Abstract
Among the remediation possibilities of oversulfated wastes, the use of hydraulic binders appears to be a promising option. Different binders (highly clinker, moderately and highly slag binders) were used here with the objective to lower the release of sulfates from various oversulfated matrices. Stabilization tests were performed with the objective to assess binders’ efficiency with respect to their chemical composition on the one hand and to characterize the preferential geochemical pathway of stabilization on the other hand. Four sulfated matrices, two natural soils from the Paris region (a and b hereafter), a laboratory model mixture (silt/gypsum) and a crushed concrete matrix were tested in this purpose. The highly clinker binder presented the best SO42− reduction performances on these materials, which justified a specific focus on the behavior of this binder. Physicochemical characterizations (IC, ICP-OES, XRD and TGA) suggested that the lowering of SO42− release was achieved via the precipitation of ettringite and gypsum. These phases were here formed, presumably, via the combination of Ca2+ from the highly clinker binder, and Al3+ cations brought by the destabilization of clayey minerals. This binder was particularly effective for two matrices (Parisian soil (a) and crushed concrete) in which SO42− lowered below both World Health Organization (WHO) and French standards. Stabilization was less conclusive on the other two matrices (Parisian soil (b) and silt/gypsum mixture) which released SO42− above the acceptability thresholds.
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The authors are grateful to Eqiom® for supporting this study, as well to Joanna Caboche and Damien Berttrancourt (IMT Lille Douai) for their technical contributions.
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Mahamat Ahmat, A., Mamindy-Pajany, Y. & Nadah, J. Lowering sulfates release from SO42−-rich geomaterials: few tests regarding the hydraulic binders’ pathway. Int. J. Environ. Sci. Technol. 18, 2661–2674 (2021). https://doi.org/10.1007/s13762-020-03027-x
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DOI: https://doi.org/10.1007/s13762-020-03027-x