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Adsorption of IFKhAN-92 Inhibitor on Low Carbon Steel from Sulfuric Acid Solution

  • GENERAL PROBLEMS OF CORROSION
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Abstract

The method of electrochemical impedance spectroscopy was used to study the adsorption of an IFKhAN-92 inhibitor, 3-substituted 1,2,4-triazole, on low-carbon steel from 2.0 M H2SO4 (22°C). It was shown that the Temkin isotherm with a relatively high value of free energy of adsorption (−ΔGads) = 49 kJ/mol described its adsorption. It was suggested that the inhibitor adsorption has a chemisorption nature, which is testified both by the description of the kinetics of adsorption by the Roginsky–Zeldovich equation and a high protective aftereffect of the inhibitor adsorbed on the steel surface.

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REFERENCES

  1. Avdeev, Ya.G. and Kuznetsov, Yu.I., Russ. Chem. Rev., 2012, vol. 81, no. 12, pp. 1133–1145. https://doi.org/10.1070/RC2012v081n12ABEH004292

    Article  Google Scholar 

  2. Tourabi, M., Nohair, K., Traisnel, M., Jama, C., and Bentiss, F., Corros. Sci., 2013, vol. 75, pp. 123–133. https://doi.org/10.1016/j.corsci.2013.05.023

    Article  CAS  Google Scholar 

  3. Ma, Q., Qi, S., He, X., Tang, Y., and Lu, G., Corros. Sci., 2017, vol. 129, pp. 91–101. https://doi.org/10.1016/j.corsci.2017.09.025

    Article  CAS  Google Scholar 

  4. Swathi, N.P., Alva, V.D.P., and Samshuddin, S., J. Bio- Tribo-Corros., 2017, vol. 3, p. 42. https://doi.org/10.1007/s40735-017-0102-3

  5. Ahmad, Y.H., Mogoda, A.S., and Gadallh, A.G., Int. J. Electrochem. Sci., 2012, vol. 7, pp. 4929–4941.

    CAS  Google Scholar 

  6. Avdeev, Ya.G., Belinskii, P.A., Kuznetsov, Yu.I., and Zel’, O.O., Korroz.: Mater., Zashch., 2008, no. 8, pp. 16–21.

  7. Avdeev, Ya.G., Frolova, L.V., Kuznetsov, Yu.I., and Zel’, O.O., Korroz.: Mater., Zashch., 2010, no. 5, pp. 22–29.

  8. Avdeev, Ya.G., Frolova, L.V., Kuznetsov, D.S., Tyurina, M.V., and Chekulaev, M.A., Int. J. Corros. Scale Inhib., 2016, vol. 5, no. 1, pp. 87–99. https://doi.org/10.17675/2305-6894-2016-5-1-7

    Article  CAS  Google Scholar 

  9. Avdeev, Ya.G., Frolova, L.V., Kuznetsov, D.S., Tyurina, M.V., and Chekulaev, M.A., Int. J. Corros. Scale Inhib., 2016, vol. 5, no. 2, pp. 147–158. https://doi.org/10.17675/2305-6894-2016-5-2-4

    Article  CAS  Google Scholar 

  10. Avdeev, Ya.G., Luchkin, A.Yu., Kuznetsov, Yu.I., Gorichev, I.G., and Tyurina, M.V., Korroz.: Mater., Zashch., 2011, no. 8, pp. 20–26.

  11. Avdeev, Ya.G., Luchkin, A.Yu., and Kuznetsov, Yu.I., Prot. Met. Phys. Chem. Surf., 2013, vol. 49, no. 7, pp. 865–868. https://doi.org/10.1134/S2070205113070046

    Article  CAS  Google Scholar 

  12. Avdeev, Ya.G., Luchkin, A.Yu., Tyurina, M.V., and Kuznetsov, Yu.I., Prot. Met. Phys. Chem. Surf., 2017, vol. 53, no. 7, pp. 1247–1251. https://doi.org/10.1134/S2070205117070048

    Article  CAS  Google Scholar 

  13. Grafov, B.M. and Ukshe, E.A., Elektrokhimicheskie tsepi peremennogo toka (Electrochemical AC Circuits), Moscow: Nauka, 1973.

  14. Kichigin, V.I., Sherstobitova, I.N., and Shein, A.B., Impedans elektrokhimicheskikh i korrozionnykh sistem (Impedance of Electrochemical and Corrosion Systems), Perm: Perm State Univ., 2009.

  15. Kolpakova, N.A. and Minakova, T.S., Termodinamika i kinetika sorbtsionnogo kontsentrirovaniya (Thermodynamics and Kinetics of Sorption Concentrating), Tomsk: Izd-vo National Research Tomsk Polytechnic Univ., 2011, part 1.

  16. Krylov, O.V., Geterogennyi kataliz. Uchebnoe posobie dlya vuzov (Heterogeneous Catalysis. Student’s Book for Institutions of Higher Education), Moscow: Akademkniga, 2004.

  17. Damaskin, B.B., Petrii, O.A., and Batrakov, V.V., Adsorbtsiya organicheskikh soedinenii na elektrodakh (Organic Compounds Adsorption at Electrodes), Moscow: Nauka, 1968.

  18. Ivanov, E.S., Ingibitory korrozii metallov v kislykh sredakh. Spravochnik (Inhibitors of Metals Corrosion in Acidic Media. Handbook), Moscow: Metallurgiya, 1986.

  19. Kartashova, T.V., Vvedenskii, A.V., and Bobrinskaya, E.V., Kondens. Sredy Mezhfaznye Granitsy, 2005, vol. 7, no. 3, pp. 255–263.

    Google Scholar 

  20. Avdeev, Ya.G., Luchkin, A.Yu., Kuznetsov, Yu.I., Kazanskii, L.P., and Pronin, Yu.E., Korroz.: Mater., Zashch., 2012, no. 11, pp. 20–25.

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Funding

This study was carried out within the framework of the Program of Fundamental Scientific Investigations of State Academies of Sciences for 2013−2020 “Development of Fundamental Scientific Foundations for the Protective Effect of Metal Corrosion Inhibitors in Gas and Condensed Media, Nanocomposites, and Paint and Conversion Coatings,” state registration no. AAAA-A18-118121090043-0.

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Authors and Affiliations

  1. A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    Ya. G. Avdeev, A. Yu. Luchkin & Yu. I. Kuznetsov

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  1. Ya. G. Avdeev
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  2. A. Yu. Luchkin
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  3. Yu. I. Kuznetsov
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Correspondence to Ya. G. Avdeev.

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Translated by E. Khozina

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Avdeev, Y.G., Luchkin, A.Y. & Kuznetsov, Y.I. Adsorption of IFKhAN-92 Inhibitor on Low Carbon Steel from Sulfuric Acid Solution. Prot Met Phys Chem Surf 56, 1244–1248 (2020). https://doi.org/10.1134/S2070205120070035

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