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Ceria-Based Catalysts for Selective Hydrogenation Reactions: A Critical Review

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Abstract

The catalytic behaviour of ceria (cerium (IV) Oxide; CeO2) incorporated with trace metals, metallic particles or mixed support systems has been studied extensively for various heterogeneous reactions. Moreover, unique redox properties and structural defects have made ceria a desirable choice for selective hydrogenation reactions. This paper provides the first review of studies focusing on the performance of ceria in selective catalytic hydrogenation. The review covers the fundamentals, economic benefits, and application of ceria in the aforementioned reaction, highlighting the theoretical basis and importance of non-stoichiometric forms of ceria (CeO2-x). We have contrasted the effect of operational parameters and molecular alterations as documented in the literature, and constructed the mechanistic and kinetic insights on the heterogeneous hydrogenation over ceria. The remarks in this review provide necessary future outlooks, recommendations, and plausaible improvements on the catalytic performance of ceria.

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Acknowledgements

Kourosh Razmgar thanks Murdoch University for the award of a postgraduate scholarship. Mohammednoor Altarawneh acknowledges a start-up grant from the College of Engineering at the United Arab Emirates University, UAEU (Grant Number: 31N421).

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  1. College of Science, Health, Engineering and Education, Murdoch University, Perth, WA, 6150, Australia

    Kourosh Razmgar, Mohammednoor Altarawneh, Ibukun Oluwoye & Gamini Senanayake

  2. Department of Chemical and Petroleum Engineering, United Arab Emirates University, 15551, Al-Ain, United Arab Emirates

    Mohammednoor Altarawneh

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Razmgar, K., Altarawneh, M., Oluwoye, I. et al. Ceria-Based Catalysts for Selective Hydrogenation Reactions: A Critical Review. Catal Surv Asia 25, 27–47 (2021). https://doi.org/10.1007/s10563-020-09319-z

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