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Investigation on the Linear and Nonlinear Properties of Morin in Presence of Reverse Micelle and Different Oil Content in Reverse Micelle

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Abstract

We investigate the linear and nonlinear optical property of Morin (MN) at different concentration (1 × 10–6 and 5 × 10–6 M) within AOT reversed micelle prepared by water-in-decane microemulsion having a constant molar ratio of water-to-surfactant molecules of 40 (W = [H2O]/[AOT] = 40) as well as the function of mass fraction of nano-droplet (MFD) values of 0.01,0.04, 0.07, and 0.1 by using UV-Visible, Fluorescence, FTIR, and Z-scan techniques. The steady-state measurement indicates that the presence of microenvironment can greatly affect the tautomeric structure of morin and also Morin property in microenvironment depends upon the amount of oil and Morin concentration. The increase in dipole moment from the ground state to excited state in microenvironment indicate the change in the molecular structure on morin. Morin does not show any nonlinear absorption property but the nonlinear refractive index is observed as a function of Morin concentration as well as MFD values which are due to the thermal agitation of formed dimers.

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Morin nonlinearity

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Data Availability

All data generated or analyzed during this study are included in this published article [and its supplementary information files].

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Acknowledgements

 Authors gratefully acknowledge the financial support for this work from the University of Zabol (grant number. UOZ-GR-9618-143). D.S. would like to thank UGC for his UGC Assistant Professorship.

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Authors and Affiliations

  1. Department of Physics, University of Zabol, P. O. Box. 98613-35856, Zabol, Iran

    Abbas Rahdar

  2. Department of Chemistry, University of Zabol, Zabol, Iran

    Esmael Sanchooli

  3. Department of Physics, Shahid Beheshti University, G.C. Evin, Tehran, 19839, Iran

    R. Karimzadeh

  4. School of Physics, Sambalpur University, Jyoti Vihar, Burla, Odisha, 768019, India

    Dibakar Sahoo

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  1. Abbas Rahdar
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Contributions

All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by [Abbas Rahdar], [Esmael Sanchooli], [R. Karimzadehc] and [Dibakar Sahoo]. The first draft of the manuscript was written by [Dibakar Sahoo], [Abbas Rahdar] and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Correspondence to Abbas Rahdar or Dibakar Sahoo.

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Highlights

The optical property of Morin can greatly be affected by the microenvironment.

The tautomeric form of MN can also be affected by its concentration and oil content of AOT

The increase in dipole moment from the ground state to excited state in microenvironment.

Morin does not show any nonlinear absorption property.

Morin shows the nonlinear refractive index as a function of Morin concentration as well as MFD values.

Supplementary Information

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Rahdar, A., Sanchooli, E., Karimzadeh, R. et al. Investigation on the Linear and Nonlinear Properties of Morin in Presence of Reverse Micelle and Different Oil Content in Reverse Micelle. J Fluoresc 31, 373–383 (2021). https://doi.org/10.1007/s10895-020-02665-1

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  • DOI: https://doi.org/10.1007/s10895-020-02665-1

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