Abstract
Conducting polymers (CPs), by virtue of their important properties, like ready availability, easy processing, cost effectiveness, ease of functionalization and derivatization, and excellent electrical, optical, electrochemical and photochemical properties, have gained such enormous attention in the last few decades that they have found extensive employment in a wide variety of real-life applications, including bioimaging, tissue engineering, sensors, energy storage devices and optoelectronic devices. The most widely studied CPs are polyaniline, polythiophene, polypyrrole, poly(3,4-ethylenedioxythiophene) and polyacetylene. On the other hand, the CP poly(p-phenylene vinylene) (PPV) has attracted relatively much lesser attention over the years, in spite of it possessing several extraordinary attributes, like tuneable optical properties, good reactivity and high electrical conductivity. These properties can be achieved by merely changing the side chains attached to the main polymer backbone. Research on development of PPV has been going on for nearly about three decades; and it has been able to find some important applications in certain crucial fields, as mentioned below. Keeping this in mind, this review aims at focusing entirely on PPV, with the objective of bringing out its several positive attributes. The objective of this review is to analyze the potential of PPV towards getting involved in a number of practically important applications. For this purpose, discussions have been made on the major routes to synthesize PPV and its exciting properties (viz. electroluminescence and photoluminescence). In terms of applications, its involvements in light-emitting diodes, solar cells, sensors, bioimaging, field-effect transistors, supercapacitors, and actuators have been presented.
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Abbas NK, Ibrahim IM, Saleh MA (2018) Characteristics of MEH-PPV/Si and MEH-PPV/PS heterojunctions as NO2 gas sensors. Silicon 10:1345–1350. https://doi.org/10.1007/s12633-017-9610-5
Alam S, Meitzner R, Nwadiaru OV, Friebe C, Cann J, Ahner J, Ulbricht C, Kan Z, Höppener S, Hager MD, Egbe DAM, Welch GC, Laquai F, Schubert US, Hoppe H (2018) Organic solar cells based on anthracene-containing PPE-PPVs and non-fullerene acceptors. Chem Pap 72:1769–1778. https://doi.org/10.1007/s11696-018-0466-y
Almassio M, Garay RO (2000) Polymerization mechanism of α, αʹ-bis(tetrahydrothiophenio)-β-xylene dichloride. Molecules 5:596–597. https://doi.org/10.3390/50300596
Baek P, Kerr-Phillips T, Damavandi M, Chaudhary OJ, Malmstrom J, Chan EWC, Shaw P, Burn P, Barker D, Travas-Sejdic J (2016) Highly processable, rubbery poly(n-butyl acrylate) grafted poly(phenylene vinylene)s. Eur Polym J 84:355–365. https://doi.org/10.1016/j.eurpolymj.2016.09.041
Becker H, Spreitzer H, Ibrom K, Kreuder W (1999) New insights into the microstructure of GILCH-polymerized PPVs. Macromolecules 32:4925–4932. https://doi.org/10.1021/ma990347q
Benzarti-Ghédira M, Hrichi H, Jaballah N, Chaâbane RB, Majdoub M, Ouada HB (2012) Investigation of the electrical properties of a new PPV derivative-based on a sandwich structure for opto-electronic applications. Phys B: Condens Matter 407:1051–1054. https://doi.org/10.1016/j.physb.2011.11.032
