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Peculiarities of Dissolving Polyacrylonitrile Copolymer Containing Methylsulfo Groups in N-Methylmorpholine-N-Oxide

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Abstract

The process of solid-phase dissolution of polyacrylonitrile copolymer containing ionic sulfo groups in an electron-donating solvent, N-methylmorpholine-N-oxide, is studied depending on its crystal hydrate form and preparation conditions. Optical studies of the transition of solid-phase copolymer–solvent systems to a viscous flow state make it possible to construct solubility curves and reveal stages of morphological transformations during dissolution, explaining their nature. Solid-phase mixed systems are studied by IR spectroscopy, and interactions of the functional groups of the copolymer with various crystal hydrates of the solvent are analyzed both during standard mechanical mixing and mechanochemical activation under intense shear deformation, which predetermines the formation of solid solutions.

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REFERENCES

  1. V. G. Kulichikhin, I. Yu. Skvortsov, M. I. Mironova, A. N. Ozerin, T. S. Kurkin, A. K. Berkovich, E. I. Frenkin, and A. Ya. Malkin, Adv. Polym. Technol. 37, 1099 (2018).

    Article  CAS  Google Scholar 

  2. I. S. Makarov, L. K. Golova, M. I. Vinogradov, D. N. Chernenko, and V. G., IOP Conf. Ser.: Earth Environ. Sci. 316, 012032 (2019).

  3. R. Eslami Farsani, A. Shokuhfar, and A. Sedghi, Fibre Chem. 38, 383 (2006).

    Article  Google Scholar 

  4. A. A. Konkin, M. T. Azarova, N. S. Volkova, R. M. Levit, and V. P. Sergeev, Fibre Chem. 9, 298 (1978).

    Article  Google Scholar 

  5. G. A. Budnitskii, V. S. Matveev, and M. E. Kazakov, Fibre Chem. 25, 360 (1994).

    Article  Google Scholar 

  6. J. M. Spörl, A. Ota, S. Son, K. Massone, F. Hermanutz, and M. R. Buchmeiser, Mater. Today Commun. 7, 1 (2016).

    Article  Google Scholar 

  7. Yu. N. Sazanov, Vestn. Tver. Gos. Univ., Ser. Khim., No. 2, 96 (2017).

  8. H. Mainka, L. Hilfert, S. Busse, F. Edelmann, E. Haak, and A. S. Herrmann, J. Mater. Res. Technol. 4, 377 (2015).

    Article  CAS  Google Scholar 

  9. A. T. Mukhamedzyanov, A. A. Mukhamedzyanova, R. N. Gimaev, and R. N. Galiakhmetov, Vestn. Bashk. Univ. 20, 1218 (2015).

    Google Scholar 

  10. A. A Konkin, Carbon and Other Heat-Resistant Fibrous Materials (Khimiya, Moscow, 1974), p. 148 [in Russian].

    Google Scholar 

  11. A. T. Serkov and M. B. Radishevskii, Fibre Chem. 40, 24 (2008).

    Article  CAS  Google Scholar 

  12. M. Kibayashi, S. Seike, and L. A. Pragner, US Patent No. 20130253096A1 (2011).

  13. T. Higuchi and M. Sakaguchi, EP Patent No. 3093380A1 (2014).

  14. S. A. Podkopaev and V. A. Tyumentsev, RF Patent No. 2330906 (2007).

  15. D. F. Grishin and I. D. Grishin, Fibre Chem. 50, 514 (2019).

    Article  CAS  Google Scholar 

  16. E. R. Badamshina, A. A. Grishchuk, A. E. Tarasov, Ya. I. Estrin, and S. M. Aldoshin, RF Patent No. 2565767 (2014).

  17. I. D. Grishin, D. Yu. Kurochkina, and D. F. Grishin, RF Patent No. 2627264 (2016).

  18. E. Fittser and V. Fros, Khim. Volokna, No. 2, 14 (1992).

    Google Scholar 

  19. O. V. Zhidkova, I. N. Andreeva, M. B. Radishevskii, A. T. Serkov, A. T. Kalashnik, and N. V. Chichinova, Fibre Chem. 25, 368 (1994).

    Article  Google Scholar 

  20. E. V. Chernikova, R. V. Toms, N. I. Prokopov, V. R. Duflot, A. V. Plutalova, S. A. Legkov, and V. I. Gomzyak, Polym. Sci. Ser. B 59, 28 (2017).

