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Polymeric Nanocomposite-Based Herbicide of Carboxymethyl Cellulose Coated-Zinc/Aluminium Layered Double Hydroxide-Quinclorac: A Controlled Release Purpose for Agrochemicals

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Abstract

In this work, the use of carboxymethyl cellulose (CMC) is highlighted in enhancing the controlled release behaviour of zinc/aluminium layered double hydroxide-quinclorac (Zn/Al-LDH-QC). The Zn/Al-LDH-QC-CMC nanocomposite were characterised using powder x-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric and derivative thermogravimetric analysis and field emission scanning electron microscopy. The release study was carried out in an aqueous solution of Na3PO4, Na2SO4 and NaCl, so as to mimic the environmental condition where the QC is frequently used. The Zn/Al-LDH-QC-CMC nanocomposites showed better performance in releasing QC, with prolonged release time ranging from 163–6083 min, compared to 99–2639 min for the uncoated nanocomposites. The hygroscopic nature of the CMC play a critical role in enhancing the release behaviour of the Zn/Al-LDH-QC-CMC. The kinetic study shows that the Zn/Al-LDH-QC-CMC follows the pseudo-second order kinetic model; hence the release mechanism occurred via dissolution of the CMC matrix and the ion exchange process. These results, therefore, indicate the potential of Zn/Al-LDH-QC-CMC in dealing with the downside effect of the excessive usage of herbicide in paddy cultivation.

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Acknowledgements

The authors wish to thank UPSI and Ministry of Education Malaysia for the support during completing the research. This work was supported by the GPU-RISING STAR Grant No. 2019−0119−103−01.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, 35900, Tanjong Malim, Perak, Malaysia

    Sharifah Norain Mohd Sharif, Norhayati Hashim, Illyas Md Isa, Mohamad Idris Saidin & Mohamad Syahrizal Ahmad

  2. Nanotechnology Research Centre, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, 35900, Tanjong Malim, Perak, Malaysia

    Norhayati Hashim & Illyas Md Isa

  3. Department of Physics, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, 35900, Tanjong Malim, Perak, Malaysia

    Suriani Abu Bakar

  4. School of Fundamental Science, Universiti Malaysia Terengganu, 21030, Kuala Terengganu, , Terengganu, Malaysia

    Mazidah Mamat

  5. Materials Synthesis and Characterization Laboratory, Institute of Advanced Technology, Universiti Putra Malaysia, 43400, Serdang, Selangor, Malaysia

    Mohd Zobir Hussein

  6. Department of Chemistry, Faculty of Mathematics and Natural Science, Universitas Negeri Padang, Padang, West Sumatera, 25171, Indonesia

    Rahadian Zainul

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  1. Sharifah Norain Mohd Sharif
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Sharif, S.N.M., Hashim, N., Isa, I.M. et al. Polymeric Nanocomposite-Based Herbicide of Carboxymethyl Cellulose Coated-Zinc/Aluminium Layered Double Hydroxide-Quinclorac: A Controlled Release Purpose for Agrochemicals. J Polym Environ 29, 1817–1834 (2021). https://doi.org/10.1007/s10924-020-01997-0

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