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Synthesis and Characterization of Hybrid Material Based on Poly(pyrrole-co-N-methyl pyrrole) and ZnCo2O4

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Abstract

This study highlights the method of synthesis and characterization of a novel hybrid material consisting of zinc cobaltite (ZnCo2O4) and the conductive copolymer based on pyrrole and N-methyl pyrrole. The pure ZnCo2O4 is synthesized by sol-gel method, polypyrrole-ZnCo2O4, poly(N-methyl pyrrole)-ZnCo2O4 and poly(pyrrole-co-N-methyl pyrrole)-ZnCo2O4 are synthesized by chemical oxidative polymerization and characterized by different techniques. X-ray diffraction results revealed the existence of a cubic spinel structure of ZnCo2O4 in all samples. The synthesis efficiency of the polymer-ZnCo2O4 nanocomposite is confirmed by the Fourier transform infrared spectroscopy. The results of scanning electron microscopy show that the nanoparticles are mostly spherical in shape and the powders morphology structure varies from sample to sample. The energy dispersive X-ray analysis shows the formation of hybrid material with a substantial purity.

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REFERENCES

  1. V. P. Ananikov, Nanomaterials 9, 1197 (2019).

    Article  CAS  PubMed Central  Google Scholar 

  2. R. Mobin, T. A. Rangreez, H. T. N. Chisti, Inamuddin, and M. Rezakazemi, “Organic-Inorganic Hybrid Materials and Their Applications,” in Functional Polymers. Polymers and Polymeric Composites: A Reference Series, Ed. by M. Jafar Mazumder, H. Sheardown, and A. Al-Ahmed (Springer, Switzerland, 2019).

    Google Scholar 

  3. S. L. Lee, and C.-J. Chang, Polymers (Basel, Switz.) 10, 206 (2019).

  4. J. Zou, H. L. Yip, S. K. Hau, and A. K. Y. Jen, J. Appl. Phys. Lett. 96, 203301 (2010).

    Article  CAS  Google Scholar 

  5. B. Z. Yang, Y. S. Lin, and J. M. Wu, Appl. Mater. Today 9, 96 (2017).

    Article  Google Scholar 

  6. M. Bharti, A. Singh, S. Samanta, and D. K. Aswal, Prog. Mater. Sci. 93, 270 (2018).

    Article  CAS  Google Scholar 

  7. R. B. Yang, P. M. Reddy, C. J. Chang, P. A. Chen, J. K. Chen, and C. C. Chang, Chem. Eng. J. 285, 497 (2016).

    Article  CAS  Google Scholar 

  8. H. Kang, H. Park, Y. Park, M. Jung, B. C. Kim, G. Wallace, and G. Cho, Sci. Rep. 4, 5387 (2014).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  9. C. J. Chang, M. H. Tsai, Y. H. Hsu, and C. S. Tuan, Thin Solid Films 516, 5523 (2008).

    Article  CAS  Google Scholar 

  10. M. Ates, M. El-Kady, and R. B. Kaner, Nanotechnology 29, 175402 (2018).

    Article  PubMed  CAS  Google Scholar 

  11. C. J. Chang, Y. Y. Leong, C. F. Lai, W. Y. Chiou, M. J. Su, and S. J. Chang, J. Appl. Polym. Sci. 134, 45210 (2017).

    Article  CAS  Google Scholar 

  12. C. J. Chang, C. F. Lai, P. Madhusudhana Reddy, Y. L. Chen, W. Y. Chiou, and S. J. Chang, J. Lumin. 160, 145 (2015).

    Article  CAS  Google Scholar 

  13. T. Selvan, J. P. Spatz, H.-A. Klok, and M. Möller, Adv. Mater. 10, 132 (1998).

    Article  CAS  Google Scholar 

  14. T. Chena, Y. Fan, G. Wang, Q. Yang, and R. Yang, RSC Adv. 5, 74523 (2015).

  15. J. P. Morán-Lázaro, F. López-Urías, E. Muñoz-Sandoval, O. Blanco-Alonso, M. Sanchez-Tizapa, A. Carreon-Alvarez, H. Guillén-Bonilla, M. de la Luz Olvera-Amador, A. Guillén-Bonilla, and V. M. Rodríguez-Betancourtt, in Nanostructured Materials—Fabrication to Applications, Ed. by M. Seehra (IntechOpen, Rijeka, 2017), Chap. 8.

    Google Scholar 

  16. H. Liu, X.Wang, H. Xu, J. Wang, Q. Ma, W. Yu, Y. Yang, X. Dong, G. Liu, and Y. Zhao, RSC Adv. 8, 39377 (2018).

  17. N. Joshi, L. F. da Silva, H. Jadhav, J.-C. M’Peko, B. B. M. Torres, K. Aguir, V. R. Mastelaro, and O. N. Oliveira, Jr., RSC Adv. 6, 92655 (2016).

  18. Y. Sharma, N. Sharma, G. V. Subba-Rao, and B. V. R. Chowdari, Adv. Funct. Mater. 17, 2855 (2007).

    Article  CAS  Google Scholar 

  19. L. Huang, G. H. Waller, Y. Ding, D. Chen, D. Ding, P. Xi, Z. L. Wang, and M. Liu, Nano Energy 11, 64 (2015).

    Article  CAS  Google Scholar 

  20. C. Wu, J. Cai, Q. Zhang, X. Zhou, Y. Zhu, L. Li, P. Shen, and K. Zhang, Electrochim. Acta 169, 202 (2015).

    Article  CAS  Google Scholar 

  21. W. Fu, X. Li, C. Zhao, Y. Liu, P. Zhang, J. Zhou, X. Pan, and E. Xie, Mater. Lett. 149, 1 (2015).

    Article  CAS  Google Scholar 

  22. N. Joshi, L. F. da Silva, H. S. Jadhav, F. M. Shimizu, P. H. Suman, J.-C. M’Peko, M. O. Orlandi, J. G. Seo, V. R. Mastelaro, and O. N. Oliveira, Jr., Sens. Actuators, B 257, 906 (2018).

