Influence of machine type and consecutive closed-loop recycling on macroscopic properties for fused filament fabrication of acrylonitrile-butadiene-styrene parts

This study aims to evaluate and compare the macroscopic properties of commercial acrylonitrile-butadiene-styrene (ABS) processed by two different types of additive manufacturing (AM) machines. The focus is also on the effect of multiple closed-loop recycling of ABS.

A conventional direct-drive, Cartesian-type machine and a Bowden, Delta-type machine with an infrared radiant heating system are used to manufacture test specimens molded in ABS. Afterward, multiple closed-loop recycling cycles are conducted, involving consecutive AM (four times) and recycling (three times). The rheological, mechanical, morphological and physicochemical properties are investigated.

The type of machine affects the quality of the produced parts. The machine containing an infrared radiant system in a temperature-controlled chamber produces parts showing higher mechanical properties and filling fraction, although it increases the yellowing. Closed-loop recycling of ABS for AM is applicable for at least two cycles, inducing a slight increase in tensile modulus (ca. 5%) and in tensile strength (ca. 13%) and a decrease in the impact strength (ca. 14%) and melt viscosity. An increase in the filling fraction of the AM parts promotes an increase in tensile strength and tensile modulus, although it does not influence the impact strength. Furthermore, multiple closed-loop recycling does not affect the overall chemical structure of ABS.

Controlling the environmental temperature and using infrared radiant heating during AM of ABS improves the quality of the produced parts. Closed-loop recycling of ABS used in AM is feasible up to at least two recycling steps, supporting the implementation of a circular economy for polymer-based AM.

This study shows original results regarding the assessment of the effect of different types of AM machines on the main end-use properties of ABS parts and the influence of multiple closed-loop recycling on the characteristics of ABS fabricated by the most suited AM machine with an infrared radiant heating system and a temperature-controlled environment.