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Extraction of spirotetramat insecticide by cloud point extraction method and its determination in environmental samples using high performance liquid chromatography

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Abstract

A simple new method based on cloud point extraction was optimized and validated to determine spirotetramat in agricultural surface water samples using HPLC–UV. In this method, the nonionic surfactant Triton X-114 was selected as a green extraction solvent because of its structure and properties. The effects of various parameters such as concentration and volume of Triton X-114, pH, temperature, and detergent agent were investigated on spirotetramat recovery and extraction and the data were optimized. Chromatographic separation was performed on the column ZORBAX Eclipse C18 (150 mm × 4.6 mm ID, 5 µm particle size) for the desired composition was detected at 240 nm. Under favorable conditions, the calibration curve was obtained for analyte of linear Dynamic range of 0.5–40 ppm with a correlation coefficient (r2) as 0.9978. In this method, the limit of detection for spirotetramat was 0.08 ppm, and for relative standard deviations (RSD, n = 5) was 4.9%.

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Acknowledgements

The authors are thankful to the Islamic Azad University, Shiraz branch for the support of this work.

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Authors and Affiliations

  1. Department of Applied Chemistry, Shiraz Branch, Faculty of Science, Islamic Azad University, Shiraz, Iran

    Elmira Ghaderi & Ali Asghar Amiri

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  1. Elmira Ghaderi
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  2. Ali Asghar Amiri
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Correspondence to Elmira Ghaderi.

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Ghaderi, E., Amiri, A.A. Extraction of spirotetramat insecticide by cloud point extraction method and its determination in environmental samples using high performance liquid chromatography. J IRAN CHEM SOC 18, 1373–1380 (2021). https://doi.org/10.1007/s13738-020-02121-8

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  • DOI: https://doi.org/10.1007/s13738-020-02121-8

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