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Cu2O Nanocatalysts Immobilized on p(SBMA) for Synergistic CO2 Activation to Afford Esters and Heterocycles at Ambient Pressure

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Abstract

Herein, we report a chemoselective insertion of CO2 into unsaturated alkyne substrates under ambient conditions, which is achieved over poly (sulfobetain methacrylate) (p(SBMA)) supported Cu2O nanocatalyst (Cu2O/p(SBMA)) and a series of 3a,4-dihydronaphtho[2,3-c]furan-1(3H)-ones, can be obtained in excellent yields. Cu2O/p(SBMA) presents high performance for environment pressure activation and interpolation of CO2 into unsaturated alkyne substrates. This provides an attainable and competent catalyst for interpolation of CO2 into aryl alkynes, and binding allylic chlorides through SN2 mechanism in order to produce efficient ester and lactone heterocycles that are supposed to have favorable utilizations. All in all, these findings signify practical methods of hybrid catalyst development for detailed alterations, including CO2 employment in a green and sustainable manner.

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Acknowledgement

This work was supported by the Special Scientific Research Project of Shaanxi Education Department (Nos:19JK0904, 18JK1194) and Science Research Foundation of Xijing University (Nos: XJ18T03, XJ18B05).

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Authors and Affiliations

  1. Key Laboratory of Organic Polymer Photoelectric Materials, School of Science, Xijing University, Xi’an, 710123, People’s Republic of China

    Yanfang Zhu, Wenqi Song, Maoni Wu & Ruijuan Yao

  2. Xi’an Modern Chemistry Research Institute, Xi’an, 710065, People’s Republic of China

    Guiyang Xu

  3. Department of Chemistry, Faculty of Sciences, Neyshabur Branch, Islamic Azad University, Neyshabur, Iran

    Seyed Mohsen Sadeghzadeh

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  1. Yanfang Zhu
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  2. Guiyang Xu
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  3. Wenqi Song
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  4. Maoni Wu
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  5. Ruijuan Yao
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  6. Seyed Mohsen Sadeghzadeh
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Correspondence to Yanfang Zhu or Seyed Mohsen Sadeghzadeh.

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Zhu, Y., Xu, G., Song, W. et al. Cu2O Nanocatalysts Immobilized on p(SBMA) for Synergistic CO2 Activation to Afford Esters and Heterocycles at Ambient Pressure. Catal Lett 151, 2724–2733 (2021). https://doi.org/10.1007/s10562-020-03518-z

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  • DOI: https://doi.org/10.1007/s10562-020-03518-z

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