Skip to main content
Log in

Catalytic Dehydrogenation on Carbon

  • Published:
Solid Fuel Chemistry Aims and scope Submit manuscript

Abstract

The formation of hydrocarbon dehydrogenation catalysts whose active centers are determined by the presence of oxygen-containing functional groups located on the surface of a porous carbon material rather than by their nontransition metal or metal oxide constituents was considered. The prospects of using carbon catalysts instead of traditional metal/metal oxide systems in the direct and oxidative dehydrogenation reactions of propane and ethylbenzene were shown.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

REFERENCES

  1. Chen, D.J., Wang, Y.T., and Klankermayer, J., Angew. Chem., Int. Ed., 2010, vol. 49, p. 9475.

    Article  CAS  Google Scholar 

  2. Hu, Z.-P., Yang, D., Wang, Z., and Yuan, Z.-Y., Chin. J. Catal., 2019, vol. 40, p. 1233.

    Article  CAS  Google Scholar 

  3. Sun, X., Wang, R., and Su, D., Chin. J. Catal., 2013, vol. 34, p. 508.

    Article  CAS  Google Scholar 

  4. Figueiredo, J.L. and Pereira, M.F.R., Catal. Today, 2010, vol. 150, p. 2.

    Article  CAS  Google Scholar 

  5. deClippel, F., Dusselier M., Van de Vyver, S., Peng, L., Jacobs, P.A., and Sels, B.F., Green Chem., 2013, vol. 15, p. 1398.

