Abstract
Jojoba seed is an attractive alternative energy source in Saudi Arabia due to its high adaptability to harsh weather, saline water, desert, and hot temperature. In the present study, cold-pressed jojoba oil is used for the synthesis of biodiesel. In addition to that, this research work carried out a detailed optimization study of process parameters using response surface methodology. An empirical model is developed and employed for the optimization of process parameters. The study also investigates the significance of process parameters on biodiesel yield from the jojoba seed. Results show that the molar ratio of methanol to oil is the most significant input parameter, followed by the reaction time and NaOH concentration. The developed model was further validated using experimental results. The study also examined the combined effects of process parameters on process optimization. The maximum yield conditions are 15.99 molar ratio of methanol to jojoba oil, 15-min reaction time, and 1.5 wt% NaOH concentration.
Similar content being viewed by others
Data Availability
The data that support the findings of this study are available on request from the corresponding author. The data are not publicly available due to the privacy restriction by the University of Jeddah.
References
Fankhauser, S.; Jotzo, F.: Economic growth and development with low-carbon energy. Wiley Interdiscip. Rev. Clim. Change 9(1), e495 (2018)
Bindraban, P.S.; Bulte, E.H.; Conijn, S.G.: Can large-scale biofuels production be sustainable by 2020? Agric. Syst. 101(3), 197–199 (2009)
Canakci, M.: Combustion characteristics of a turbocharged DI compression ignition engine fueled with petroleum diesel fuels and biodiesel. Biores. Technol. 98(6), 1167–1175 (2007)
Antolın, G.; Tinaut, F.; Briceno, Y.; Castano, V.; Perez, C.; Ramırez, A.: Optimisation of biodiesel production by sunflower oil transesterification. Bioresour. Technol. 83(2), 111–114 (2002)
Nguyen, H.C.; et al.: Direct transesterification of black soldier fly larvae (Hermetia illucens) for biodiesel production. J. Taiwan Inst. Chem. Eng. 85, 165–169 (2018). https://doi.org/10.1016/j.jtice.2018.01.035
Gui, M.M.; Lee, K.; Bhatia, S.: Feasibility of edible oil vs. non-edible oil vs. waste edible oil as biodiesel feedstock. Energy 33(11), 1646–1653 (2008)
Busson-Breysse, J.; Farines, M.; Soulier, J.: Jojoba wax: its esters and some of its minor components. J. Am. Oil. Chem. Soc. 71(9), 999–1002 (1994)
Hoda, N.: Optimization of biodiesel production from cottonseed oil by transesterification using NaOH and methanol. Energy Sources Part A Recov. Util. Environ. Eff. 32(5), 434–441 (2010)
Gimbun, J.; et al.: Biodiesel production from rubber seed oil using activated cement clinker as catalyst. Procedia Eng. 53, 13–19 (2013)
Da Silva, N.D.L.; Maciel, M.R.W.; Batistella, C.B.; Maciel Filho, R.: Optimization of biodiesel production from castor oil. In: Twenty-Seventh Symposium on Biotechnology for Fuels and Chemicals, pp. 405–414. Springer (2006)
Fadhil, A.B.; Ahmed, K.M.; Dheyab, M.M.: Silybum marianum L. seed oil: a novel feedstock for biodiesel production. Arab. J. Chem. 10, S683–S690 (2017)
Nehdi, I.A.; Sbihi, H.M.; Mokbli, S.; Rashid, U.; Al-Resayes, S.I.: Yucca aloifolia oil methyl esters. Ind. Crops Prod. 69, 257–262 (2015)
Abbott, T.P.; Holser, R.A.; Plattner, B.J.; Plattner, R.D.; Purcell, H.C.: Pilot-scale isolation of simmondsin and related jojoba constituents. Ind. Crops Prod. 10(1), 65–72 (1999)
Lein, S.; et al.: Simultaneous determination of carbohydrates and simmondsins in jojoba seed meal (Simmondsia chinensis) by gas chromatography. J. Chromatogr. A 977(2), 257–264 (2002)
Shah, S.N.; Sharma, B.K.; Moser, B.R.; Erhan, S.Z.: Preparation and evaluation of jojoba oil methyl esters as biodiesel and as a blend component in ultra-low sulfur diesel fuel. BioEnergy Res. 3(2), 214–223 (2010). https://doi.org/10.1007/s12155-009-9053-y
Al-Hamamre, Z.; Rawajfeh, K.: Investigating the energy value of jojoba as an alternative renewable energy source. Int. J. Green Energy 12(4), 398–404 (2015)
