Abstract
Development of metal-free electrocatalyst recycled from waste is highly beneficial for environment-friendly application. Effective oxygen reduction reaction (ORR) relies on physico-chemical properties of electrocatalyst. Herein, the present report demonstrates the ORR studies of metal-free carbon nanoelectrocatalyst processed from biomass of Allium sativum. Carbon nanoparticles (CNPs) with various nitrogenation have been achieved by tuning the pyrolytic condition (400–1000 °C), using single bio-resource without additional dopants/activators. Under optimal condition, CNPs processed from 800 °C exhibit superior oxygen reduction function in alkaline medium with a Tafel slope value of 81 mV/dec, suggesting that the co-existence of nitrogen species improved the oxygen reduction active sites. Spectroscopic studies reveal that the inherent nitrogenation enriched the defects with mesoporosity in the graphitic carbon network synergizing the interfacial electron diffusion. Biomass-derived CNPs enable altered chemical species under different pyrolytic conditions suitable for cost-efficient, scalable, and sustainable ORR application.
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Acknowledgements
P. K. thankfully acknowledges the support of CSIR (HRDG) for the award of SRF (31/20(0181)/2019-EMR-I. G. P. thankfully acknowledges the support of ICMR for the award of ICMR-SRF (5/3/8/26/ITR-F/2020). M. V. gratefully acknowledges the support of the Department of Science and Technology, India for the DST-Inspire Faculty award (DST/INSPIRE/04/2015/002081). G. H. would like to thank DST-Nanomission, Government of India for providing grant titled “Biowaste based porous nano materials for efficient low-cost energy storage devices” having Grant no SR/NM/NT-1026/2017. All authors’ thanks the staffs of Central Instrumentation Facility (CIF), CSIR-Central Electrochemical Research Institute, Karaikudi. The authors declare no conflict of interest.
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Kanagavalli, P., Pandey, G.R., Bhat, V.S. et al. Nitrogenated-carbon nanoelectrocatalyst advertently processed from bio-waste of Allium sativum for oxygen reduction reaction. J Nanostruct Chem 11, 343–352 (2021). https://doi.org/10.1007/s40097-020-00370-w
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DOI: https://doi.org/10.1007/s40097-020-00370-w