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Synthesis of the superabsobents enriched in chitosan derivatives with excellent water absorption properties

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Abstract

The superabsorbent polymers (SAPs) containing up to 30% w of N-succinylchitosan and N-maleoylchitosan were successfully synthesized by free radical polymerization in an aqueous solution. The structures and surfaces of the synthesized SAPs were characterized by FTIR and SEM, respectively. The influence of the parameters such as type and content of polysaccharide, cross-linker, and comonomer mixture content on the swelling rate was researched. The chitosan-derivative-based SAPs have a higher swelling rate compared to chitosan-based SAPs. Equilibrium swelling rate, Qe, of the synthesized SAPs lying in the range 102–1144 g/g decreases with the rise of polysaccharide content. It was found that N-succinylchitosan-based SAPs are characterized by higher Qe values compared to N-maleoylchitosan ones. The highest swelling rate (Qe = 1144 g/g) was achieved for N-succinylchitosan-based polymer containing 2% w of N-succinylchitosan, 0.5% w of cross-linker, and acrylamide-acrylic acid weight ratio was 1:3. Researching the swelling kinetics shows equilibrium swelling is reached during 0–30 min for all synthesized polymers, and equilibrium reaching time rises with the increase in polysaccharide content. Also, swelling is correctly described by the pseudo-second-order model and controlled by chemical absorption of water molecules. The synthesized eco friendly SAPs enriched in polysaccharide content are characterized by excellent water-absorbing properties.

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References

  1. Mignon A, De Belie N, Dubruel P, Van Vlierberghe S (2019) Superabsorbent polymers: a review on the characteristics and applications of synthetic, polysaccharide-based, semi-synthetic and “smart” derivatives. Eur Polym J 117:165–178

    Article  CAS  Google Scholar 

  2. Guilherme MR, Aouada FA, Fajardo AR et al (2015) Superabsorbent hydrogels based on polysaccharides for application in agriculture as soil conditioner and nutrient carrier: A review. Eur Polym J 72:365–385

    Article  CAS  Google Scholar 

  3. Rashidzadeh A, Olad A (2014) Slow-released NPK fertilizer encapsulated by NaAlg-g-poly(AA-co-AAm)/MMT superabsorbent nanocomposite. Carbohyd Polym 114:269–278

    Article  CAS  Google Scholar 

  4. Tubert E, Vitali VA, Alvarez MS, Tubert FA, Baroli I, Amodeo G (2018) Synthesis and evaluation of a superabsorbent-fertilizer composite for maximizing the nutrient and water use efficiency in forestry plantations. J of Environ Manag 210:39–254

    Article  Google Scholar 

  5. Borsagli FGLM, Borsagli A (2019) Chemically modified chitosan bio-sorbents for the competitive complexation of heavy metals ions: a potential model for the treatment of wastewaters and industrial spills. J Polym Env 27:1542–1556

    Article  CAS  Google Scholar 

  6. Dumont VC, Mansur AAP, Carvalho SM, Medeiros Borsagli FGL, Pereira MM, Mansur HS (2016) Chitosan and carboxymethyl-chitosan capping ligands: effects on the nucleation and growth of hydroxyapatite nanoparticles for producing biocomposite membranes. Mater Sci Eng: C 59:265–277

    Article  CAS  Google Scholar 

  7. Medeiros Borsagli FGL, Carvalho IC, Mansur HS (2018) Amino acid-grafted and N- acylated chitosan thiomers: construction of 3D bio-scaffolds for potential cartilage repair applications. Int J Biol Macromol 114:270–282

    Article  CAS  PubMed  Google Scholar 

  8. Borsagli FGLM, Ciminelli VST, Ladeira CL, Haas DJ, Lage AP, Mansur HS (2019) Multi-functional eco-friendly 3d scaffolds based on n-acyl thiolated chitosan for potential absorption of methyl orange and antibacterial activity against pseudomonas aeruginosa. J Env Chem Eng 7(5):103286

    Article  Google Scholar 

  9. Ullah F, Othman MBH, Javed F, Ahmad Z, Akil HM (2015) Classification, processing and application of hydrogels: A review. Mater Sci and Eng: C 57:414–433