    Article  CAS  Google Scholar 

  23. M. Sharma and A. Gaur, Sci. Rep. 10, 2035 (2020).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  24. X. Wei, D. Chen, and W. Tang, Mater. Chem. Phys. 103, 54 (2007).

    Article  CAS  Google Scholar 

  25. F. Z. Kouidri, R. Berenguer, A. Benyoucef, and E. Morallon, J. Mol. Struct. 1188, 121 (2019).

    Article  CAS  Google Scholar 

  26. S. Senthilkumar and A. Rajendran, MOJ Polym. Sci. 1, 192 (2017).

    Google Scholar 

  27. Q. Wang, L. Zhu, L. Sun, Y. Liub, and L. Jiao, J. Mater. Chem. A 10, 1039 (2014).

    Google Scholar 

  28. A. O. Bokuniaeva and A. S. Vorokhm, J. Phys.: Conf. Ser. 1410, 012057 (2019).

    CAS  Google Scholar 

  29. N. M. Juibari and A. Eslami, J. Therm. Anal. Calorim. 130 (2), 1 (2017).

    Article  CAS  Google Scholar 

  30. M. Baskey, R. Maiti, S K. Saha, and D. Chakravorty, J. Appl. Phys. 115, 094306 (2014).

    Article  CAS  Google Scholar 

  31. M. Šetka, J. Drbohlavová, and J. Hubálek, Sensors 17, 562 (2017).

    Article  CAS  PubMed Central  Google Scholar 

  32. B. Duran and G. zen Bereket, Ind. Eng. Chem. Res. 51, 5246 (2012).

    Article  CAS  Google Scholar 

  33. S. Bahraeian, K. Abron, F. Pourjafarian, and R. A. Majid, Adv. Mater. Res. 795, 707 (2013).

    Article  CAS  Google Scholar 

  34. S. Khademi, B. Pourabbas, and K. Foroutani, Polym. Bull. 75, 4291 (2018).

    Article  CAS  Google Scholar 

  35. A. Batoola, F. Kanwalb, M. Imranb, T. Jamilc, and S. A. Siddiqi, Synt. Met. 161, 2753 (2012).

    Article  CAS  Google Scholar 

  36. N. H. Bouabida, A. Hachemaoui, A. Yahiaoui, H. Gherras, A. Belfedal, A. Dehbi, and A.-H. I. Mourad, Polym. Sci., Ser. B 62, 163 (2020).

    Article  CAS  Google Scholar 

  37. A. Dehbi, A. H. I. Mourad, K. Djakhdane, and A. Hilal-Alnaqbi, Polym. Eng. Sci. 55, 287 (2015).

    Article  CAS  Google Scholar 

  38. K. Djakhdane, A. Dehbi, A. H. I. Mourad, A. Zaoui, and P. Picuno, Plast. Rubber Compos. 45, 346 (2016).

    Article  CAS  Google Scholar 

  39. H. Gherrass, A. Hachemaoui, A. Yahiaoui, A. Belfadel, A. Dehbi, and A. H. I. Mourad, J. Semicond. 39, 102001 (2018).

  40. I. Tiffour, A. Dehbi, A.-H.-I. Mourad, and A. Belfedal, Mater. Chem. Phys. 178, 49 (2016).

    Article  CAS  Google Scholar 

  41. Sachin. V. Bangale, S. M. Khetre, and S. R. Bamane, Chem. Sin. 2, 303 (2011).

  42. Y. Al Haj, J. Balamurugan, N. H. Kim, and J. H. Lee, J. Mater. Chem. A 7, 3941 (2019).

    Article  CAS  Google Scholar 

  43. A. Banerjee and Z. Singh, J. Solid State Electrochem. 13, 1201 (2009).

    Article  CAS  Google Scholar 

  44. H. J. Kim, I. C. Song, J. H. Sim, H. Kim, D. Kim, Y. E. Ihm, and W. K. Choo, Solid State Commun. 129, 627 (2004).

    Article  CAS  Google Scholar 

  45. C. R. Mariappan, R. Kumar, and G. Vijaya Prakash, RSC Adv. 5, 26843 (2015).

  46. D. O. Scanlon and G. W. Watson, Phys. Chem. Chem. Phys. 13, 9667 (2011).

    Article  CAS  PubMed  Google Scholar 

  47. Y. Zhu, X. Ji, Z. Wu, W. Song, H. Hou, Z. Wu, X. He, Q. Chen, and C. E. Banks, J. Power Sources 267, 888 (2014).

    Article  CAS  Google Scholar 

  48. L. Hu, L. Wu, M. Liao, X. Hu, and X. Fang, Adv. Funct. Mater. 22, 998 (2012).

    Article  CAS  Google Scholar 

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Funding

This work is funding by La Direction Générale de la Recherche Scientifique et du Développement Technologique (DGRSDT) Algeria.

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Correspondence to Abdelkader Dehbi.

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Boualem Alouche, Yahiaoui, A. & Dehbi, A. Synthesis and Characterization of Hybrid Material Based on Poly(pyrrole-co-N-methyl pyrrole) and ZnCo2O4 . Polym. Sci. Ser. B 62, 750–755 (2020). https://doi.org/10.1134/S1560090420330015

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  • DOI: https://doi.org/10.1134/S1560090420330015

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