Benzarti-Ghédira M, Zahou I, Hrichi H, Jaballah N, Chaâbane RB, Majdoub M, Ouada HB (2015a) Effect of the spacer group nature on the optical and electrical properties of confined poly(p-phenylene vinylene) derivatives. Appl Phys A 120:897–908. https://doi.org/10.1007/s00339-015-9218-9
Benzarti-Ghédira M, Hrichi H, Jaballah N, Chaâbane RB, Majdoub M, Ouada HB (2015b) Effect of the side-chain size on the optical and electrical properties of confined-PPV derivatives. Superlattices Microstruct 85:469–481. https://doi.org/10.1016/j.spmi.2015.05.006
Berggren M, Crispin X, Fabiano S, Jonsson MP, Simon DT, Stavrinidou E, Tybrandt K, Zozoulenko I (2019) Ion electron-coupled functionality in materials and devices based on conjugated polymers. Adv Mater 31:1805813. https://doi.org/10.1002/adma.201805813
Bhat D, Jena S, Babusenan A, Bhattacharyya J, Ray D (2019) Organic field effect transistors (OFETs) of poly(p-phenylenevinylene) fabricated by chemical vapor deposition (CVD) with improved hole mobility. Synth Met 255:116108. https://doi.org/10.1016/j.synthmet.2019.116108
Blayney AJ, Perepichka IF, Wudl F, Perepichka DF (2014) Advances and challenges in the synthesis of poly(p-phenylene vinylene)-based polymers. Isr J Chem 54:674–688. https://doi.org/10.1002/ijch.201400067
Borah R, Ingavle GC, Sandeman SR, Kumar A, Mikhalovsky S (2018) Electrically conductive MEH-PPV:PCL electrospun nanofibers for electrical stimulation of rat PC12 pheochromocytoma cells. Biomater Sci 6:2342–2359. https://doi.org/10.1039/C8BM00559A
Breeze AJ, Schlesinger Z, Carter SA, Brock PJ (2001) Charge transport in TiO2/MEH-PPV polymer photovoltaics. Phys Rev B 64:125205. https://doi.org/10.1103/PhysRevB.64.125205
Burroughes JH, Bradley DDC, Brown AR, Marks RN, Mackay K, Friend RH, Burns PL, Holmes AB (1990) Light-emitting diodes based on conjugated polymers. Nature 347:539–541. https://doi.org/10.1038/347539a0
Byler DM, Patel Y, Arbuckle-Keil GA (2011) An IR study of poly-1,4-phenylenevinylene (PPV), the 2,5-dimethoxy derivative [(MeO)2-PPV], and their corresponding xanthate precursor polymers and monomers. Spectrochim Acta Part A: Mol Biomol Spectrosc 79:118–126. https://doi.org/10.1016/j.saa.2011.02.021
Chen H-W, Huang T-Y, Chang T-H, Sanehira Y, Kung C-W, Chu C-W, Ikegami M, Miyasaka T, Ho K-C (2016) Efficiency enhancement of hybrid perovskite solar cells with MEH-PPV hole-transporting layers. Sci Rep 6:34319. https://doi.org/10.1038/srep34319
Chou H-L, Lin K-F, Wang D-C (2006) Miscibility and luminescence properties of MEH-PPV/DPO-PPV polyblends. J Polym Res 13:79–84. https://doi.org/10.1007/s10965-005-9017-7
Chouk R, Bergaoui M, Jaballah N, Majdoub M, Khalfaoui M (2019) Shedding light on structural, optoelectronic and charge transport properties of PPV stereoisomers for multilayer OLED application: a first principle computational studies. J Mol Liq 284:193–202. https://doi.org/10.1016/j.molliq.2019.03.154
Cosemans I, Vandenbergh J, Voet VSD, Loos K, Lutsen L, Vanderzande D, Junkers T (2013) Anionic PPV polymerization from the sulfinyl precursor route: block copolymer formation from sequential addition of monomers. Polymer 54:1298–1304. https://doi.org/10.1016/j.polymer.2012.12.070
