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Qualitative and energy recovery potential analysis: plastic-derived fuel oil versus conventional diesel oil

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Abstract

Due to depleting fossil fuel sources, plastic-derived fuel oil (PDFO) has received much attention over the past decade as an alternative to conventional diesel oil. Although several researchers have reported the properties of PDFO and recommended its usage in diesel engines, no study has thoroughly compared it with conventional diesel oil. This study aims at comparing PDFO produced from pyrolysis of waste plastic (LDPE, HDPE, PS, and PP) with conventional diesel oil based on a number of quality parameters and energy recovery potential. The quality parameters of color and appearance, water content, density, viscosity, volatility, copper strip corrosion, flash point, pour point, and energy content, as well as the cetane index of the fuels, were assessed following ASTM standards. The obtained results indicated no significant difference between the water contents and densities of the fuel oils. Pensky–Martens Closed Cup (PMCC) flash point for PDFO was significantly lower than that of conventional diesel oil. Although the pour points and viscosities of PDFO were significantly different from conventional diesel oil, the values were within the recommended range. All the PDFO types had higher volatilities than conventional diesel oil in the lighter section of the distillation curve, whereas no significant difference was detected in the heavier section. On the ASTM corrosion chart, conventional diesel oil belongs to class 1a, whereas all the PDFO types belong to class 2a. Energy recovery calculations revealed that PDFO has the potential to produce energy equivalent to 203,000 barrels of oil. It can be concluded that although PDFO has undesirable high volatility in the lighter section of the distillation curve and relatively low flash point, it compares relatively well with conventional diesel oil and thus is a potential substitute.

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All the data used in this study are available in the form of a spreadsheet (ESM).

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References

  • Abnisa F, Daud WMAW (2014) A review on co-pyrolysis of biomass: an optional technique to obtain a high-grade pyrolysis oil. Energy Convers Manag 87:71–85

    Article  CAS  Google Scholar 

  • Abnisa F, Daud WW, Sahu J (2014) Pyrolysis of mixtures of palm shell and polystyrene: an optional method to produce a high-grade of pyrolysis oil. Environ Prog Sustain Energy 33:1026–1033

    Article  CAS  Google Scholar 

  • Aboulkas A, El Bouadili A (2010) Thermal degradation behaviors of polyethylene and polypropylene. Part I: pyrolysis kinetics and mechanisms. Energy Convers Manag 51:1363–1369

    Article  CAS  Google Scholar 

  • Aguado J, Serrano D, San Miguel G (2007) European trends in the feedstock recycling of plastic wastes. Global Nest J 9:12–19

    Google Scholar 

  • Al-Salem S, Antelava A, Constantinou A, Manos G, Dutta A (2017) A review on thermal and catalytic pyrolysis of plastic solid waste (PSW). J Environ Manag 197:177–198

    Article  CAS  Google Scholar 

  • Andrady AL, Neal MA (2009) Applications and societal benefits of plastics. Philos Trans R Soc B Biol Sci 364:1977–1984

    Article  CAS  Google Scholar 

  • Arbab M, Masjuki H, Varman M, Kalam M, Imtenan S, Sajjad H (2013) Fuel properties, engine performance and emission characteristic of common biodiesels as a renewable and sustainable source of fuel. Renew Sustain Energy Rev 22:133–147

    Article  CAS  Google Scholar 

  • Asadullah M, Rahman MA, Ali MM, Motin MA, Sultan MB, Alam MR, Rahman MS (2008) Jute stick pyrolysis for bio-oil production in fluidized bed reactor. Bioresour Technol 99:44–50

    Article  CAS  Google Scholar 

  • ASTM D1298-12 (2012b) Standard test method for density, relative density (specific gravity), or API gravity of crude petroleum and liquid petroleum products by hydrometer method. ASTM International, West Conshohocken. doi:https://doi.org/10.1520/D1298-12

  • ASTM D130-12 (2012a) Standard test method for corrosiveness to copper from petroleum products by copper strip test. ASTM International, West Conshohocken. doi:https://doi.org/10.1520/D0130-12

