Issue 13, 2021
From the journal:

Chemical Communications

A radical mixed-ligand gold bis(dithiolene) complex†

Romain Perochon,a   Frédéric Barrière,a   Olivier Jeannin,a   Lidia Piekara-Sadyb  and  Marc Fourmigué ORCID logo *a  

* Corresponding authors

a Univ. Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) – UMR 6226, Rennes F- 35042, France
E-mail: marc.fourmigue@univ-rennes1.fr

b Institute of Molecular Physics, Polish Academy of Science, M. Smoluchowskiego 17, Poznań 60-179, Poland

Abstract

A mixed-ligand bis(dithiolene) gold complex is isolated from scrambling reaction of two neutral radical symmetric complexes. Its asymmetric character translates into specific structural and electronic properties including larger electrochemical and optical band gaps than those of both precursors.

Graphical abstract: A radical mixed-ligand gold bis(dithiolene) complex

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Article information

DOI
https://doi.org/10.1039/D0CC07602C
Article type
Communication
Submitted
19 Nov 2020
Accepted
11 Jan 2021
First published
15 Jan 2021

Chem. Commun., 2021,57, 1615-1618

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A radical mixed-ligand gold bis(dithiolene) complex

R. Perochon, F. Barrière, O. Jeannin, L. Piekara-Sady and M. Fourmigué, Chem. Commun., 2021, 57, 1615 DOI: 10.1039/D0CC07602C

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