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Two Cd(II) Complexes Based on Carboxylate and Bis(imidazolyl) Ligands: Syntheses, Crystal Structures and Luminescence Properties

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Abstract

Two new metal–organic coordination complexes, {[Cd8(tdc)8(bbi)8(H2O)8]·4DMF]}n (1) and {[Cd(cbba)2(m-bix)2]}n (2) (H2tdc = 2,5-thiophenedicarboxylic acid, bbi = 1,1′-(1,4-butanediyl)bis (imidazole), Hcbba = 2-(4-chlorobenzoyl)benzoic acid, m-bix = 1,3-bis((1H-imidazolyl)-methyl) benzene) were synthesized under hydrothermal conditions and characterized by techniques of single-crystal X-ray diffraction analysis, elemental analysis, powder X-ray diffraction and thermogravimetric analysis (TGA). Single-crystal structure analyses reveal that complex 1 displays a 3D 4-connected threefold interpenetrating framework with the point symbol of {42·84}. Complex 2 shows a 3D supramolecular architecture via intermolecular hydrogen bonds and intermolecular π⋯π stacking interactions. Furthermore, the luminescence of the two complexes was also studied.

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Acknowledgements

This work was financially supported by the Scientific Research Foundation for the Introduced Talents of Kunming University of Science and Technology (No. KKSY201507026), the Analysis Testing Fund of Kunming University of Science and Technology (No. 2019M20182111050), the Joint Fund of National Natural Science Foundation of China and Yunnan (Grant No. U1502273), and the State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming 650093 (Grant No. CNMRCUKF1606).

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Authors and Affiliations

  1. Faculty of Science, Kunming University of Science and Technology, Kunming, 650500, People’s Republic of China

    Qingqing Zhang, Yuqi Liu, Kaiming Wang, Nanhao Jin, Xinying Wang & Wei Li

  2. The State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming, 650093, People’s Republic of China

    Wei Li

  3. Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming, 650093, People’s Republic of China

    Wei Li

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  1. Qingqing Zhang
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Correspondence to Yuqi Liu or Wei Li.

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Supplementary Information

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10876_2020_1966_MOESM1_ESM.doc

Supplementary Information CCDC 1945473 and CCDC1983817 contain the supplementary crystallographic data for complexes. The data can be obtained free of charge via http://www.ccdc.cam.ac.uk/data_request/cif. (DOC 17140 kb)

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Zhang, Q., Liu, Y., Wang, K. et al. Two Cd(II) Complexes Based on Carboxylate and Bis(imidazolyl) Ligands: Syntheses, Crystal Structures and Luminescence Properties. J Clust Sci 33, 321–329 (2022). https://doi.org/10.1007/s10876-020-01966-6

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