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Preparation of Core/Shell CaO@SiO2-SO3H as a Novel and Recyclable Nanocatalyst for One-Pot Synthesize of Dihydropyrano[2,3-c]Pyrazoles and Tetrahydrobenzo[b]Pyrans

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Abstract

The core/shell CaO@SiO2-SO3H nanoparticles were prepared by stabilizing of sulfonic acid on the surface of silica-coated CaO nanoparticles. The structure of CaO@SiO2-SO3H was characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), wavelength-dispersive X-ray spectroscopy (WDX) and thermal gravimetric analysis (TGA). CaO@SiO2-SO3H was used as a new acidic catalyst for green synthesis of dihydropyrano[2,3-c]pyrazoles and tetrahydrobenzo[b]pyrans via one-pot three-component reactions with good to excellent yields. This catalyst could be recycled and reused for six runs without significant loose of activity.

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Funding

We gratefully acknowledge the financial support of this work by the research council of Arak University.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Arak Univercity, Arak, 38156-88138, Iran

    Fatemeh Sameri, Akbar Mobinikhaledi & Mohammad Ali Bodaghifard

  2. Institute of Nanosciences and Nanotechnology, Arak University, Arak, 38156-88138, Iran

    Fatemeh Sameri, Akbar Mobinikhaledi & Mohammad Ali Bodaghifard

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  1. Fatemeh Sameri
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  2. Akbar Mobinikhaledi
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  3. Mohammad Ali Bodaghifard
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Contributions

F. Sameri and M.A. Bodaghifard conceived and planned the experiments and also they contributed to the interpretation of the results. F. Sameri carried out the experiments and products synthesis and also provided the primary draft of the manuscript. A. mobinikhaledi supervised the project and revised the final version of the manuscript. All authors approved the final version of the manuscript to be published.

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Correspondence to Akbar Mobinikhaledi.

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Sameri, F., Mobinikhaledi, A. & Bodaghifard, M.A. Preparation of Core/Shell CaO@SiO2-SO3H as a Novel and Recyclable Nanocatalyst for One-Pot Synthesize of Dihydropyrano[2,3-c]Pyrazoles and Tetrahydrobenzo[b]Pyrans. Silicon 14, 1395–1406 (2022). https://doi.org/10.1007/s12633-021-00942-7

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