Abstract
Increasing ambient carbon dioxide (CO2) concentration from anthropogenic greenhouse gas emission has contributed to the growing rate of global land and ocean surface temperature. Various carbon capture and storage (CCS) technologies were established to mitigate this impending issue. CO2 adsorption is gaining prominence since unlike traditional chemical absorption, it does not require high energy usage for solvent regeneration and consumption of corrosive chemical solvent. In CO2 adsorption, activated carbons show high CO2 adsorption capacity given their well-developed porous structures. Numerous researches employed oil palm wastes as low-cost precursors. This paper provides a comprehensive assessment of research works available thus far in oil palm-derived activated carbon (OPdAC) for CO2 adsorption application. First, we present the desired OPdAC characteristics and its precursors in terms of their chemical properties, elemental, and proximate compositions. This is followed by an overview of various activation methodologies and surface modification methods to attain the desired characteristics for CO2 adsorption. Then the focus turned to present available OPdAC CO2 adsorption performance and how it is affected by its physical and chemical characteristics. Based on these, we identify the challenges and the potential development in different aspects such as precursor selection, process development, and optimization of parameter. A pilot scale production cost analysis is also presented to compare various activation and surface modification methods, so that the appropriate method can be selected for CO2 adsorption.
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Change history
15 February 2021
A Correction to this paper has been published: https://doi.org/10.1007/s42823-021-00232-7
Abbreviations
- OPdAC:
-
Oil palm-derived activated carbon
- CO2 :
-
Carbon dioxide
- CCS:
-
Carbon capture and storage
- DAC:
-
Direct air capture
- CH4 :
-
Methane
- NH2COOH:
-
Carbamic acid
- MO:
-
Metal oxide
- NOx :
-
Nitrogen oxides
- SOx :
-
Sulfur oxides
- BET:
-
Brunauer–Emmett–Teller
- MF:
-
Mesocarp fibers
- PKS:
-
Palm kernel shells
- EFB:
-
Empty fruit bunches
- POME:
-
Palm oil mill effluent
- OPT:
-
Oil palm trunks
- OPL:
-
Oil palm leaves
- OPF:
-
Oil palm frond
- POS:
-
Palm oil sludge
- CHNS-O:
-
Carbon, hydrogen, nitrogen, sulfur, and oxygen
- N2 :
-
Nitrogen
- CO:
-
Carbon monoxide
- H2 :
-
Hydrogen
- SEM:
-
Scanning electron micrograph
- KOH:
-
Potassium hydroxide
- NaOH:
-
Sodium hydroxide
- K2CO3 :
-
Potassium carbonate
- H3PO4 :
-
Phosphoric acid
- H2SO4 :
-
Sulfuric acid
- ZnCl2 :
-
Zinc chloride
- K2O:
-
Potassium oxide
- H2O:
-
Water
- K:
-
Metallic potassium
- Na2CO3 :
-
Sodium carbonate
- PSAC:
-
Palm shell porous carbon
- PAC:
-
Physicochemically porous activated carbon
- NH3 :
-
Ammonia
- PEI:
-
Polyethyleneimine
- AMPD:
-
2-Amino-2-methyl-1,3-propanediol
- AMP:
-
2-Amino-2-methyl-1-propanol
- MMEA:
-
2-(Methylamino)ethanol
- MEA:
-
Mono-ethanolamine
- DEA:
-
Diethanolamine
- EDA:
-
Ethylenediamine
- DETA:
-
Diethylenetriamine
- NH2 :
-
Amino radical
- NH:
-
Imidogen radical
- HCN:
-
Hydrogen cyanide
- (CN)2 :
-
Cyanogen
- -CN:
-
Cyano radical
- GAC:
-
Granular palm kernel shell-based activated carbon
- MDEA:
-
Methyl diethanolamine
- TEPA:
-
Tetra ethylene pentamine
- PEHA:
-
Penta ethylene-hexamine
- Mg:
-
Magnesium
- Ca:
-
Calcium
- Cu:
-
Copper
- Co:
-
Cobalt
- Ni:
-
Nickel
- Fe:
-
Iron
- Cr:
-
Chromium
- HNO3 :
-
Nitric acid
- Cu2 + :
-
Cupric ion
- Zn2 + :
-
Zinc ion
- Ni(NO3)2·6H2O:
-
Nickel nitrate hexahydrate
- NH4VO3 :
-
Ammonium metavanadate
- Ce(NO3)3·6H2O:
-
Cerium nitrate
- Fe(NO3)3·9H2O:
-
Ferum nitrate
- MgO:
-
Magnesium oxide
- CuO:
-
Copper oxide
- CeO2 :
-
Cerium oxide
- TiO2 :
-
Titanium oxide
- BaO:
-
Barium oxide
- H2S:
-
Hydrogen sulphide
- TSA:
-
Temperature swing adsorption
- VSA:
-
Vacuum swing adsorption
- VTSA:
-
Vacuum and temperature swing adsorption
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Lai, J.Y., Ngu, L.H., Hashim, S.S. et al. Review of oil palm-derived activated carbon for CO2 capture. Carbon Lett. 31, 201–252 (2021). https://doi.org/10.1007/s42823-020-00206-1
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DOI: https://doi.org/10.1007/s42823-020-00206-1