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Au (111)-like electrode in highly ordered SiO2-cavity: a novel nonenzymatic amperometric detection of glucose

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Abstract

In this work, we report a novel nonenzymatic glucose detection base on the use of Au (111)-like/SiO2 indium tin oxide (ITO) electrode. First, the ordered SiO2-cavity array was fabricated on the ITO electrodes via the ordered polystyrene spheres (PS) templates. Secondly, the nucleation stage of Au NPs was generated by an electrochemical seeding growth method. As a matter of fact, \( AuCl_{4}^{ - } \) could be electrodeposited on the as-prepared Au seeds in a subsequent cyclic voltammetry, the raspberry-like Au NPs were formed with major facet of (111). The size and density of raspberry-like Au NPs could be successfully controlled. The as-prepared electrode showed good electrochemical performance for glucose oxidation with the linear range from 50 μM to 1.5 mM (R = 0.9995), a low detection limit of 12 μM, and good selectivity of the interferences of AA and UA. The raspberry-like Au (111)-like/SiO2 ITO electrode might become an enzyme-free glucose sensor with long-term stability and good reproducibility.

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Acknowledgements

Financial supports from the Nature Science Foundation of Jiangsu Ocean University (No. Z2015003), the Natural Science Foundation of Jiangsu Higher Education Institution of China (No. 19KJB150004), the Natural Science Fund of Jiangsu Province (No. BK20181485), and a Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) are gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemical Engineering, Jiangsu Ocean University, Lianyungang, 222005, People’s Republic of China

    Na Li, Hongying Zhou, Gui Zhao, Tao Yang, Mingyan Wang, Ou Sha, Yanhui Li & Haihong Jia

  2. College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, People’s Republic of China

    Qun Zhou & Junwei Zheng

  3. College of Physics, Optoelectronics and Energy, Soochow University, Suzhou, 215006, People’s Republic of China

    Junwei Zheng

Authors
  1. Na Li
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  2. Hongying Zhou
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  3. Gui Zhao
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  4. Tao Yang
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  5. Mingyan Wang
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  7. Yanhui Li
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  9. Qun Zhou
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  10. Junwei Zheng
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Correspondence to Na Li, Mingyan Wang or Junwei Zheng.

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Li, N., Zhou, H., Zhao, G. et al. Au (111)-like electrode in highly ordered SiO2-cavity: a novel nonenzymatic amperometric detection of glucose. J IRAN CHEM SOC 18, 1667–1675 (2021). https://doi.org/10.1007/s13738-020-02139-y

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  • DOI: https://doi.org/10.1007/s13738-020-02139-y

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