Damavandi M, Pilkington LI, Whitehead KA, Wilson-Nieuwenhuis J, McBrearty J, Dempsey-Hibbert N, Travis-Sejdic J, Barker D (2018) Poly(para-phenylene ethynylene) (PPE)- and poly(para-phenylene vinylene) (PPV)-poly[(2-(methacryloyloxy)ethyl) trimethylammonium chloride] (PMETAC) graft copolymers exhibit selective antimicrobial activity. Eur Polym J 98:368–374. https://doi.org/10.1016/j.eurpolymj.2017.11.044
Davenas J, Chouiki M, Besbes S, Ltaief A, Ouada HB, Bouazizi A, Trad H, Majdoub M (2003) Influence of the molecular structure on the optical absorption and emission of PPV derivatives. Synth Met 139:617–620. https://doi.org/10.1016/S0379-6779(03)00266-2
Derakhshankhah H, Mohammad-Rezaei R, Massoumi B, Abbasian M, Rezaei A, Samadian H, Jaymand M (2020) Conducting polymer-based electrically conductive adhesive materials: Design, fabrication, properties, and applications. J Mater Sci: Mater Electron 31:10947–10961. https://doi.org/10.1007/s10854-020-03712-0
Friend RH, Gymer RW, Holmes AB, Burroughes JH, Marks RN, Taliani C, Bradley DDC, Dos Santos DA, Brédas JL, Lögdlund M, Salaneck WR (1999) Electroluminescence in conjugated polymers. Nature 397:121–128. https://doi.org/10.1038/16393
Geens W, Shaheen SE, Wessling B, Brabec CJ, Poortmans J, Sariciftci NS (2002) Dependence of field-effect hole mobility of PPV-based polymer films on the spin-casting solvent. Org Electron: Phys Mater App 3:105–110. https://doi.org/10.1016/S1566-1199(02)00039-3
Gilch HG, Wheelwright WL (1966) Polymerization of α-halogenated p-xylenes with base. J Polym Sci Part A-1 Polym Chem 4:1337–1349. https://doi.org/10.1002/pol.1966.150040602
Granier T, Thomas EL, Gagnon DR, Karasz FE, Lenz RW (1986) Structure investigation of poly(p-phenylene vinylene). J Polym Sci, Part B: Polym Phys 24:2793–2804. https://doi.org/10.1002/polb.1986.090241214
Greenham NC, Moratti SC, Bradley DDC, Friend RH, Holmes AB (1993) Efficient light-emitting diodes based on polymers with high electron affinities. Nature 365:628–630. https://doi.org/10.1038/365628a0
Gündüz B (2015) Optical properties of poly[2-methoxy-5-(3ʹ,7ʹ-dimethyloctyloxy)-1,4-phenylenevinylene] light-emitting polymer solutions: effects of molarities and solvents. Polym Bull 72:3241–3267. https://doi.org/10.1007/s00289-015-1464-7
Holmes AB, Bradley DDC, Brown AR, Burn PL, Burroughes JH, Friend RH, Greenham NC, Gymer RW, Halliday DA, Jackson RW, Kraft A, Martens JHF, Pichler K, Samuel IDW (1993) Photoluminescence and electroluminescence in conjugated polymeric systems. Synth Met 57:4031–4040. https://doi.org/10.1016/0379-6779(93)90553-9
Hörhold H-H, Helbig M (1987) Poly(phenylenevinylene)s—synthesis and redoxchemistry of electroactive polymers. Makromol Chem, Macromol Symp 12:229–258. https://doi.org/10.1002/masy.19870120112
Hou X, He J (2015) Polymerization of bifunctional dithioester and the conversion into poly(p-phenylene vinylene)s. Eur Polym J 70:157–165. https://doi.org/10.1016/j.eurpolymj.2015.07.012
Hussain SQ, Kim S, Ahn S, Balaji N, Lee Y, Lee JH, Yi J (2014) Influence of high work function ITO: Zr films for the barrier height modification in a-Si:H/c-Si heterojunction solar cells. Sol Energy Mater Sol Cells 122:130–135. https://doi.org/10.1016/j.solmat.2013.11.031
