Abstract
KDP (Potassium dihydrogen phosphate) single crystals were grown from Amaranth dye and EDTA (Ethylenediaminetetraacetic acid disodium salt) mixed KDP solutions by the temperature lowering method and Sankaranarayanan-Ramasamy technique. The molar concentration of EDTA in the solutions was 1 mol%. The Amaranth concentrations were 0.001, 0.005, 0.01, 0.03 and 0.05 mol%. The growth of KDP crystals was oriented in type I and type II phase-matching directions which bring maximum second harmonic generation (SHG) efficiency to the crystals. Optical properties of Amaranth and EDTA co-doped KDP crystals (KAE) were investigated by Ultraviolet-Visible (UV-Vis) spectroscopy, FT-Raman spectroscopy, and photoluminescence. SHG efficiency of the crystals was measured by shining 1064 nm Nd:YAG laser directly into them and receiving output signals. The most important result in the study showed that KAE crystals had SHG efficiency of 1.7 and 2.4 times higher than EDTA doped KDP crystal (KE) and pure KDP crystal respectively. Then second-order nonlinear optical coefficients of these crystals were calculated. The simultaneous doping of two organic substances into KDP crystals has further enhanced their nonlinear optical characteristics.
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Anis, M., Muley, G.G., Baig, M.I., Rabbani, G., Ghramh, H.A., Ramteke, S.P.: Doping effect of Ni2+ on structural, UV-visible, SHG efficiency, dielectric and microhardness traits of KH2PO4 (KDP) crystal. Optik 178, 757 (2019). https://doi.org/10.1016/j.ijleo.2018.10.061
Anis, M., Muley, G.G., Shirsat, M.D., Hussaini, S.S.: Single crystal growth, structural, optical, mechanical, dielectric and thermal studies of formic acid doped potassium dihydrogen phosphate crystal for NLO applications. Cryst. Res. Technol., (2015), https://doi.org/10.1002/crat.201400472
Asakuma, Y., Nishimura, M., Li, Q., Ang, H.M., Tade, M., Maeda, K., Fukui, K.: Colouring mechanism of dyed KDP crystal by quantum chemistry. J. Mol. Struct. 810, 7 (2007a). https://doi.org/10.1016/j.theochem.2007a.01.041
Asakuma, Y., Ukita, E., Maeda, K., Fukui, K., Iimura, K., Suzuki, M., Hirota, M.: Surface topography of dyed potassium dihydrogen phosphate (KDP) crystals. J. Cryst. Growth 7, 420 (2007). https://doi.org/10.1021/cg0602055
Bai, Z., Wang, Y., Lu, Z., Yuan, H., Jiang, L., Tan, T., Liu, Z., Wang, H., Cui, C., Hasi, W.: Efficient KDP frequency doubling SBS pulse compressed 532 nm hundred picosecond laser. Optik. 127, 9205 (2016). https://doi.org/10.1016/j.ijleo.2016.07.021
Baig, M.I., Muley, A.M.: G. G.: Influence of tartaric acid on linear-nonlinear optical and electrical properties of KH2PO4 crystal. Opt. Mater. 72, 1 (2017). https://doi.org/10.1016/j.optmat.2017.05.042
Balamurugan, N., Ramasamy, P.: Investigation of the growth rate formula and bulk laser damage threshold KDP crystal growth from aqueous solution by the Sankaranarayanan-Ramasamy (SR) method. Cryst. Growth Des. 6, 1644 (2006). https://doi.org/10.1021/cg050680n
Balamurugan, S., Ramasamy, P., Sharma, S. K., Inkong, Y., Manyum, P.: Investigation of SR method grown < 0 0 1 > directed KDP single crystal and its charaterization by high-resolution X-ray diffractometry (HRXRD), laser damage threshold, dielectric, thermal analysis, optical and hardness studies. Mater. Chem. Phys. 117, 465 (2009) https://doi.org/10.1016/j.matchemphys.2009.06.021
Balamurugan, S., Ramasamy, P.: Growth and characterization of unidirectional < 1 0 0 > KDP single crystal by Sankaranarayanan–Ramasamy (SR) method. Spectrochim. Acta, Part A 71, 1979 (2009) https://doi.org/10.1016/j.saa.2008.07.047
