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Licensed Unlicensed Requires Authentication Published by De Gruyter June 13, 2019

Progress and perspectives in high-purity substance production for semiconductor industry

  • Andrey V. Vorotyntsev

    Andrey V. Vorotyntsev graduated from Lobachevsky University (Russia) in 2004. He received his PhD in physical chemistry from N. Novgorod Technical University (NNSTU) in 2013. Currently, he is doing postdoctoral research on heterogeneous catalysis and its applications for the silicon chemistry at NNSTU. His research interests connect to disproportionation, hydrogenation and reduction reactions, methodologies of supported ionic liquids like phases and operando technique in heterogeneous catalysis.

    , Anton N. Petukhov

    Anton N. Petukhov received his PhD in physical chemistry from NNSTU in 2013. Currently, he is doing postdoctoral research on gas hydrates and their applications in the process of separation and purification at NNSTU. His research interests include obtaining high-purity substances by hybrid methods (adsorption, advanced gas hydrate and membrane technology), ionic liquids and their applications in separations and catalysts for the production of chlorosilanes.

    , Maxim M. Trubyanov

    Maxim M. Trubyanov is a senior researcher at NNSTU. He received his PhD in physical chemistry from NNSTU in 2014. His research interests include the development of hybrid distillation-membrane methods for separation and high purification of gases used in semiconductor industry, intensification of mass transfer processes, increasing the separation performance and reducing the energy consumption. He also has a solid experience in gas chromatographic trace impurity analysis of specialty gases.

    , Artem A. Atlaskin

    Artem A. Atlaskin is a PhD student at the Laboratory of Membrane and Catalytic Processes at Nanotechnology and Biotechnology Department, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, under the supervision of Prof. Ilya V. Vorotyntsev. His research interests include the development of hybrid membrane-based techniques for separation and high-purification of gases and intensification of membrane mass transfer processes.

    , Dmitriy A. Makarov

    Dmitriy A. Makarov graduated from Lobachevsky University (Russia) in 2017. Currently, he is a PhD student at Nizhniy Novgorod State Technical University n.a. R.E. Alekseev under the supervision of Prof. Vladimir M. Vorotyntsev. His research interests include dismutation of trichloro- and thiethoxysilane and operando FTIR studies of the catalytic processes.

    , Maria S. Sergeeva

    Maria S. Sergeeva is a PhD student at NNSTU under the supervision of Prof. Vladimir M. Vorotyntsev. Her research interests include gas separation by membrane-gas hydrate crystallization, gas hydrate film growth kinetics and the effect of adding thermodynamic and kinetic gas hydrate formation promoters on the rate and efficiency of the gas hydrates formation.

    , Ilya V. Vorotyntsev

    Ilya V. Vorotyntsev received his PhD in physical chemistry from Lobachevsky University (Russia). He spent several years in industry working on the product launch of ultra-high purity gases (incl. membrane gas separation approach) for semiconductors industry. In 2005, he joined NNSTU and in 2013 became a professor. From 2011 to 2013, his administrative duties in NNSTU included appointments as the Deputy Dean of Chemical Engineering Department. His research activity covers material science, membrane gas separation, hybrid and integrated process.

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    and Vladimir M. Vorotyntsev

    Vladimir M. Vorotyntsev graduated from Lobachevsky University (Russia) in 1970. He received his PhD in physical chemistry (under the supervision of Prof. Devyatykh). Currently, he is head of the Nanotechnology and Biotechnology Department of NNSTU. His research interests include high-purity substance production by disproportionation, hydrogenation and reduction reactions, methodologies of supported ionic liquid like phases and operando technique in heterogeneous catalysis.

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Abstract

In the last decade, novel approaches for post-synthesis processes of separation and high purification of gases are gaining larger acceptance in industry. The market is competing with consolidated operations such as cryogenic distillation. The key for new approaches of distillation, membranes and crystallization in challenging and harsh environments is the development of new tough, high-performance materials that are characterized by higher energy efficiency compared with conventional cryogenic distillation. This review highlights the most promising fields of research in high purification and separation of gases by considering the elevated pressure and thermal distillations, membrane cascades, purification in synthesis by use of catalytic technologies, crystallization and hydride methods based on them.