Ibrahim IM, Khalid AH, Wahid MHA (2018) Enhancement of MEH-PPV:CNT for H2S gas sensor. J Phys: Conf Ser 1032:012003. https://doi.org/10.1088/1742-6596/1032/1/012003
Inigo AR, Huang YF, White JD, Huang YS, Fann WS, Peng KY, Chen SA (2010) Review of morphology dependent charge carrier mobility in MEH-PPV. J Chin Chem Soc 57:459–468. https://doi.org/10.1002/jccs.201000068
Jaballah N, Chemli M, Hriz K, Fave J-L, Jouini M, Majdoub M (2011) Blue-luminescent poly(p-phenylenevinylene) derivatives: synthesis and effect of side-group size on the optical properties. Eur Polym J 47:78–87. https://doi.org/10.1016/j.eurpolymj.2010.10.017
Janata J, Josowicz M (2003) Conducting polymers in electronic chemical sensors. Nat Mater 2:19–24. https://doi.org/10.1038/nmat768
Jemmeli D, Belhaj M, Salem BB, Jaballah N, Yatskiv R, Dridi C, Grym J, Majdoub M (2018) PPV derivative/ZnO nanorods heterojunction: fabrication, characterization and near-UV light sensor development. Mater Res Bull 106:28–34. https://doi.org/10.1016/j.materresbull.2018.05.017
Junkers T, Vandenbergh J, Adriaensens P, Lutsen L, Vanderzande D (2012) Synthesis of poly(p-phenylene vinylene) materials via the precursor routes. Polym Chem 3:275–285. https://doi.org/10.1039/C1PY00345C
Kenry LB (2018b) Recent advances in biodegradable conducting polymers and their biomedical applications. Biomacromol 19:1783–1803. https://doi.org/10.1021/acs.biomac.8b00275
Kenry LB (2018a) Conductive polymer-based functional structures for neural therapeutic applications. In: Liu B (ed) Conjugated polymers for biological and biomedical applications, 1st edn. Wiley-VCH Verlag GmbH & Co KGaA, New York, pp 243–267. https://doi.org/10.1002/9783527342747.ch9
Kraft A, Grimsdale AC, Holmes AB (1998) Electroluminescent conjugated polymers—Seeing polymers in a new light. Angew Chem Int Ed 37:402–428. https://doi.org/10.1002/(SICI)1521-3773(19980302)37:4%3c402::AID-ANIE402%3e3.0.CO;2-9
Kumar S, Nann T (2004) First solar cells based on CdTe nanoparticle/MEH-PPV composites. J Mater Res 19:1990–1994. https://doi.org/10.1557/JMR.2004.0279
Li X-C, Spencer GCW, Holmes AB, Moratti SC, Cacialli F, Friend RH (1996) The synthesis, optical and charge transport properties of poly(aromatic oxadiazole)s. Synth Met 76:153–156. https://doi.org/10.1016/0379-6779(95)03441-L
Li S, Yuan H, Chen H, Wang X, Zhang P, Lv F, Liu L, Wang S (2016) Cationic poly(p-phenylene vinylene) materials as a multifunctional platform for light-enhanced SiRNA delivery. Chem Asian J 11:2686–2689. https://doi.org/10.1002/asia.201600447
Lorenz T, Crumbach M, Eckert T, Lik A, Helten H (2017) Poly(p-phenylene iminoborane): a boron-nitrogen analogue of poly(p-phenylene vinylene). Angew Chem Int Ed 56:2780–2784. https://doi.org/10.1002/anie.201612476
Louwet F, Vanderzande D, Gelan J, Mullens J (1995) A new synthetic route to a soluble high molecular weight precursor for poly(p-phenylenevinylene) derivatives. Macromolecules 28:1330–1331. https://doi.org/10.1021/ma00108a079
Magu TO, Agobi AU, Hitler L, Dass PM (2019) A review on conducting polymers-based composites for energy storage application. J Chem Rev 1:19–34. https://doi.org/10.33945/sami/jcr.2019.1.1934
Meier M, Cölle M, Karg S, Buchwald E, Gmeiner J, Riess W, Schwoerer M (1996) Metal/insulator/polymer—LEDs based on PPV. Mole Cryst Liq Cryst Sci Technol. Sect A Mol Cryst Liq Cryst 283:197–202. https://doi.org/10.1080/10587259608037886