    Article  CAS  Google Scholar 

  6. Kyotani, T., Nakazaki, S., Xu, W.-H., and Tomita, A., Carbon, 2001, vol. 39, p. 782.

    Article  CAS  Google Scholar 

  7. Rosca, I.D., Watari, F., Uo, M., and Akasaka, T., Carbon, 2005, vol. 43, p. 3124.

    Article  CAS  Google Scholar 

  8. Wang, Z., Shirley, M.D., and Meikle, S.T., Carbon, 2009, vol. 47, p. 73.

    Article  CAS  Google Scholar 

  9. Ovejero, G., Sotelo, J.L., and Romero, M.D., Ind. Eng. Chem. Res., 2006, vol. 45, p. 2206.

    Article  CAS  Google Scholar 

  10. Glebova, N.V. and Nechitailov, A.A, Techn. Phys. Lett., 2010, vol. 36, no. 10, p. 878.

    Article  CAS  Google Scholar 

  11. Datsyuk, V., Kalyva, M., and Papagelis, K., Carbon, 2008, vol. 46, p. 833.

    Article  CAS  Google Scholar 

  12. Mazov, I., Kuznetsov, V.L., and Simonova, I.A., Appl. Surf. Sci., 2012, vol. 258, p. 6272.

    Article  CAS  Google Scholar 

  13. Rasheed, A., Howe, J.Y., Dadmun, M.D., and Britt, P.F., Carbon, 2007, vol. 45, p. 1072.

    Article  CAS  Google Scholar 

  14. Osorio, A.G., Silveira, I.C.L., Bueno, V.L., and Bergmann, C.P., Appl. Surf. Sci., 2008, vol. 255, p. 2485.

    Article  CAS  Google Scholar 

  15. Boehm, H.P., Carbon, 1994, vol. 32, p. 759.

    Article  CAS  Google Scholar 

  16. Schonherr, J., Buchheim, J.R., Scholz, P., and Adelhelm, P., J. Carbon Res., 2018, vol. 4, p. 2.

    Google Scholar 

  17. Carmo, M., Linardi, M., Guilherme, J., and Poco, R., Appl. Catal. A: Gen., 2009, vol. 355, p. 132.

    Article  CAS  Google Scholar 

  18. Lin, T., Bajpai, V., Ji, T., and Dai, L., Aust. J. Chem., 2003, vol. 56, p. 635.

    Article  CAS  Google Scholar 

  19. Smith, M.R., Jr., Hedges, S.W., and La Count, R., Carbon, 2003, vol. 41, p. 1221.

    Article  CAS  Google Scholar 

  20. Huang, J.-Q., Zhang, Q., Zhao, M.-Q., and Wei, F., Carbon, 2010, vol. 48, p. 1441.

    Article  CAS  Google Scholar 

  21. Ran, M., Sun, W., and Liu, Y., J. Solid State Chem., 2013, vol. 197, p. 517.

    Article  CAS  Google Scholar 

  22. Ajayan, P.M., Ebbesen, T.W., and Ichihashi, T., Nature, 1993, vol. 362, p. 522.

    Article  CAS  Google Scholar 

  23. Yao, V., Lordi, S.X.C., and Ma, E., J. Mater. Res., 1998, vol. 13, p. 2432.

    Article  CAS  Google Scholar 

  24. Solhy, A., Machado, B.F., and Beausoleil, J., Carbon, 2008, vol. 46, p. 1194.

    Article  CAS  Google Scholar 

  25. Cataldo, F.A., Fullerenes, Nanot. Carbon Nanostruct., 2008, vol. 16, p. 1.

    Article  CAS  Google Scholar 

  26. Simmons, J.M., Nichols, B.M., and Baker, S.E., J. Phys. Chem. B, 2006, vol. 110, p. 7113.

    Article  CAS  PubMed  Google Scholar 

  27. Peng, K., Liu, L.-Q., and Li, H., Carbon, 2011, p. 70.

  28. Tang, L., Zhang, H., and Han, J.-H., Compos. Sci. Technol., 2011, vol. 72, p. 7.

    Article  CAS  Google Scholar 

  29. Kokhanovskaya, O.A. and Likholobov, V.A., AIP Conf. Proc., 2019, vol. 2143, p. 20032.

    Article  CAS  Google Scholar 

  30. Baklanova, O.N., Drozdov, V.A., Lavrenov, A.V., Vasilevich, A.V., Muromtsev, I.V., Trenikhin, M.V., Arbuzov, A.B., Likholobov, V.A., and Gorbunova, O.V., J. Alloy. Comp., 2015, vol. 646, p. 145.

    Article  CAS  Google Scholar 

  31. Baklanova, O.N., Knyazheva, O.A., Lavrenov, A.V., P’yanova, L.G., Puchkov, S.S., Kudrya, E.N., Arbuzov, A.B., Mitryaeva, N.S., and Russkikh, G.S., Russ. J. Appl. Chem., 2017, vol. 90, p. 1982. https://doi.org/10.1134/S1070427217120138

    Article  CAS  Google Scholar 

  32. Baklanova, O.N., Knyazheva, O.A., Lavrenov, A.V., Drozdov, V.A., Trenikhin, M.V., Arbuzov, A.B., Kuznetsova, Yu.V., and Rempel, A.A., Micropor. Mesopor. Mater., 2019, vol. 279, p. 193.

    Article  CAS  Google Scholar 

  33. Figueiredo, J., Pereira, M.F.R., Freitas, M.M.A., and Oґrfao, J.J.M., Carbon, 1999, vol. 37, p. 1379.

    Article  CAS  Google Scholar 

  34. Ferjancic, Z., Matovic, R., and Bihelovic, F., J. Serb. Chem. Soc., 2011, vol. 76, p. 757.

    Article  CAS  Google Scholar 

  35. Mahardiani, L., Saputro, S., Baskoro, F., Zinki, N.M., and Taufiq, M. IOP Conf. Ser.: Mater. Sci. Eng., 2019, vol. 578, p. 012003.