Barati, F., Dizaji, H.R.: Growth of KDP single crystal in second harmonic direction by modified Sankaranarayanan-Ramasamy method. Opt. Quant. Electron. 48, 432 (2016). https://doi.org/10.1007/s11082-016-0704-x
Burgot, J.-L.: Ionic Equilibria in Analytical Chemistry. Springer, New York (2012)
Chandran, S., Paulraj, R., Ramasamy, P.: Influence of amaranth dye on the growth and properties of KDP single crystal. Mater. Res. Bull. 68, 210 (2015). https://doi.org/10.1016/j.materresbull.2015.03.056
Chen, C., Sasaki, T., Li, R., Wu, Y., Lin, Z., Mori, Y., Hu, Z., Wang, J., Uda, S., Yoshimura, M., Yushi, K.Y.: Nonlinear Optical Borate Crystals: Principles and Applications. Wiley-VCH Verlag GmbH & Co. KgaA, Weinheim (2012)
Dmitriev, V.G., Gurzadyan, G.G., Nikogosyan, D.N.: Handbook of optical nonlinear crystal. Springer Series in Optical Sciences, Saladruck, Berlin (1999)
Dyan, A., Duchateau, G., Eslava, S., Stehle, J.L., Damiani, D., Piombini, H.: Transmission measurements in rapid growth KDP and DKDP crystals. J. Mod. Opt. 56, 45 (2009). https://doi.org/10.1080/09500340802428322
Eckardt, R.C., Masuda, H., Fan, Y.X., Byer, R.L.: Absolute and relative nonlinear optical coefficients of KDP, KD*P, BaB2O4, LiIO3, MgO:LiNbO3, and KTP measured by phase-matched second-harmonic generation. IEEE J. Quantum Electron. 26, 922 (1990). https://doi.org/10.1109/3.55534
Gouldieff, C., Wagner, F.R., Bertussi, B., Guillet, F., Natoli, J.Y.: Photoluminescence characterization of KH2PO4 crystal: application to three-dimensional growth-sector identification. Appl. Opt. 53, 3063 (2014). https://doi.org/10.1364/AO.53.003063
Hirota, S., Miki, H., Fukui, K., Maeda, K.: Coloring and habit modification of dyed KDP crystals as functions of supersaturation and dye concentration. J. Cryst. Growth. 235, 541 (2002). https://doi.org/10.1016/S0022-0248(01)01915-7
Huang, H., Lin, Z.S., Chen, C.T.: Mechanism of the linear electro-optic effect in potassium dihydrogen phosphate crystals. J. Appl. Phys. 104, 073116 (2008). https://doi.org/10.1063/1.2990769
Koechner, W., Bass, M.: Solid-State Lasers: A Graduate Text. Springer, New York (2003)
Kucheyev, S.O., Bostedt, C., Buuren, T.V., Willey, T.M., Land, T.A., Terninello, L.J., Felter, T.E., Hamza, A.V., Demos, S.G., Nelson, A.J.: Electronic structure of KD2xH2(1–x)PO4 studied by soft x-ray absorption and emission spectroscopies. Phys. Rev. B. 70, 245106 (2004). https://doi.org/10.1103/PhysRevB.70.245106
Li, W., Yu, G., Wang, S., Ding, J., Xu, X., Gu, Q., Wang, D., Huang, P.: Influence of temperature on the growth and surface morphology of Fe3+ poisoned KDP crystals. RSC Adv. 7, 17531 (2017). https://doi.org/10.1039/c6ra25710k
Lin, Z., Wang, Z., Chen, C.: Mechanism of linear and nonlinear optical effects of KDP and urea crystals. J. Chem. Phys. 118, 2349 (2003). https://doi.org/10.1063/1.1533734
Lu, G.W., Xia, H.R., Zhang, S.Q., Sun, X., Gao, Z.S., Wang, J.Y.: Raman scattering investigation of the effect of EDTA additives on growth habit of KDP. J. Cryst. Growth. 233, 730 (2001). https://doi.org/10.1016/S0022-248(01)01616-5
Naik, A.P., Salkar, A.V., Majik, M.S., Morajkar, P.P.: Enhanced photocatalytic degradation of Amaranth dye on mesoporous anatase TiO2: evidence of C–N, N=N bond cleavage and identification of new intermediates. Photochem. Photobiol. Sci. 16, 1126 (2017). https://doi.org/10.1039/C7PP00090A
Phan, V.T., Do, T.T.P., Ho, T.M., Nguyen, D.T., Le, B.V., Le, A.T.Q., Le, N.V., Huynh, D.T.: Some structural, linear and nonlinear optical characteristics of single KDP crystals infuenced by EDTA additive. Opt. Quant. Electron. 50, 429 (2018). https://doi.org/10.1007/s11082-018-1681-z
