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Insights on the Heating Characteristics of Mn and Co Ferrites

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Abstract

The heating characteristics of ferrite nanoparticles are inconsistent due to various factors that affect the optimum particle size required for maximum power dissipation. The heating mechanism of Fe3O4, MnFe2O4, and Co0.5Fe2.5O4 in the size range 10–40 nm with varying particle size distribution is correlated with the effective specific absorption rate (ESAR). The effective magnetic anisotropy of the ferrite samples determined using electron spin resonance is between 11.8 and 24.8 kJ· m−3. The thermal profiles of Fe3O4, MnFe2O4, and Co0.5Fe2.5O4 are probed employing infrared thermography where the measured ESAR is between 1.74 and 3.16 nHm2·kg−1. The theoretical ESAR of 16.63 and 9.19 nHm2·kg−1 are obtained for the Co substituted Fe3O4 and MnFe2O4, respectively, for an average size of 40 nm. The analysis of particle size distributions in combination with theoretical estimations gives the percentage of particles contributing to the power dissipation as 80 % for narrow dispersion and 45 % for broad dispersion deviating from the predicted optimum size range. In addition to ascertaining the functioning regime of the linear response theory, an increase in ESAR with decreasing anisotropy energy is observed. The discrepancy between the simulations and experimentations is prudently examined, taking the intrinsic as well as extrinsic parameters into account.

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Data Availability

The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.

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Acknowledgements

The authors acknowledge the Department of Science and Technology (DST), Government of India, for the experimental facilities. Ms. J. Shebha Anandhi acknowledges Dr. T. Arun, Mr. G. Antilen Jacob, and Sophisticated Analytical Instruments Facility (SAIF), Indian Institute of Technology Madras for the electron spin resonance measurements, and Dr. R. Justin Joseyphus acknowledges DST for the project CRG/2018/000939.

Funding

No funding was received for conducting this study.

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Authors and Affiliations

  1. Magnetic Materials Laboratory, Department of Physics, National Institute of Technology, Tiruchirappalli, 620015, India

    J. Shebha Anandhi & R. Justin Joseyphus

Authors
  1. J. Shebha Anandhi
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  2. R. Justin Joseyphus
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Contributions

All authors contributed to the study conception and design. Material preparations, data collection, analysis and writing of the first draft of the manuscript were performed by Ms. J. Shebha Anandhi. Supervision was done by Dr. R. Justin Joseyphus. All authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Correspondence to R. Justin Joseyphus.

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Anandhi, J.S., Joseyphus, R.J. Insights on the Heating Characteristics of Mn and Co Ferrites. Int J Thermophys 42, 30 (2021). https://doi.org/10.1007/s10765-020-02782-w

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