Issue 14, 2021
From the journal:

Chemical Communications

Solvophobic interaction promoted supramolecular helical assembly of building blocks of weak intermolecular halogen bonding†

Xiaosheng Yan, ORCID logo ‡a   Jinlian Cao,‡a   Yanhan Zhang,a   Peimin Weng,a   Daiyu Miao,a   Zhixing Zhao,a   Zhao Lia  and  Yun-Bao Jiang ORCID logo *a  

* Corresponding authors

a Department of Chemistry, College of Chemistry and Chemical Engineering, The MOE Key Laboratory of Spectrochemical Analysis and Instrumentation, and iChEM, Xiamen University, Xiamen 361005, China
E-mail: ybjiang@xmu.edu.cn

Abstract

We report supramolecular helical assembly in water of β-turn structured bis(N-amidothioureas) containing Br-substitutes of moderate halogen bonding ability, promoted by stronger hydrophobic interaction. The helical polymers show an unusual negative nonlinear CD-ee dependence.

Graphical abstract: Solvophobic interaction promoted supramolecular helical assembly of building blocks of weak intermolecular halogen bonding

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D0CC08041A
Article type
Communication
Submitted
11 Dec 2020
Accepted
13 Jan 2021
First published
13 Jan 2021

Chem. Commun., 2021,57, 1802-1805

Permissions

Request permissions

Solvophobic interaction promoted supramolecular helical assembly of building blocks of weak intermolecular halogen bonding

X. Yan, J. Cao, Y. Zhang, P. Weng, D. Miao, Z. Zhao, Z. Li and Y. Jiang, Chem. Commun., 2021, 57, 1802 DOI: 10.1039/D0CC08041A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements