Abstract
The separation strategies of mixtures are determined by knowledge of their structures of phase equilibrium diagrams. In this paper, in two independent ways, namely, by constructing K = 1 lines and on the basis of the analysis of the transformations of the phase diagrams when the external conditions change, all thermodynamically possible subtypes of the phase portraits of the trajectories of the open equilibrium evaporation of three-component systems containing binary biazeotropic components and not containing ternary azeotropes are determined. An atlas of structures of vapor–liquid equilibrium diagrams of the indicated systems is created (116 diagrams in total).
Similar content being viewed by others
REFERENCES
Serafimov, L.A., Thermodynamic and topological analysis of liquid–vapor phase equilibrium diagrams and problems of rectification of multicomponent mixtures, Mathematical Methods in Contemporary Chemistry, Kuchanov, S.I., Ed., Amsterdam: Gordon and Breach, 1996, ch. 10, pp. 557–605.
Kiva, V., Hilmen, E.K., and Skogestad, S., Azeotropic phase equilibrium diagrams: A survey, Chem. Eng. Sci., 2003, vol. 58, no. 10, p. 1903. https://doi.org/10.1016/S0009-2509(03)00018-6
Shen, W.F., Benyounes, H., and Song, J., A review of ternary azeotropic mixtures advanced separation strategies, Theor. Found. Chem. Eng., 2016, vol. 50, no. 1, p. 28. https://doi.org/10.1134/S0040579516010140
Gurikov, Yu.V., Some issues of the structure of vapor–liquid phase equilibrium diagrams for ternary homogeneous systems, Zh. Fiz. Khim., 1958, vol. 32, no. 9, p. 1980.
Serafimov, L.A., Theoretical principles of distillation flowsheet design for nonideal multicomponent mixtures, Doctoral (Eng.) Dissertation, Moscow: Lomonosov Moscow Inst. of Fine Chemical Technology, 1968.
Zharov, V.T., Thermodynamic and topological analysis of open phase processes and nonlocal regularities of phase equilibrium diagrams for heterogeneous systems of different types, Extended Abstract of Doctoral (Chem.) Dissertation, Leningrad: Leningrad State Univ., 1969.
Zharov, V.T. and Serafimov, L.A., Fiziko-khimicheskie osnovy distillyatsii i rektifikatsii (Physicochemical Fundamentals of Distillation Processes), Leningrad: Khimiya, 1975.
Matsuyama, H. and Nishimura, H., Topological and thermodynamic classification of ternary vapor-liquid equilibria, J. Chem. Eng. Jpn., 1977, vol. 10, no. 3, p. 181.
Komarova, L.V., Serafimov, L.A., and Garber, Yu.N., Classification of the diagrams of three-component mixtures containing biazeotropic constituents, Zh. Fiz. Khim., 1974, vol. 48, no. 6, p. 1391.
Kushner, T.M., Chelyuskina, T.V., and Serafimov, L.A., A thermodynamic–topological analysis of vapor–liquid equilibrium diagrams for ternary systems with two ternary azeotropes, Russ. J. Phys. Chem. A, 1999, vol. 73, no. 3, pp. 356– 364.
Chelyuskina, T.V., Thermodynamic and topological analysis of three-component systems with two ternary azeotropes, Cand. Sci. (Eng.) Dissertation, Moscow: Lomonosov Moscow State Academy of Fine Chemical Technology, 2001.
Myagkova, T.O., Physicochemical fundamentals of the separation of biazeotropic mixtures, Cand. Sci. (Eng.) Dissertation, Moscow: Lomonosov Moscow State Academy of Fine Chemical Technology, 2007.
Serafimov, L.A. and Chelyuskina, T.V., Principles of classifying diagrams for different types of biazeotropic ternary mixtures, Russ. J. Phys. Chem. A, 2011, vol. 85, no. 5, pp. 767–776. https://doi.org/10.1134/S003602441105027X
Serafimov, L.A., General regularities of K-lines in three-component vapor–liquid systems, Sbornik trudov “Fiziko-khimicheskie osnovy rektifikatsii” (Physicochemical Fundamentals of Distillation: A Collection of Scientific Works), Lvov, S.V., Ed., Moscow: Mosk. Inst. Tonkoi Khim. Tekhnol. im. M.V. Lomonosova, 1970, p. 20.
Serafimov, L.A., Thermodynamic and topological analysis of heterogeneous equilibrium diagrams of multicomponent mixtures, Russ. J. Phys. Chem. A, 2002, vol. 76, no. 8, p. 1211.
Serafimov, L.A., Chelyuskina, T.V., Polkovnichenko, A.V., and Yakushev, R.A., The analysis of the mutual transformations of the structures of diagrams of ternary systems via the formation of binary internal tangential azeotropes, Theor. Found. Chem. Eng., 2018, vol. 52, no. 6, pp. 963–974. https://doi.org/10.1134/S0040579518040401
Chelyuskina, T.V., Polkovnichenko, A.V., and Modurova, D.D., Analysis of mutual transformations of the structures of the diagrams of ternary systems via the formation of binary boundary tangential azeotropes, Theor. Found. Chem. Eng., 2020, vol. 54, no. 4, pp. 560–568. https://doi.org/10.1134/S0040579520040156
Serafimov, L.A., Chelyuskina, T.V., and Yakushev, R.A., Thermodynamic and topological analysis of the formation of internal tangential azeotropes in binary two-phase systems, Tonkie Khim. Tekhnol., 2015, vol. 10, no. 4, p. 41.
Funding
This study was financially supported by the Russian Foundation for Basic Research (project no. 18-03-01224-a).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Chelyuskina, T.V., Polkovnichenko, A.V. & Modurova, D.D. Extension of the Classification of Three-Component Systems Containing Binary Biazeotropic Components and Not Containing Ternary Azeotropes. Theor Found Chem Eng 54, 1247–1255 (2020). https://doi.org/10.1134/S0040579520060135
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0040579520060135