Li, T.; Kou, G.; Peng, Y.; Shi, Y.: Classifying with adaptive hyper-spheres: an incremental classifier based on competitive learning. IEEE Trans. Syst. Man Cybern. Syst. 50(4), 1218–1229 (2020)
Kou, G.; Lu, Y.; Peng, Y.; Shi, Y.: Evaluation of classification algorithms using MCDM and rank correlation. Int. J. Inf. Technol. Decis. Mak. 11(01), 197–225 (2012)
Box, G.E.; Draper, N.R.: Empirical Model-Building and Response Surfaces. Wiley, New York (1987)
Ali, A.; Abdulrahman, A.: Optimization and sensitivity study of biodiesel synthesis from Jojoba oil using mixed-integer programming. Materialwissenschaft und Werkstofftechnik 51(7), 920–929 (2020). https://doi.org/10.1002/mawe.201900160
Lim, S.; Lee, K.T.: Optimization of supercritical methanol reactive extraction by Response Surface Methodology and product characterization from Jatropha curcas L. seeds. Bioresour. Technol. 142, 121–130 (2013)
Ong, L.K.; Effendi, C.; Kurniawan, A.; Lin, C.X.; Zhao, X.S.; Ismadji, S.: Optimization of catalyst-free production of biodiesel from Ceiba pentandra (kapok) oil with high free fatty acid contents. Energy 57, 615–623 (2013)
Coteron, A.; Sanchez, N.; Martinez, M.; Aracil, J.: Optimisation of the synthesis of an analogue of jojoba oil using a fully central composite design. Can. J. Chem. Eng. 71(3), 485–488 (1993)
Canoira, L.; Alcantara, R.; García-Martínez, M.J.; Carrasco, J.: Biodiesel from Jojoba oil-wax: transesterification with methanol and properties as a fuel. Biomass Bioenergy 30(1), 76–81 (2006)
Abdelmoez, W.; Tayeb, A.M.; Mustafa, A.; Abdelhamid, M.: Green approach for biodiesel production from jojoba oil supported by process modeling and simulation. Int. J. Chem. Reactor Eng. 14(1), 185–193 (2016)
Bouaid, A.; Bajo, L.; Martinez, M.; Aracil, J.: Optimization of biodiesel production from jojoba oil. Process Saf. Environ. Prot. 85(5), 378–382 (2007)
Sánchez, M.; Avhad, M.R.; Marchetti, J.M.; Martínez, M.; Aracil, J.: Jojoba oil: a state of the art review and future prospects. Energy Convers. Manag. 129, 293–304 (2016). https://doi.org/10.1016/j.enconman.2016.10.038
Kubendran, D.; Salma-Aathika, A.R.; Amudha, T.; Thiruselvi, D.; Yuvarani, M.; Sivanesan, S.: Utilization of leather fleshing waste as a feedstock for sustainable biodiesel production. Energy Sources Part A Recov. Util. Environ. Eff. 39(15), 1587–1593 (2017)
Danish, M.; Yahya, S.M.; Saha, B.B.: Modelling and optimization of thermophysical properties of aqueous titania nanofluid using response surface methodology. J. Therm. Anal. Calorim. 139, 3051–3063 (2020)
Chabbi, A.; Yallese, M.A.; Meddour, I.; Nouioua, M.; Mabrouki, T.; Girardin, F.: Predictive modeling and multi-response optimization of technological parameters in turning of Polyoxymethylene polymer (POM C) using RSM and desirability function. Measurement 95, 99–115 (2017)
Danish, M.; Ginta, T.L.; Habib, K.; Carou, D.; Rani, A.M.A.; Saha, B.B.: Thermal analysis during turning of AZ31 magnesium alloy under dry and cryogenic conditions. Int. J. Adv. Manuf. Technol. 91(5–8), 2855–2868 (2017)
Devaraj, K.; et al.: Study on effectiveness of activated calcium oxide in pilot plant biodiesel production. J. Cleaner Prod. 225, 18–26 (2019)
Acknowledgements
This work was funded by the University of Jeddah, Saudi Arabia, under Grant No. (UJ-13-18-ICP). The authors, therefore, acknowledge with thanks to the University’s technical and financial support.
Author information
Authors and Affiliations
Contributions
AA was involved in conceptualization, methodology, and writing—reviewing and editing. AA was involved in RSM modeling, simulation, and validation, reviewing and editing. AA was involved in experimentation, data collection, and organization, reviewing and editing.
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Rights and permissions
About this article
Cite this article
Abdulrahman, A., Ali, A. & Alfazazi, A. Synthesis and Process Parameter Optimization of Biodiesel from Jojoba Oil Using Response Surface Methodology. Arab J Sci Eng 46, 6609–6617 (2021). https://doi.org/10.1007/s13369-020-05302-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13369-020-05302-y