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CdSnO3/SnD NPs as a Nanocatalyst for Carbonylation of o-Phenylenediamine with CO2

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Abstract

In order to carbonize o-phenylenediamine with CO2, an effective approach was used with UV light irradiation by Sn(IV) doping DFNS (SnD) supported CdSnO3 as a catalyst (CdSnO3/SnD). In this catalyst, SnD with the ratios of Si/Sn in the range of 6 to 50 were obtained using the Direct Hydrothermal Synthesis (DHS), and the nanoparticles of CdSnO3 on the surfaces of SnD were reduced in situ. Scanning Electron Microscope (SEM), X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), X-ray Energy Dispersive Spectroscopy (EDS), and Transmission Electron Microscopy (TEM) were utilized for characterizing CdSnO3/SnD. It was found that CdSnO3/SnD nanostructures could be used for synthesizing o-phenylenediamines due to their effective and novel catalytic behavior through the reaction between o-phenylenediamines and CO2.

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Authors and Affiliations

  1. School of Electronic Engineering, Xi’an Shiyou University, Xi’an, 710065, China

    Can Liu

  2. Department of Chemistry, Faculty of Sciences, Neyshabur Branch, Islamic Azad University, Neyshabur, Iran

    Seyed Mohsen Sadeghzadeh

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  1. Can Liu
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  2. Seyed Mohsen Sadeghzadeh
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Correspondence to Can Liu or Seyed Mohsen Sadeghzadeh.

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Liu, C., Sadeghzadeh, S.M. CdSnO3/SnD NPs as a Nanocatalyst for Carbonylation of o-Phenylenediamine with CO2. Catal Lett 151, 2807–2815 (2021). https://doi.org/10.1007/s10562-020-03528-x

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  • DOI: https://doi.org/10.1007/s10562-020-03528-x

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