Skip to main content
Log in

Thermodynamic Modelling of Molybdenite Roasting in a Multiple-Hearth Furnace

  • Thermodynamic Optimization of Critical Metals Processing and Recovery
  • Published:
JOM Aims and scope Submit manuscript

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

A thermodynamic model was developed to study the roasting of molybdenite ore into molybdenum trioxide in a multiple-hearth furnace roaster. The model was developed using FactSage, a software specializing in thermochemical simulations. The model assumes thermodynamic equilibrium between the solid and gaseous phases on each hearth. The results from the model were compared with operational data obtained from an earlier paper regarding molybdenite conversion at the then Climax Molybdenum Co. roaster in Langeloth, PA, USA. A good correlation has been observed between the conversion of molybdenum-containing species on each hearth and experimental data from the Climax roaster. The developed model also describes the behavior of some of the minor compounds typically present as impurities in molybdenite concentrates.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. C. Gupta, Extractive Metallurgy of Molybdenum (CRC, Boca Raton, 1992).

    Google Scholar 

  2. A.N. Zelikman, and B.G. Korshunov, Metallurgiya redkikh metallov [Metallurgy of Rare Metals] (Metallurgy, Moscow, 1991).

  3. E.S. Wheeler, AIME 159, 431 (1944).

    Google Scholar 

  4. L.F. McHugh, J. Godshalk, and M. Kuzior, Can. Metall. Q. 16, 21 (1977).

  5. Y.I. Voronov, V.P. Zayko, and V.I. Zuchkov, Technology of Molybdenum Containing Ferro-Alloys (Russian Academy of Sciences; Urals Institute of Metallurgy, Ekaterinburgh, 2000).

    Google Scholar 

  6. M.I. Gasik, N.P. Lyakishev, and E.I. Emlin, Theory and Technology of Ferro-Alloys Production (Metallurgy, Moscow, 1988).

    Google Scholar 

  7. M.C. Jha and W.A. May, Extraction of Rhenium from Molybdenite Concentrates (The Minerals, Metals & Materials Society, 1997), pp. 69–78.

  8. B.P. Luke, and L.Y. Chang, J. Am. Ceram. Soc. 52, 527 (1969).

    Article  Google Scholar 

  9. A. Roine, HSC Chemistry for Windows 7.11, Outotec Research Center, Finland (2006).

  10. C.W. Bale, Calphad 54, 35 (2016).

    Article  Google Scholar 

  11. V.I. Deev, and V.I. Smirnov, Soviet J. Nonferr. Met. 5, 64 (1964).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Nimit M. Shah.

Ethics declarations

Conflict of interest

The authors whose names are listed immediately below certify that they have no affiliations with or involvement in any organization or entity with any financial interest (such as honoraria; educational grants, participation in speakers’ bureaus, membership, employment, consultancies, stock ownership, or other equity interest, or expert testimony or patent-licensing arrangements), or non-financial interest (such as personal or professional relationships, affiliations, knowledge, or beliefs) in the subject matter or materials discussed in this manuscript.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shekhter, L.N., Litz, J.E., Shah, N.M. et al. Thermodynamic Modelling of Molybdenite Roasting in a Multiple-Hearth Furnace. JOM 73, 873–880 (2021). https://doi.org/10.1007/s11837-020-04549-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11837-020-04549-y

Navigation