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Research Progress on the Water Stability of a Metal-Organic Framework in Advanced Oxidation Processes

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Abstract

Metal-organic frameworks (MOFs) are a new class of organic-inorganic hybrid materials that are self-assembled metal clusters and organic ligands. Because MOFs have an ultrahigh surface area, a controllable size, and adjustable chemical properties, which are not available in other porous materials, it has broad application potential in chemical sensing, gas storage, and catalysis. However, the stability of MOFs in water is poor. The presence of water molecules changes the structures and properties of MOFs, which limits their industrial application in advanced oxidation process. In this paper, the definition of water stability is introduced in detail, and the damage mechanism of water molecules on MOFs is analyzed from the perspective of thermodynamic stability and kinetic stability. According to varying factors that affect MOFs’ water stability, corresponding methods to improve MOFs water stability are proposed, and research trends on the stability of MOFs in water are speculated.

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Abbreviations

aIM:

2-carbaldehyde imidazolate

Al-MIL-101:

Cr3F(H2O)2O(BDC)3

BDC:

1,4-benzenedicarboxylate

BET:

Brunauer-Emmett-Teller

BOD5 :

biochemical oxygen demand

BPTC:

biphenyl-3,3′,5,5′-tetracarboxylate

BTB:

4,4′,4′′-benzene-1,3,5-triyltribenzoate

BTC:

1,3,5-benzenetricarboxylate

BTDD:

(bis(1H-1,2,3-triazolo[4,5-b],[4′,5′-i])dibenzo[1,4] dioxin)

COD:

chemical oxygen demand

DABCO:

4-diazabicyclo[2.2.2]-octane

DMF:

2,5-dimercapto-1,4-benzenedicarboxylate

DMOF:

Zn(BDC)(DABCO)0.5

DOBDC:

2,5-dihydroxyterephthalate

DOT:

2,5-dihydroxyterephthalic

DTTDC:

dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylic

DUT-67:

Zr6O6(OH)2(TDC)4(CH3COO)2

eIM:

2-ethyleimidazolate

MIL:

Materials Institute Lavoisier

MIL-53:

M(OH)(BDC)

MIL-47-V:

V(O)(BDC)

MIL-140:

ZrO(BDC)

MIL-88:

Fe3O(OH)(H2O)2(BDC)3

MIL-100(Fe):

[Fe3O(H2O)2(L)](BTC)2

MIL-101:

[M3OL3](BDC)3

IR:

infrared absorption spectrum

IRMOF-1:

M4O(BDC)3

IRMOF-3:

Zn4O(NH2-BDC)3

MAF-6:

RHO-Zn(eIM)2

mIM:

2-methyl-1H-imidazole

MOF-5:

Zn4O(BDC)3

MOF-2:

Zn2(BDC)2(H2O)2

MOF-69C:

Zn3(OH)2(BDC)2

MOF-74:

M2(DOT)

MOF-177:

Zn4O(BTB)2

MOF-505:

[Cu2(bptc)(H2O)2(dmf)3(H2O)]

MOF-508b:

Zn(BDC)(bipy)0.5

PCN-61:

Cu3(H2O)3(BTEI)

PCN-134:

Zr6O4(OH)4(TCPP-H2)3

PCN-225:

Zr6O4(OH)4(TCPP-H2)2(H2O)4(OH)4

PCN-601:

Ni8(OH)4(H2O)2TPP12

PXRD:

powder X-ray diffraction

TDC:

thiophene-2,5-dicarboxylic

TPTC:

terphenyl-3,3′,5,5′-tetracarboxylaic

ZIF-7:

Zn(BIM)2

ZIF-8:

Zn(mIM)2

ZIF-90:

Zn(aIM)2

ZIF-67:

Co(Hmim)2

Zn-MOF-74:

Zn2(DOBDC)

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Funding

The study was financially supported by the Petro China Innovation Foundation (No. 2016D-5007-0604), the Heilongjiang Province Natural Science Fund (No. B2015012), and the Applied Technology Research and Development Project of Heilongjiang Province (No. GC13C305).

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Authors and Affiliations

  1. School of Civil Architecture Engineering, Northeast Petroleum University, Daqing, 163318, China

    Zhongchen Yu, Xiaoling Cao, Hongmei Cui & Chenxi Li

  2. School of Earth Science, Northeast Petroleum University, Daqing, 163318, China

    Song Wang & Genwang Zhu

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  1. Zhongchen Yu
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Correspondence to Song Wang.

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Yu, Z., Cao, X., Wang, S. et al. Research Progress on the Water Stability of a Metal-Organic Framework in Advanced Oxidation Processes. Water Air Soil Pollut 232, 18 (2021). https://doi.org/10.1007/s11270-020-04953-9

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