Mustapha N, Fekkai Z, Alkaoud A (2016) Enhanced efficiency of organic solar cells based on (MEH-PPV) with graphene and quantum dots. Optik 127:2755–2760. https://doi.org/10.1016/j.ijleo.2015.11.218
Nezakati T, Seifalian A, Tan A, Seifalian AM (2018) Conductive polymers: opportunities and challenges in biomedical applications. Chem Rev 118:6766–6843. https://doi.org/10.1021/acs.chemrev.6b00275
Ni B, Chen H, Zhang M, Keller P, Tatoulian M, Li M-H (2019) Thermo-mechanical and photo-luminescence properties of micro-actuators made of liquid crystal elastomers with cyano-oligo(p-phenylene vinylene) crosslinking bridges. Mater Chem Front 3:2499–2506. https://doi.org/10.1039/c9qm00480g
Nie L, Xu J, Luo X, Chen H, Chang S, Wang T, Liu G (2019) Study of aramid and carbon fibers on the tensile properties of early strength cement mortar. IOP Conf Ser: Earth Environ Sci 267:032009. https://doi.org/10.1088/1755-1315/267/3/032009
Nikolić JD, Wouters S, Romanova J, Shimizu A, Champagne B, Junkers T, Vanderzande D, Neck DV, Waroquier M, Speybroeck VV, Catak S (2015) PPV polymerization through the Gilch route: Diradical character of monomers. Chem Eur J 21:19176–19185. https://doi.org/10.1002/chem.201501900
Nimith KM, Satyanarayan MN, Umesh G (2018) Enhancement in fluorescence quantum yield of MEH-PPV:BT blends for polymer light emitting diode applications. Opt Mater 80:143–148. https://doi.org/10.1016/j.optmat.2018.04.046
Nishioka H, Tsuji H, Nakamura E (2018) Homo- and copolymers based on carbon-bridged oligo(p-phenylenevinylene)s for efficient fluorescence over the entire visible region. Macromolecules 51:2961–2968. https://doi.org/10.1021/acs.macromol.8b00102
Ohsawa M, Hashimoto N, Takeda N, Tsuneyasu S, Satoh T (2020) Flexible powder electroluminescent device on transparent electrode of printed invisible silver-grid laminated with conductive polymer. Flex Print Electron 5:025004. https://doi.org/10.1088/2058-8585/ab8ab8
Olsen BD, Alcazar D, Krikorian V, Toney MF, Thomas EL, Segalman RA (2008) Crystalline structure in thin films of DEH-PPV homopolymer and PPV-b-PI rod-coil block copolymers. Macromolecules 41:58–66. https://doi.org/10.1021/ma0714971
Papadimitrakopoulos F, Konstadinidis K, Miller TM, Opila R, Chandross EA, Galvin ME (1994) The role of carbonyl groups in the photoluminescence of poly(p-phenylenevinylene). Chem Mater 6:1563–1568. https://doi.org/10.1021/cm00045a014
Pichler K, Jarrett CP, Friend RH, Ratier B, Moliton A (1995) Field-effect transistors based on poly(p-phenylene vinylene) doped by ion implantation. J Appl Phys 77:3523–3527. https://doi.org/10.1063/1.358647
Rakstys K, Stephen M, Saghaei J, Jin H, Gao M, Zhang G, Hutchinson K, Chesman A, Burn PL, Gentle I, Shaw PE (2020) Precursor route poly(1,4-phenylenevinylene)-based interlayers for perovskite solar cells. ACS Appl Energy Mater 3:889–899. https://doi.org/10.1021/acsaem.9b01997
Rimmele M, Ableidinger K, Marsh AV, Cheetham NJ, Taublaender MJ, Buchner A, Prinz J, Fröhlich J, Unterlass MM, Heeney M, Glöcklhofer F (2019) Thioalkyl- and sulfone-substituted poly(p-phenylene vinylene)s. Polym Chem 10:738–750. https://doi.org/10.1039/C8PY01717D