  • ASTM D445-06 (2006) Standard test method for kinematic viscosity of transparent and opaque liquids (and calculation of dynamic viscosity). ASTM International, West Conshohocken. doi:https://doi.org/10.1520/D0445-06

  • ASTM D4737-04 (2004a) Standard test method for calculated cetane index by four variable equation. ASTM International, West Conshohocken. doi:https://doi.org/10.1520/D4737-04

  • ASTM D86-01 (2001) Standard test method for distillation of petroleum products at atmospheric pressure. ASTM International, West Conshohocken. doi:https://doi.org/10.1520/D0086-01

  • ASTM D93-00 (2000) Standard test methods for flash-point by Pensky–Martens closed cup tester. ASTM International, West Conshohocken. doi:https://doi.org/10.1520/D0093-00

  • ASTM D95-18 (2018) Standard test method for water in petroleum products and bituminous materials by distillation. ASTM International, West Conshohocken. doi:https://doi.org/10.1520/D0095-13R18

  • ASTM D97-15 (2015) Standard test method for pour point of petroleum products. ASTM International, West Conshohocken. doi:https://doi.org/10.1520/D0097-15

  • ASTM D976-04 (2004b) Standard test methods for calculated cetane index of distillate fuels. ASTM International, West Conshohocken. doi:https://doi.org/10.1520/D0976-04

  • Bezaire N, Wadumesthrige K, Ng KS, Salley SO (2010) Limitations of the use of cetane index for alternative compression ignition engine fuels. Fuel 89:3807–3813

    Article  CAS  Google Scholar 

  • Çepelioğullar Ö, Pütün AE (2013) Utilization of two different types of plastic wastes from daily and industrial life. J Selcuk Univ Nat Appl Sci 2:694–706

    Google Scholar 

  • Cookson DJ, Iliopoulos P, Smith BE (1995) Composition-property relations for jet and diesel fuels of variable boiling range. Fuel 74:70–78. https://doi.org/10.1016/0016-2361(94)P4333-W

    Article  CAS  Google Scholar 

  • del Coro Fernández-Feal MM, Sánchez-Fernández LR, Sánchez-Fernández B (2017) Distillation: basic test in quality control of automotive fuels. In: Distillation Innovative Applications and Modeling, p 77

  • Demirbas A, Al-Sasi BO, Nizami A-S (2016) Conversion of waste tires to liquid products via sodium carbonate catalytic pyrolysis. Energy Sour A Recovery Util Environ Effects 38:2487–2493

    Article  CAS  Google Scholar 

  • DeNeve D, Joshi C, Samdani A, Higgins J, Seay J (2017) Optimization of an appropriate technology based process for converting waste plastic in to liquid fuel via thermal decomposition. J Sustain Dev 10:116–124

    Article  Google Scholar 

  • FakhrHoseini SM, Dastanian M (2013) Predicting pyrolysis products of PE, PP, and PET using NRTL activity coefficient model. J Chem 2013

  • Flórez JAÁ, Agramunt IC (2005) Motores alternativos de combustión interna. Universitat Politecnica de Catalunya. Iniciativa Digital Politecnica

  • Hartulistiyoso E, Sigiro FA, Yulianto M (2015) Temperature distribution of the plastics Pyrolysis process to produce fuel at 450°C. Proced Environ Sci 28:234–241

    Article  CAS  Google Scholar 

  • He B, Thompson J, Routt D, Van Gerpen J (2007) Moisture absorption in biodiesel and its petro-diesel blends. Appl Eng Agric 23:71–76

    Article  CAS  Google Scholar 

  • Heikkinen J, Hordijk JD, de Jong W, Spliethoff H (2004) Thermogravimetry as a tool to classify waste components to be used for energy generation. J Anal Appl Pyrolysis 71:883–900

    Article  CAS  Google Scholar 

  • Hopewell J, Dvorak R, Kosior E (2009) Plastics recycling: challenges and opportunities. Philos Trans Royal Soc B Biol Sci 364:2115–2126

    Article  CAS  Google Scholar 

  • Jahirul MI, Rasul MG, Chowdhury AA, Ashwath N (2012) Biofuels production through biomass pyrolysis: a technological review. Energies 5:4952–5001

