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Solid Phase Interaction of the Recondensed Finely Dispersed Mixture (VC0.40O0.53–C) with Titanium Hydride

  • Inorganic Synthesis and Industrial Inorganic Chemistry
  • Published:
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Abstract

The processing of industrial waste and highly hazardous substances using extreme techniques of formation, in addition to else, of nanocrystalline materials, which include plasmachemical synthesis according to the plasma recondensation scheme in low-temperature nitrogen plasma, is an urgent issue of chemical technology. In the work, an attempt was made to plasma recondensation of a mechanical mixture consisting of crystalline hydrates of the VnOn·xH2O type and gas soot in an 1 : 1 ratio. The solid phase interaction of the VC0.40O0.53–Cfree nanocrystalline mixture with TiH2 hydride in various proportions in the course of high-temperature vacuum sintering was studied. Based on the data of X-ray diffraction, scanning electron microscopy, and EDX analysis, the main patterns of solid phase interaction in the system (VC0.40O0.53–Cfree)–TiH2 were described, and schemes of the processes were proposed occurring during sintering.

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ACKNOWLEDGMENTS

The work was carried out in accordance with the state order of the Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences (project no. 0397-2019-0003 “New functional materials for advanced technologies: synthesis, properties, spectroscopy and computer simulation”).

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 620990, Yekaterinburg, Russia

    Yu. A. Avdeeva, A. N. Ermakov, I. V. Luzhkova & Yu. G. Zainulin

  2. Ural Federal University named after the first President of Russia B. N. Yeltsin, 620002, Yekaterinburg, Russia

    L. Kh. Askarova

  3. Scientific Research Institute of Chemistry and Technology of Organoelement Compounds, 105118, Moscow, Russia

    E. K. Dobrinskii

Authors
  1. Yu. A. Avdeeva
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  2. A. N. Ermakov
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  3. I. V. Luzhkova
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  4. L. Kh. Askarova
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  5. E. K. Dobrinskii
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  6. Yu. G. Zainulin
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Correspondence to Yu. A. Avdeeva.

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Avdeeva, Y.A., Ermakov, A.N., Luzhkova, I.V. et al. Solid Phase Interaction of the Recondensed Finely Dispersed Mixture (VC0.40O0.53–C) with Titanium Hydride. Russ J Appl Chem 93, 1696–1704 (2020). https://doi.org/10.1134/S1070427220110105

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