Award Identifier / Grant number: 18-19-00453

Funding statement: The study reported in this article was funded by the Russian Science Foundation, Funder Id: http://dx.doi.org/10.13039/501100006769 (project no. 18-19-00453 in part of membrane based hybrid processes, project no. 17-79-20286 in part crystallization methods, project no. 17-79-10464 in part of unsteady-state membrane separation and project no. 17-73-20275 in part of the catalytic technologies in semiconductor precursor production), the Russian Foundation of Basic Research (project no. 17-08-01053 in part of thermal distillation, project no. 16-38-60192 mol_a_dk in part of the silane production and project no. 16-38-60174 mol_a_dk in part of membrane based hybrid processes and MC concept for gases high purification) and the Grant of the President of the Russian Federation (MC-2924.2017.8) and in part of elevated pressure distillation and by the Ministry of Education and Science of the Russian Federation in the Framework of the Basic Part of the State Task (project no. 4.6535.2017/8.9).

About the authors

Andrey V. Vorotyntsev

Andrey V. Vorotyntsev graduated from Lobachevsky University (Russia) in 2004. He received his PhD in physical chemistry from N. Novgorod Technical University (NNSTU) in 2013. Currently, he is doing postdoctoral research on heterogeneous catalysis and its applications for the silicon chemistry at NNSTU. His research interests connect to disproportionation, hydrogenation and reduction reactions, methodologies of supported ionic liquids like phases and operando technique in heterogeneous catalysis.

Anton N. Petukhov

Anton N. Petukhov received his PhD in physical chemistry from NNSTU in 2013. Currently, he is doing postdoctoral research on gas hydrates and their applications in the process of separation and purification at NNSTU. His research interests include obtaining high-purity substances by hybrid methods (adsorption, advanced gas hydrate and membrane technology), ionic liquids and their applications in separations and catalysts for the production of chlorosilanes.

Maxim M. Trubyanov

Maxim M. Trubyanov is a senior researcher at NNSTU. He received his PhD in physical chemistry from NNSTU in 2014. His research interests include the development of hybrid distillation-membrane methods for separation and high purification of gases used in semiconductor industry, intensification of mass transfer processes, increasing the separation performance and reducing the energy consumption. He also has a solid experience in gas chromatographic trace impurity analysis of specialty gases.

Artem A. Atlaskin

Artem A. Atlaskin is a PhD student at the Laboratory of Membrane and Catalytic Processes at Nanotechnology and Biotechnology Department, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, under the supervision of Prof. Ilya V. Vorotyntsev. His research interests include the development of hybrid membrane-based techniques for separation and high-purification of gases and intensification of membrane mass transfer processes.

Dmitriy A. Makarov

Dmitriy A. Makarov graduated from Lobachevsky University (Russia) in 2017. Currently, he is a PhD student at Nizhniy Novgorod State Technical University n.a. R.E. Alekseev under the supervision of Prof. Vladimir M. Vorotyntsev. His research interests include dismutation of trichloro- and thiethoxysilane and operando FTIR studies of the catalytic processes.

Maria S. Sergeeva

Maria S. Sergeeva is a PhD student at NNSTU under the supervision of Prof. Vladimir M. Vorotyntsev. Her research interests include gas separation by membrane-gas hydrate crystallization, gas hydrate film growth kinetics and the effect of adding thermodynamic and kinetic gas hydrate formation promoters on the rate and efficiency of the gas hydrates formation.

Ilya V. Vorotyntsev

Ilya V. Vorotyntsev received his PhD in physical chemistry from Lobachevsky University (Russia). He spent several years in industry working on the product launch of ultra-high purity gases (incl. membrane gas separation approach) for semiconductors industry. In 2005, he joined NNSTU and in 2013 became a professor. From 2011 to 2013, his administrative duties in NNSTU included appointments as the Deputy Dean of Chemical Engineering Department. His research activity covers material science, membrane gas separation, hybrid and integrated process.

Vladimir M. Vorotyntsev

Vladimir M. Vorotyntsev graduated from Lobachevsky University (Russia) in 1970. He received his PhD in physical chemistry (under the supervision of Prof. Devyatykh). Currently, he is head of the Nanotechnology and Biotechnology Department of NNSTU. His research interests include high-purity substance production by disproportionation, hydrogenation and reduction reactions, methodologies of supported ionic liquid like phases and operando technique in heterogeneous catalysis.

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Received: 2018-07-16
Accepted: 2019-02-06
Published Online: 2019-06-13
Published in Print: 2021-01-27

© 2019 Walter de Gruyter GmbH, Berlin/Boston

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