    Article  CAS  Google Scholar 

  10. Hassan M, Reddy KR, Haque E, Minett AI, Gomes VG (2013) High-yield aqueous phase exfoliation of graphene for facile nanocomposite synthesis via emulsion polymerization. J Colloid Interf Sci 410:43–51

    Article  CAS  Google Scholar 

  11. Choi SH, Kim DHR, Reddy AV et al (2011) Properties of graphene/waterborne polyurethane nanocomposites cast from colloidal dispersion mixtures. J Macromol Sci: B 51:197–207

    Article  Google Scholar 

  12. Reddy KR, Lee KP, Gopalan AI, Kang HD (2007) Organosilane modified magnetite nanoparticles/poly(aniline-co-o/m-aminobenzenesulfonic acid) composites: Synthesis and characterization. React Funct Polym 67:943–954

    Article  CAS  Google Scholar 

  13. Zhang YP, Lee SH, Reddy KR, Gopalan AI, Lee KP (2007) Synthesis and characterization of core-shell SiO2 nanoparticles/poly(3-aminophenylboronic acid) composites. J App Polym Sci 104:2743–2750

    Article  CAS  Google Scholar 

  14. Khan MU, Reddy KR, Snguanwongchai T, Haque E, Gomes VG (2016) Polymer brush synthesis on surface modified carbon nanotubes via in situ emulsion polymerization. Colloid Polym Sci 294:1599–1610

    Article  CAS  Google Scholar 

  15. Reddy KR, Sin BC, Yoo CH, Sohn D, Lee Y (2009) Coating of multiwalled carbon nanotubes with polymer nanospheres through microemulsion polymerization. J Colloid Interf Sci 340:160–165

    Article  CAS  Google Scholar 

  16. Bajpai P (2017) Pulp and Paper Industry. Elsevier, Amsterdam

    Book  Google Scholar 

  17. Wang W, Wang A (2010) Nanocomposite of carboxymethyl cellulose and attapulgite as a novel pH-sensitive superabsorbent: synthesis, characterization and properties. Carbohyd Polym 82:83–91

    Article  CAS  Google Scholar 

  18. Yoshimura T, Uchikoshi I, Yoshiura Y, Fujioka R (2005) Synthesis and characterization of novel biodegradable superabsorbent hydrogels based on chitin and succinic anhydride. Carbohyd Polym 61:322–326

    Article  CAS  Google Scholar 

  19. Yoshimura T, Matsuo K, Fujioka R (2006) Novel biodegradable superabsorbent hydrogels derived from cotton cellulose and succinic anhydride: synthesis and characterization. J Appl Polym Sci 99:3251–3256

    Article  CAS  Google Scholar 

  20. Hou X, Zhang W, He M, Lu Y, Lou K, Gao F (2017) Preparation and characterization of β-cyclodextrin grafted N-maleoyl chitosan nanoparticles for drug delivery. Asian J Pharm Sci 12:558–568

    Article  PubMed  PubMed Central  Google Scholar 

  21. Aiping Z, Tian C, Lanhua Y, Hao W, Ping L (2006) Synthesis and characterization of N-succinylchitosan and its self-assembly of nanospheres. Carbohyd Polym 66:274–279

    Article  Google Scholar 

  22. Bashir S, Teo YY, Ramesh S, Ramesh K (2016) Synthesis, characterization, properties of N-succinyl chitosan-g-poly(methacrylic acid) hydrogels and in vitro release of theophylline. Polym 92:36–49

    Article  CAS  Google Scholar 

  23. Cakmak I, Ozturk T (2005) Synthesis of triblock copolymers via photopolymerization of styrene and methyl methacrylate using macrophotoinitiators possessing poly(ethylene glycol) units. J Polym Res 12:121–126

    Article  CAS  Google Scholar 

  24. Liu X, Luan S, Li W (2019) Utilization of waste hemicelluloses lye for superabsorbent hydrogel synthesis. Int J Biol Macromol 132:954–962

    Article  CAS  PubMed  Google Scholar 

  25. Fang S, Wang G, Xing R et al (2019) Synthesis of superabsorbent polymers based on chitosan derivative graft acrylic acid-co-acrylamide and its property testing. Int J Biol Macromol 132:575–584

    Article  CAS  PubMed  Google Scholar 

  26. Liu X, Li X, Lu Z, Miao X, Feng Y (2010) Modified acrylic-based superabsorbents with hydrophobic monomers: synthesis, characterization and swelling behaviors. J Polym Res 18:897–905

