information
Authors and Affiliations
Corresponding authors
Additional information
Translated by I. Baksheev
Rights and permissions
About this article
Cite this article
Savelyeva, V.B., Bazarova, E.P. & Khromova, E.A. Chrome Spinels in Carbonate Veins of the Onguren Complex, Western Baikal Region. Geol. Ore Deposits 62, 652–668 (2020). https://doi.org/10.1134/S1075701520070107
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1075701520070107