Rispens MT, Meetsma A, Rittberger R, Brabec CJ, Sariciftci NS, Hummelen JC (2003) Influence of the solvent on the crystal structure of PCBM and the efficiency of MDMO-PPV:PCBM ‘plastic’ solar cells. Chem Commun. https://doi.org/10.1039/b305988j
Roex H, Adriaensens P, Vanderzande D, Gelan J (2003) Identification and quantification of polymerization defects in 13C-labeled sulfinyl and Gilch OC1C10-PPV by NMR spectroscopy. Macromolecules 36:5613–5622. https://doi.org/10.1021/ma030025t
Sarnecki GJ, Burn PL, Kraft A, Friend RH, Holmes AB (1993) The synthesis and characterisation of some poly(2,5-dialkoxy-1,4-phenylene vinylene)s. Synth Met 55:914–917. https://doi.org/10.1016/0379-6779(93)90174-U
Schönbein A-K, Wagner M, Blom PWM, Michels JJ (2017) Quantifying the kinetics of the Gilch polymerization toward alkoxy-substituted poly(p-phenylene vinylene). Macromolecules 50:4952–4961. https://doi.org/10.1021/acs.macromol.7b00697
Schubert S, Klumbies H, Müller-Meskamp L, Leo K (2011) Electrical calcium test for moisture barrier evaluation for organic devices. Rev Sci Instrum 82:094101. https://doi.org/10.1063/1.3633956
Shirakawa H, Louis EJ, MacDiarmid AG, Chiang CK, Heeger AJ (1977) Synthesis of electrically conducting organic polymers: Halogen derivatives of polyacetylene (CH)x. J Chem Soc, Chem Commun. https://doi.org/10.1039/C39770000578
Soares CG, Caseli L, Bertuzzi DL, Santos FS, Garcia JR, Péres LO (2015) Ultrathin films of poly(2,5-dicyano-p-phenylene-vinylene)-co-(p-phenylene-vinylene) DCN-PPV/PPV: a Langmuir and Langmuir-Blodgett films study. Colloids Surf A: Physicochem Eng Aspects 467:201–206. https://doi.org/10.1016/j.colsurfa.2014.11.033
Son S, Dodabalapur A, Lovinger AJ, Galvin ME (1995) Luminescence enhancement by the introduction of disorder into poly(p-phenylene vinylene). Science 269:376–378. https://doi.org/10.1126/science.269.5222.376
Sreeram A, Patel NG, Venkatanarayanan RI, McLaughlin JB, DeLuca SJ, Yuya PA, Krishnan S (2014) Nanomechanical properties of poly(para-phenylene vinylene) determined using quasi-static and dynamic nanoindentation. Polym Test 37:86–93. https://doi.org/10.1016/j.polymertesting.2014.04.012
Srinivas ARG, Kerr-Phillips TE, Peng H, Barker D, Travas-Sejdic J (2013) Water-soluble anionic poly(p-phenylene vinylenes) with high luminescence. Polym Chem 4:2506–2514. https://doi.org/10.1039/C3PY21090A
Steenberge PHMV, Vandenbergh J, Dhooge DR, Reyniers M-F, Adriaensens PJ, Lutsen L, Vanderzande DJM, Marin GB (2011) Kinetic Monte Carlo modeling of the sulfinyl precursor route for poly(p-phenylene vinylene) synthesis. Macromolecules 44:8716–8726. https://doi.org/10.1021/ma201617r
Sun BJ, Miao Y-J, Bazan GC, Conwell EM (1996) Luminescent behavior of soluble poly(para-phenylene vinylene) copolymers. Chem Phys Lett 260:186–190. https://doi.org/10.1016/0009-2614(96)00907-4
Trad H, Majdoub M, Davenas J (2006b) Soluble PPVs with few structural defects: synthesis and characterization. Mater Sci Eng C 26:334–339. https://doi.org/10.1016/j.msec.2005.10.041
Trad H, Ltaief A, Majdoub M, Bouazizi A, Davenas J (2006a) Effect of the side chain length on the optical and electrical properties of soluble PPV derivatives. Mater Sci Eng C 26:340–343. https://doi.org/10.1016/j.msec.2005.10.075