Pritula, I., Gayvoronsky, V., Gromov, Y., Kopylovsky, M., Kolybaeva, M., Puzikov, V., Kosinova, A., Savvin, Y., Velikhov, Y., Levchenko, A.: Linear and nonlinear optical properties of dye-doped KDP crystal: Effect of thermal treatment. Opt. Commun. 282, 1141 (2009). https://doi.org/10.1016/j.optcom.2008.11.043
Pritula, I.M., Kostenyukova, E.I., Bezkrovnaya, O.N., Kolybaeva, M.I., Sofronov, D.S., Dolzhenkova, E.F., Kanaev, A., Tsurikov, V.: KDP crystal doped with L-arginine amino acid: growth, structure perfect ion, optical and strength characteristics. Opt. Mater. 57, 217 (2016). https://doi.org/10.1016/j.optmat.2016.04.044
Rajesh, N.P., Meera, K., Srinivasan, K., Raghavan, P.S., Ramasamy, P.: Effect of EDTA on the metastable zone width of ADP. J. Cryst. Growth. 213, 389 (2000). https://doi.org/10.1016/S0022-0248(00)00374-2
Rajesh, P., Sreedhar, S., Boopathi, K., Rao, S. V., Ramasamy, P.: Enhancement of the crystalline perfection of < 001 > directed KDP single crystal. Curr. Appl. Phys. 11, 1343 (2011) https://doi.org/10.1016/j.cap.2011.03.076
Rak, M., Eremin, N.N., Eremina, T.A., Kuznetsov, V.A., Okhrimenko, T.M., Furmanova, N.G., Efremova, E.P.: On the mechanism of impurity influence on growth kinetics and surface morphology of KDP crystals—I: defect centres formed by bivalent and trivalent impurity ions incorporated in KDP structure—theoretical study. J. Cryst. Growth 273, 577 (2005). https://doi.org/10.1016/j.jcrysgro.2004.09.067
Ristau, D.: Laser-Induced Damage in Optical Materials. CRC Press, Taylor & Francis Group, Boca Raton (2015)
Snehalatha, M., Ravikumar, C., Sekar, N., Jayakumar, V.S., Joe, I.H.: FT-Raman, IR and UV-visible spectral investigations and ab initio computations of a nonlinear food dye amaranth. J. Raman Spectrosc. 39, 928 (2008). https://doi.org/10.1002/jrs.1938
Strukov, B., Shnaidshtein, I., Grabovsky, S.: Phase transitions in KDP crystals with the complex organic and inorganic impurities. Condens. Matter Phys. 10, 111 (2006). https://doi.org/10.5488/CMP.10.1.111
Subramony, J.A., Jang, S., Kahr, B.: Dyeing KDP. Ferroelectric 191, 293 (1997). https://doi.org/10.1080/00150199708015653
Sun, X., Xu, X., Gao, Z., Fu, Y., Wang, S., Zeng, H., Li, Y.: Effect of EDTA on the light scatter in KDP crystal. J. Cryst. Growth. 217, 404 (2000). https://doi.org/10.1016/S0022-0248(00)00527-3
Velikhov, Y., Pritula, I., Ganina, I., Kolybayeva, M., Puzikov, V., Levehenko, A.N.: Growth and properties of dyed KDP crystals. Cryst. Res. Technol. 42, 27 (2006). https://doi.org/10.1002/crat.200610765
Yariv, A., Yeh, P.: Optical Waves in Crystals: Propagation and Control of Laser Radiation. Wiley, Hoboken (1984)
Zhou, G., Li, G., Lü, Y., Ma, Y., Sun, X., Deng, X., Zhang, P., Lu, G., Wang, X.: Growth and characterization of L-phenylalanine doped KDP crystals. Mater. Res. Bull. 113, 146 (2019). https://doi.org/10.1016/j.materresbull.2019.02.001
Acknowledgements
The authors would like to thank all the staff of the Optics and Photonics Laboratory, Department of Applied Physics, Faculty of Physics-Engineering Physics, University of Science, Vietnam National University-Ho Chi Minh City for supporting the measurement and analysis in this paper.
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Phan, V.T., Do, T.T.P., Nguyen, D.T. et al. Growth, ultraviolet‐visible, vibrational, photoluminescence and second harmonic generation studies of Amaranth and EDTA co‐doped KDP crystals. Opt Quant Electron 53, 52 (2021). https://doi.org/10.1007/s11082-020-02677-y
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DOI: https://doi.org/10.1007/s11082-020-02677-y