  36. Polyanskaya, E.M. and Taran, O.P., Vestn. Tomsk. Gos. Univ., Khim., 2017, no. 10, p. 6.

  37. Rey, A., Faraldos, M., Bahamonde, A., and Casas, J.A., Ind. Eng. Chem. Res., 2008, vol. 47, p. 8166.

    Article  CAS  Google Scholar 

  38. Zhou, J.-H., Dui, Z.-J., Zhu, J., Li, P., Chen, D., Dai, Y.-C., and Yuan, W.-K., Carbon, 2007, vol. 45, p. 785.

    Article  CAS  Google Scholar 

  39. Keleme, S.R. and Freund, H., Energy Fuels, 1988, vol. 2, p. 111.

    Article  Google Scholar 

  40. Georgiou, P., Walton, J., and Simtzis, J., Electochim. Acta, 2010, vol. 55, p. 1207.

    Article  CAS  Google Scholar 

  41. Desimoni, E., Casella, G.L., Morone, A., and Salvi, A.M., Surf. Interface Anal., 1990, vol. 15, p. 627.

    Article  CAS  Google Scholar 

  42. Rosenthal, D., Ruta, M., Schlogl, R., and Kiwi-Minsker, L., Carbon, 2010, vol. 48, p. 1835.

    Article  CAS  Google Scholar 

  43. Jiang, F., Zeng, L., Li, S., Liu, G., Wang, S., and Gong, J., ACS Catal., 2014, vol. 5, p. 438.

    Article  CAS  Google Scholar 

  44. Nawaz, Z., Rev. Chem. Eng., 2015, vol. 31, p. 413.

    Article  CAS  Google Scholar 

  45. Sun, Y.-P., Fu, K., Lin, Y., and Huang, W., Acc. Chem. Res., 2002, vol. 35, p. 1096.

    Article  CAS  PubMed  Google Scholar 

  46. Liu, L., Deng, Q.F., Agula, B., Zhao, X., Ren, T.Z., and Yuan, Z.Y., Chem. Commun., 2011, vol. 47, p. 8334.

    Article  CAS  Google Scholar 

  47. Liu, L., Deng, Q.F., Agula, B., Ren, T.Z., Liu, Y.P., Zhaorigetu, B., and Yuan, Z.Y., Catal. Today, 2012, vol. 186, p. 35.

    Article  CAS  Google Scholar 

  48. Liu, L., Deng, Q.F., Liu, Y.P., Ren, T.Z., and Yuan, Z.Y., Catal. Commun., 2011, vol. 16, p. 81.

    Article  CAS  Google Scholar 

  49. Song, Y., Liu, G., and Yuan, Z.Y., RSC Adv., 2016, vol. 6, p. 94636.

    Article  CAS  Google Scholar 

  50. Hu, Z.P., Zhao, H., Chen, C., and Yuan, Z.Y., Catal. Today, 2018, vol. 316, p. 214.

    Article  CAS  Google Scholar 

  51. Hu, Z.P., Zhang, L.F., Wang, Z., and Yuan, Z.Y., J. Chem. Technol. Biotechnol., 2018, vol. 93, p. 3410.

    Article  CAS  Google Scholar 

  52. Li, L., Zhu, W., Liu, Y., Shi, L., Liu, H., Ni, Y., Liu, S., Zhou, H., and Liu, Z., RSC Adv., 2015, vol. 5, p. 56304.

    Article  CAS  Google Scholar 

  53. Mestl, G., Maksimova, N., Keller, N., Roddatis, V., and Schlogl, R., Angew. Chem., Int. Ed. Engl., 2001, vol. 40, p. 2066.

    Article  CAS  Google Scholar 

  54. Keller, N., Maksimova, N., Roddatis, V., Schuler, M., Mestl, G., Butenko, Y., Kuznetsov, V., and Schlogl, R., Angew. Chem., Int. Ed. Engl., 2002, vol. 41, p. 1885.

    Article  CAS  Google Scholar 

  55. Su, D., Maksimova, N., Delgado, J., Keller, N., Mestl, G., Ledoux, M., and Schlogl, R., Catal. Today, 2005, vol. 102–103, pp. 110–114.

    Article  CAS  Google Scholar 

  56. Su, D., Maksimova, N., Mestl, G., Kuznetsov, V., Keller, V., Schlogl, R., and Keller, N., Carbon, 2007, vol. 45, p. 2145.

    Article  CAS  Google Scholar 

  57. Zhang, J., Su, D., Zhang, A., Di, W., Schlogl, R., and Hebert, C., Angew. Chem., Int. Ed. Engl., 2007, vol. 46, p. 7319.

    Article  CAS  Google Scholar 

  58. Yu, D.S., Nagelli, E., Du, F., and Dai, L.M., J. Phys. Chem. Lett., 2010, vol. 1, p. 2165.

    Article  CAS  Google Scholar 

  59. Pereira, M.F.R., Orfao, J.J.M., and Figueiredo, J.L., Appl. Catal. A, 1999, vol. 184, p. 153.

    Article  CAS  Google Scholar 

  60. Liu, X., Su, D., and Schlogl, R., Carbon, 2008, vol. 46, p. 547.

    Article  CAS  Google Scholar 

  61. Frank, B., Zhang, J., Blume, R., Schlogl, R., and Su, D., Angew. Chem., Int. Ed. Engl., 2009, vol. 48, p. 6913.

    Article  CAS  Google Scholar 

  62. Frank, B., Morassutto, M., Schomacker, R., Schlogl, R., and Su, D., Chem. Cat. Chem., 2010, vol. 2, p. 644.

    CAS  Google Scholar 

Download references

Funding

This work was carried out at the Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences within the framework of a state contract (project no. AAAA-A19-119050790074-9).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to O. A. Knyazheva, O. N. Baklanova or A. V. Lavrenov.

Additional information

Translated by V. Makhlyarchuk

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Knyazheva, O.A., Baklanova, O.N. & Lavrenov, A.V. Catalytic Dehydrogenation on Carbon. Solid Fuel Chem. 54, 345–353 (2020). https://doi.org/10.3103/S0361521920060051

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S0361521920060051

Keywords:

Navigation