Vandenbergh J, Dergent J, Conings B, Krishna TVVG, Maes W, Cleij TJ, Lutsen L, Manca J, Vanderzande DJM (2011) Synthesis and characterization of water-soluble poly(p-phenylene vinylene) derivatives via the dithiocarbamate precursor route. Eur Polym J 47:1827–1835. https://doi.org/10.1016/j.eurpolymj.2011.06.014
Vaschetto ME, Monkman AP, Springborg M (1999) First-principles studies of some conducting polymers: PPP, PPy, PPV, PPyV, and PANI. J Mol Struct: THEOCHEM 468:181–191. https://doi.org/10.1016/S0166-1280(98)00565-X
Vilbrandt N, Gassmann A, von Seggern H, Rehahn M (2016) Blue-greenish electroluminescent poly(p-phenylenevinylene) developed for organic light-emitting diode applications. Macromolecules 49:1674–1680. https://doi.org/10.1021/acs.macromol.5b01249
Wang H-L, Wen T-C (2003) Blending polyurethane ionomer with poly(p-phenylene vinylene) for light-emitting electrochemical cells. Mater Chem Phys 82:341–346. https://doi.org/10.1016/S0254-0584(03)00141-X
Wee B-H, Hong J-D (2014) Multilayered poly(p-phenylenevinylene)/reduced graphene oxide film: an efficient organic current collector in an all-plastic supercapacitor. Langmuir 30:5267–5275. https://doi.org/10.1021/la500636m
Xie G, Lv X, Zhang P, Liu B, Gao L, Duan J, Ma B, Wu Z (2020) Uncontactless detection of improvised explosives TATP realized by Au NCs tailored PPV flexible photoelectric Schottky sensor. Nanoselect 1:419–431. https://doi.org/10.1002/nano.202000044
Young CA, Hammack A, Lee HJ, Jia H, Yu T, Marquez MD, Jamison AC, Gnade BE, Lee TR (2019) Poly(1,4-phenylene vinylene) derivatives with ether substituents to improve polymer solubility for use in organic light-emitting diode devices. ACS Omega 4:22332–22344. https://doi.org/10.1021/acsomega.9b02396
Zaquen N, Baeten E, Vandenbergh J, Lutsen L, Vanderzande D, Junkers T (2015) Continuous synthesis and thermal elimination of sulfinyl-route poly(p-phenylene vinylene) in consecutive flow reactions. Chem Eng Technol 38:1749–1757. https://doi.org/10.1002/ceat.201400754
Zaquen N, Lutsen L, Vanderzande D, Junkers T (2016) Controlled/living polymerization towards functional poly(p-phenylene vinylene) materials. Polym Chem 7:1355–1367. https://doi.org/10.1039/c5py01987g
Zhang TX, Wang LG, Zhu JJ, Liu JY, Guo SJ (2019) Electron transport and electrical properties in poly(p-phenylene vinylene):methanofullerene bulk-heterojunction solar cells. J Nanoelectron Optoelectron 14:227–231. https://doi.org/10.1166/jno.2019.2479
Zrida H, Hriz K, Jaballah N, Kreher D, Majdoub M (2016) Synthesis and study of morphological, optical and electrical properties of new organic semi conducting polymers containing isosorbide pendant group. Synth Met 221:227–235. https://doi.org/10.1016/j.synthmet.2016.09.010
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JB acknowledges CSIR for the Research Associateship (Grant No. 09/092(1012)/2019-EMR-I, Dated: 31/03/2019).
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Banerjee, J., Dutta, K. A short overview on the synthesis, properties and major applications of poly(p-phenylene vinylene). Chem. Pap. 75, 5139–5151 (2021). https://doi.org/10.1007/s11696-020-01492-9
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DOI: https://doi.org/10.1007/s11696-020-01492-9