    Article  Google Scholar 

  27. Ahmed EM (2015) Hydrogel: preparation, characterization, and applications: a review. J Adv Res 6:105–121

    Article  CAS  Google Scholar 

  28. Sinha V, Chakma S (2019) Advances in the preparation of hydrogel for wastewater treatment: a concise review. J Environ Chem Eng 7:103295

    Article  CAS  Google Scholar 

  29. Bakshia PS, Selvakumara D, Kadirvelub K, Kumara NS (2019) Chitosan as an environment friendly biomaterial-a review on recent modifications and applications. Int J Biol 150:1072–1083

    Google Scholar 

  30. Wu F, Zhang Y, Liu L, Yao J (2012) Synthesis and characterization of a novel cellulose-g-poly(acrylic acid-co-acrylamide) superabsorbent composite based on flax yarn waste. Carbohyd Polym 87:2519–2525

    Article  CAS  Google Scholar 

  31. Lide DR (2005) CRC Handbook of Chemistry and Physics (eighty, 5th edn. CRC Press, Boca Raton

    Google Scholar 

  32. Tan H, Chu CR, Payne KA, Marra KG (2009) Injectable in situ forming biodegradable chitosan–hyaluronic acid based hydrogels for cartilage tissue engineering. Biomater 30:2499–2506

    Article  CAS  Google Scholar 

  33. Bashir S, Teo YY, Ramesh S, Ramesh K (2016) Synthesis, characterization, properties of N-succinyl chitosan-g-poly (methacrylic acid) hydrogels and in vitro release of theophylline. Polym 92:36–49

    Article  CAS  Google Scholar 

  34. Suo A, Qian J, Yao Y, Zhang W (2006) Synthesis and properties of carboxymethyl cellulose-graft-poly(acrylic acid-co-acrylamide) as a novel cellulose-based superabsorbent. J App Polym Sci 103:1382–1388

    Article  Google Scholar 

  35. Jacobasch H-J, Simon F, Weidenhammer P (1998) Absorption of ions onto polymer surfaces and its influence on zeta potential and adhesion phenomena. Colloid Polym Sci 276:434–442

    Article  CAS  Google Scholar 

  36. Mahon R, Balogun Y, Oluyemi G et al (2020) Swelling performance of sodium polyacrylate and poly (acrylamide-co-acrylic acid) potassium salt. SN Appl Sci 2(1):117

    Article  CAS  Google Scholar 

  37. Ho Y, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochem 34:451–465

    Article  CAS  Google Scholar 

  38. Ritger PL, Peppas NA (1987) A simple equation for describing of solute release I. fickian and non-fickian release from non-swellable devices in the form of slabs, spheres, cylinders or discs. J Control Release 5:23–36

    Article  CAS  Google Scholar 

  39. Thakur S, Pandey S, Arotiba OA (2016) Development of a sodium alginate-based organic/inorganic superabsorbent composite hydrogel for absorption of methylene blue. Carbohyd Polym 153:34–46

    Article  CAS  Google Scholar 

  40. Schott H (1992) Swelling kinetics of polymers. J Macromol Sci B 31:1–9

    Article  CAS  Google Scholar 

  41. Yu X, Wang Z, Liu J, Mei H, Yong D, Li J (2018) Preparation, swelling behaviors and fertilizer-release properties of sodium humate modified superabsorbent resin. Mater Today Commun 19:124–130

    Article  Google Scholar 

  42. Zhou Y, Fu S, Zhang L, Zhan H (2013) Superabsorbent nanocomposite hydrogels made of carboxylated cellulose nanofibrils and CMC-g-p(AA-co-AM). Carbohyd Polym 97:429–443

    Article  CAS  Google Scholar 

Download references

Acknowledgements

FTIR and SEM data were obtained with the use of equipment of the Research Core Centre of Voronezh State University.

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Correspondence to Andrey Sorokin.

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Sorokin, A., Lavlinskaya, M. Synthesis of the superabsobents enriched in chitosan derivatives with excellent water absorption properties. Polym. Bull. 79, 407–427 (2022). https://doi.org/10.1007/s00289-020-03521-9

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  • DOI: https://doi.org/10.1007/s00289-020-03521-9

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