    Article  CAS  Google Scholar 

  • Joshi C, Seay J (2019a) Building momentum for sustainable behaviors in developing regions using Locally Managed Decentralized Circular Economy principles. Chin J Chem Eng 27:1566–1571

    Article  CAS  Google Scholar 

  • Joshi CA, Seay JR (2019b) Total generation and combustion emissions of plastic derived fuels: a trash to tank approach. Environ Prog Sustain Energy

  • Joshi C, Seay J, Banadda N (2019) A perspective on a locally managed decentralized circular economy for waste plastic in developing countries. Environ Prog Sustain Energy 38:3–11

    Article  CAS  Google Scholar 

  • Jung S-H, Cho M-H, Kang B-S, Kim J-S (2010) Pyrolysis of a fraction of waste polypropylene and polyethylene for the recovery of BTX aromatics using a fluidized bed reactor. Fuel Process Technol 91:277–284

    Article  CAS  Google Scholar 

  • Kiran N, Ekinci E, Snape CE (2000) Recyling of plastic wastes via pyrolysis. Resour Conserv Recycl 29:273–283. https://doi.org/10.1016/S0921-3449(00)00052-5

    Article  Google Scholar 

  • Kizza R, Banadda N, Kabenge I, Seay J, Willet S, Kiggundu N, Zziwa A (2019) Pyrolysis of wood residues in a cylindrical batch reactor: effect of operating parameters on the quality and yield of products. J Sustain Dev 12:112–130

    Article  Google Scholar 

  • Komakech AJ, Banadda NE, Kinobe JR, Kasisira L, Sundberg C, Gebresenbet G, Vinnerås B (2014) Characterization of municipal waste in Kampala, Uganda. J Air Waste Manag Assoc 64:340–348. https://doi.org/10.1080/10962247.2013.861373

    Article  CAS  Google Scholar 

  • Lee S, Chen L, Yoshida K, Yoshikawa K (2015) Application of waste biomass pyrolysis oil in a direct injection diesel engine: for a small scale non-grid electrification. J Energ Power Eng 9:929–943

    CAS  Google Scholar 

  • Levis JW, Barlaz MA (2011) Is biodegradability a desirable attribute for discarded solid waste? Perspectives from a national landfill greenhouse gas inventory model. Environ Sci Technol 45:5470–5476

    Article  CAS  Google Scholar 

  • Medina M (2007) Waste picker cooperatives in developing countries. Membersh Based Org Poor 105:21

    Google Scholar 

  • Medina M (2008) The informal recycling sector in developing countries: organizing waste pickers to enhance their impact

  • Miandad R, Rehan M, Nizami A-S, Barakat MAE-F, Ismail IM (2016) The energy and value-added products from pyrolysis of waste plastics. Recycling of solid waste for biofuels and bio-chemicals. Springer, New York, pp 333–355

    Chapter  Google Scholar 

  • Miandad R, Barakat M, Aburiazaiza AS, Rehan M, Ismail I, Nizami A (2017) Effect of plastic waste types on pyrolysis liquid oil. Int Biodeterior Biodegrad 119:239–252

    Article  CAS  Google Scholar 

  • Miranda R, Yang J, Roy C, Vasile C (1999) Vacuum pyrolysis of PVC I. Kinetic study Polym Degrad Stab 64:127–144

    Article  CAS  Google Scholar 

  • Mofijur M, Rasul MG, Hassan NMS, Masjuki HH, Kalam MA, Mahmudul HM (2017) Chapter fourteen: assessment of physical, chemical, and tribological properties of different biodiesel fuels. In: Rasul MG, Azad Ak, Sharma SC (eds) Clean energy for sustainable development. Academic Press, Cambridge, pp 441–463. doi: https://doi.org/10.1016/B978-0-12-805423-9.00014-4

  • Munu N, Banadda N (2016) Can cities become self-reliant in energy? A technological scenario analysis for Kampala, Uganda. Environ Eng Res 21:219–225

    Article  Google Scholar 

  • Nileshkumar KD, Jani R, Patel TM, Rathod GP (2015) Effect of blend ratio of plastic pyrolysis oil and diesel fuel on the performance of single cylinder CI engine. Int J Sci Technol Eng 1:195–203