    Article  CAS  Google Scholar 

  21. H. Jiang, D. Pan, and M. Zhou, Global J. Eng. Sci. Res. Manage. 2 (8), 9 (2015).

    Google Scholar 

  22. A. Gupta and R. Singhal, J. Polym. Sci., Polym. Phys. Ed. 21, 2243 (1983).

    Article  CAS  Google Scholar 

  23. M. Hattori, H. Yamazaki, M. Saito, K. Hisatani, and K. Okajima, Polym. J. 28, 594 (1996).

    Article  CAS  Google Scholar 

  24. M. M. Iovleva, V. N. Smirnova, and G. A. Budnitskii, Fibre Chem. 33, 262 (2001).

    Article  CAS  Google Scholar 

  25. I. S. Makarov, L. K. Golova, L. K. Kuznetsova, A. V. Rebrov, A. K. Berkovich, I. Yu. Skvortsov, and V. G. Kulichikhin, Russ. J. Gen. Chem. 87, 1351 (2017).

    Article  CAS  Google Scholar 

  26. D. L. Johnson, US Patent No. 3447939 (1969).

  27. L. K. Golova, Fibre Chem. 28, 5 (1996).

    Article  Google Scholar 

  28. L. K. Golova, Ross. Khim. Zh. 46, 49 (2002).

    CAS  Google Scholar 

  29. R. G. Zhbankov and P. V. Kozlov, Physics of Cellulose and its Derivatives (Nauka i Tekhnika, Minsk, 1983) [in Russian].

    Google Scholar 

  30. I. S. Makarov, L. K. Golova, M. I. Vinogradov, M. V. Mironova, I. S. Levin, G. N. Bondarenko, G. A. Shandryuk, N. A. Arkharova, and V. G. Kulichikhin, Polym. Sci., Ser. A 61, 598 (2019).

    Article  CAS  Google Scholar 

  31. L. K. Golova, I. S. Makarov, E. V. Matukhina, S. A. Kuptsov, G. K. Shambilova, and V. G. Kulichikhin, Polym. Sci., Ser. A 50, 665 (2008).

    Article  Google Scholar 

  32. L. K. Golova, I. S. Makarov, and E. P. Plotnikova, G. Sh. Shambilova, A. K. Tereshin, and V. G. Kulichikhin, Polym. Sci., Ser. A 51, 283 (2009).

    Article  Google Scholar 

  33. B. Morgenstern, O. Leillinger, and R. Maron, Angew. Makromol. Chem. 243 (4251), 129 (1996).

    Article  CAS  Google Scholar 

  34. I. S. Makarov, L. K. Golova, L. K. Kuznetsova, A. V. Shlyakhtin, I. E. Nifant’ev, and V. G. Kulichikhin. RF Patent No. 2541473 (2014).

  35. V. Kulichikhin, L. Golova, I. Makarov, G. Bondarenko, V. Makarova, S. Ilyin, I. Skvortsov, and A. Berkovich, Eur. Polym. J. 92, 326 (2017).

    Article  CAS  Google Scholar 

  36. I. S. Gorodnyakova, L. A. Shcherbina, and K. Yu. Ustinov, Polim. Mater. Tekhnol. 3 (4), 37 (2017).

    Google Scholar 

  37. L. K. Golova, V. V. Romanov, O. B. Lunina, V. A. Platonov, S. P. Papkov, O. D. Khorozova, V. V. Yakshin, T. P. Belasheva, and A. N. Sokira, RF Patent No. 1645308 (1991).

  38. H. Chanzy and A. Peguy, J. Polym. Sci., Polym. Phys. Ed. 18, 1137 (1980).

    Article  CAS  Google Scholar 

  39. M. M. Iovleva and V. N. Smirnova, Polym. Sci., Ser. A 25, 749 (1986).

    Google Scholar 

  40. L. K. Golova, O. E. Borodina, O. B. Lunina, I. D. Zenkov, and I. N. Andreeva, Physical and Chemical Foundations of Production of Rayon by Nontraditional Methods, Ed. by S. P. Papkova and I. P. Baksheeva (VNIIVproekt, Mytishchi, 1989), p. 113 [in Russian].

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The study was supported by the Russian Science Foundation (grant no. 17-79-30108).

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Correspondence to L. K. Golova.

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Golova, L.K., Bondarenko, G.N., Makarov, I.S. et al. Peculiarities of Dissolving Polyacrylonitrile Copolymer Containing Methylsulfo Groups in N-Methylmorpholine-N-Oxide. Polym. Sci. Ser. A 62, 597–606 (2020). https://doi.org/10.1134/S0965545X20060036

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  • DOI: https://doi.org/10.1134/S0965545X20060036

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