Issue 2, 2021

Experimental evidence for onset of L1–L3M5 transition at Z = 75 through measurements of fluorescence and Coster–Kronig yields for W and Re

Abstract

In the present work, the experimental Li (i = 1–3) sub-shell fluorescence (ω1, ω2, ω3) and Coster–Kronig (f12, f13, f23) yields for W and Re have been deduced from synchrotron radiation induced X-ray line intensities measured at different incident energies across the Li absorption edge energies of both the elements employing two sets of photoionization cross sections based on the non-relativistic Hartree–Fock–Slater model and the self-consistent Dirac–Hartree–Fock model. These deduced yields have been compared with the Dirac–Hartree–Slater model based theoretical values, the semi-empirical values tabulated by Krause and the recommended values tabulated by Campbell. The present investigation provided reliable experimental evidence indicating the onset of intense L1–L3M5 Coster–Kronig transition at Z = 75.

Graphical abstract: Experimental evidence for onset of L1–L3M5 transition at Z = 75 through measurements of fluorescence and Coster–Kronig yields for W and Re

Article information

Article type
Paper
Submitted
29 Oct 2020
Accepted
09 Dec 2020
First published
10 Dec 2020

J. Anal. At. Spectrom., 2021,36, 380-389

Experimental evidence for onset of L1–L3M5 transition at Z = 75 through measurements of fluorescence and Coster–Kronig yields for W and Re

V. Ayri, S. Kaur, A. Kumar, M. Czyzycki, A. G. Karydas and S. Puri, J. Anal. At. Spectrom., 2021, 36, 380 DOI: 10.1039/D0JA00455C

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