    Google Scholar 

  • Omar R, Idris A, Yunus R, Khalid K, Isma MA (2011) Characterization of empty fruit bunch for microwave-assisted pyrolysis. Fuel 90:1536–1544

    Article  CAS  Google Scholar 

  • Ouda OK, Raza S, Nizami A, Rehan M, Al-Waked R, Korres N (2016) Waste to energy potential: a case study of Saudi Arabia. Renew Sustain Energy Rev 61:328–340

    Article  Google Scholar 

  • Owusu PA, Banadda N, Zziwa A, Seay J, Kiggundu N (2018) Reverse engineering of plastic waste into useful fuel products. J Anal Appl Pyrolysis 130:285–293

    Article  CAS  Google Scholar 

  • Philip M, Attwood J, Hulme A, Williams G, Shipton P (2004) Evaluation of weathering in mixed polyethylene and polypropylene products. Published by The Waste and Resources Action Program p 113

  • Rochman CM et al (2013) Policy: classify plastic waste as hazardous. Nature 494:169

    Article  CAS  Google Scholar 

  • Scalenghe R (2018) Resource or waste? A perspective of plastics degradation in soil with a focus on end-of-life options. Heliyon. https://doi.org/10.1016/j.heliyon.2018.e00941

    Article  Google Scholar 

  • Sharuddin SDA, Abnisa F, Daud WMAW, Aroua MK (2016) A review on pyrolysis of plastic wastes. Energy Convers Manag 115:308–326

    Article  Google Scholar 

  • Sharuddin SDA, Abnisa F, Daud WMAW, Aroua MK (2017) Energy recovery from pyrolysis of plastic waste: Study on non-recycled plastics (NRP) data as the real measure of plastic waste. Energy Convers Manag 148:925–934

    Article  Google Scholar 

  • Sogancioglu M, Ahmetli G, Yel E (2017) A comparative study on waste plastics pyrolysis liquid products quantity and energy recovery potential. Energy Proced 118:221–226

    Article  CAS  Google Scholar 

  • Tukahirwa JT, Mol AP, Oosterveer P (2010) Civil society participation in urban sanitation and solid waste management in Uganda. Local Environment 15:1–14

    Article  Google Scholar 

  • Uganda National Bureau of Standards (UNBS) (2019) Draft Uganda standard: automotive gas oil (automotive diesel): specification, 3rd edn. Uganda National Bureau of Standards (UNBS), Uganda

  • World Economic Forum (WEF) (2020) Plastics, the circular economy and global trade. Geneva

  • WorldWide Fund for Nature (WWF) (2018) The lifecycle of plastics, vol 2020. World Wide Fund for Nature WWF, Australia

    Google Scholar 

  • Xing-cai L, Jian-Guang Y, Wu-Gao Z, Zhen H (2004) Effect of cetane number improver on heat release rate and emissions of high speed diesel engine fueled with ethanol–diesel blend fuel. Fuel 83:2013–2020

    Article  Google Scholar 

  • Zohoori M, Ghani A (2017) Municipal solid waste management challenges and problems for cities in low-income and developing countries. Int J Sci Eng Appl 6:39–48

    Google Scholar 

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Funding

This study was funded by the University of Kentucky Appropriate Technology and Sustainability (UKATS) Research Group and Makerere University Department of Agricultural and Bio-systems Engineering.

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Authors and Affiliations

  1. Department of Agricultural and Bio-Systems Engineering, Makerere University, P. O. Box 7062, Kampala, Uganda

    Ronald Kizza & Noble Banadda

  2. Department of Chemical and Materials Engineering, University of Kentucky, Lexington, KY, 42002, USA

    Jeffrey Seay

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  1. Ronald Kizza
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  2. Noble Banadda
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  3. Jeffrey Seay
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Correspondence to Jeffrey Seay.

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Kizza, R., Banadda, N. & Seay, J. Qualitative and energy recovery potential analysis: plastic-derived fuel oil versus conventional diesel oil. Clean Techn Environ Policy 24, 789–800 (2022). https://doi.org/10.1007/s10098-021-02028-9

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