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Synthesis, characterization and Hirshfeld surface analysis of a mixed-ligand copper (II) coordination polymer from 1,4,8,11-tetraazacyclotetradecane and pyromellitic dianhydride

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Abstract

One pot synthesis of a new mixed-ligand coordination polymer has been carried out by combining copper salt, macrocyclic ligand 1,4,8,11-tetraazacyclotetradecane (cyclam) and benzene-1,2,4,5-tetracarboxylic dianhydride (pyromellitic dianhydride, PMDA). The molecular composition of the synthesized complex was found to be [Cu(H2btca)2(H2O)2Cu(cyclam)]·H2O [H2btca = 1,2,4,5-benzene tetracarboxylic dianion]. The complex has been characterized by physicochemical and spectroscopic methods. Its crystallographic analysis shows two different types of Cu(II) atoms (Cu1 and Cu2) in octahedral environments. In the structure, the coordination of bidentate H2btca2− dianion with Cu1 atoms in 1,4-COO− position forms a two-dimensional (2D) sheet, while the O(µ2)-axial atoms of water ligands coordinated to [Cu(cyclam)]2+ units with long Cu2-Ow bond indicates a Jahn–Teller distortion effect producing a three-dimensional (3D) network. Using the same combination of ligands (cyclam and PMDA) with nickel salt led to an already reported one dimensional (1D) polymer, viz. {[Ni(cyclam)H2btca]·2H2O}n. Hirshfeld surface analysis on H2btca2− dianion along with 2D fingerprint plots was carried out in order to have an in-depth understanding of the intermolecular interactions in the crystal system.

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Crystallographic data (including structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Center. CCDC 1985181 contain the supplementary crystallographic data. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, of by email data_request@ccdc.cam.ac.uk, or by contacting The Cambridge Crystallographic Data Center, 12 Union Road Cambridge CB2 1EZ, UK; fax: +44 1223 336033.

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Acknowledgements

We are grateful to the Natural Sciences and Engineering Research Council of Canada (RGPIN-2015-06425), the Fonds de Recherche du Québec – Nature et Technologie, the Canada Foundation for Innovation, the Canadian Queen Elizabeth II Diamond Jubilee Scholarships, Mitacs and the Université du Québec à Trois-Rivières for financial supports.

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The authors have mentioned all the funding agencies associated with this research in the acknowledgement section.

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Authors and Affiliations

  1. Département de Chimie, Biochimie et physique and Institut de Recherche sur l’Hydrogène, Université du Québec à Trois-Rivières, Trois-Rivières, Québec, G9A 5H7, Canada

    Nour Dissem, Prabhjyot Kaur, Love Karan Rana & Adam Duong

  2. Département de Chimie, Université de Montréal, Montréal, Québec, H3C 3J7, Canada

    Thierry Maris

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  1. Nour Dissem
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Correspondence to Adam Duong.

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Supplementary material

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11243_2020_444_MOESM1_ESM.pdf

Supporting Information. IR spectra of 1, cyclam and PMDA. TGA/DTA curves of 1. Crystallographic Tables of 1 (PDF 504 kb)

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Dissem, N., Kaur, P., Rana, L.K. et al. Synthesis, characterization and Hirshfeld surface analysis of a mixed-ligand copper (II) coordination polymer from 1,4,8,11-tetraazacyclotetradecane and pyromellitic dianhydride. Transit Met Chem 46, 283–290 (2021). https://doi.org/10.1007/s11243-020-00444-2

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