Abstract
Based on a comparison of the spectral data of dimethylsulfonium derivatives of polyhedral boron hydrides and dimethylsulfide complexes of tantalum and niobium pentahalides, an analogy has been recognized between the Lewis acidity of quasiborinium cations formed upon the removal of the hydride ion from polyhedral boron hydrides, on the one hand, and tantalum and niobium pentahalides, on the other.
Similar content being viewed by others
REFERENCES
I. B. Sivaev, V. I. Bregadze, and S. Sjoberg, Collect. Czech. Chem. Commun. 67, 679 (2002). https://doi.org/10.1135/cccc20020679
I. B. Sivaev, N. Yu. Kulikova, E. A. Nizhnik, et al., J. Organomet. Chem. 693, 519 (2008). https://doi.org/10.1016/j.jorganchem.2007.11.027
I. B. Sivaev, A. V. Prikaznov, and D. Naoufal, Collect. Czech. Chem. Commun. 75, 1149 (2010). https://doi.org/10.1135/cccc2010054
K. Yu. Zhizhin, A. P. Zhdanov, and N. T. Kuznetsov, Russ. J. Inorg. Chem. 55, 2089 (2010). https://doi.org/10.1134/S0036023610140019
E. J. M. Hamilton, H. T. Leung, R. G. Kultyshev, et al., Inorg. Chem. 51, 2374 (2012). https://doi.org/10.1021/ic2023709
I. N. Klyukin, A. S. Kubasov, I. P. Limarev, et al., Polyhedron 101, 215 (2015). https://doi.org/10.1016/j.poly.2015.09.025
A. S. Kubasov, E. S. Turishev, I. N. Polyakova, et al., J. Organomet. Chem. 828, 106 (2017). https://doi.org/10.1016/j.jorganchem.2016.11.035
I. B. Sivaev and V. I. Bregadze, Collect. Czech. Chem. Commun. 64, 783 (1999). https://doi.org/10.1135/cccc19990783
B. P. Dash, R. Satapathy, B. R. Swain, et al., J. Organomet. Chem. 849–850, 170 (2017). https://doi.org/10.1016/j.jorganchem.2017.04.006
M. Bakardjiev, S. El Anwar, D. Bavol, et al., Molecules 25, 814 (2020). https://doi.org/10.3390/molecules25040814
V. I. Bregadze, S. V. Timofeev, I. B. Sivaev, and I. A. Lobanova, Russ. Chem. Rev. 73, 433 (2004). https://doi.org/10.1070/RC2004v073n05ABEH000868
T. L. Breen and D. W. Stephan, Inorg. Chem. 31, 4019 (1992). https://doi.org/10.1021/ic00045a032
O. J. Metters, S. J. K. Forrest, H. A. Sparkes, et al., J. Am. Chem. Soc. 138, 1994 (2016). https://doi.org/10.1021/jacs.5b12536
L. R. Avens, D. M. Barnhart, C. J. Burns, and S. D. McKee, Inorg. Chem. 35, 537 (1996). https://pubs.acs.org/doi/10.1021/ic9505211
N. E. Travia, M. J. Monreal, B. L. Scott, and J. L. Kiplinger, Dalton Trans. 41, 1451 (2012). https://doi.org/10.1039/C2DT31676E
V. Yu. Kukushkin and A. J. L. Pombeiro, Chem. Rev. 102, 1771 (2002). https://doi.org/10.1021/cr0103266
V. Yu. Kukushkin and A. J. L. Pombeiro, Inorg. Chim. Acta 358, 1 (2005). https://doi.org/10.1016/j.ica.2004.04.029
N. A. Bokach and V. Yu. Kukushkin, Russ. Chem. Rev. 74, 153 (2005). https://doi.org/10.1070/RC2005v074n02ABEH000979
A. A. Semioshkin, I. B. Sivaev, and V. I. Bregadze, Dalton Trans., No. 8, 977 (2008). https://doi.org/10.1039/b715363e
I. B. Sivaev and V. I. Bregadze, Boron Science: New Technologies and Applications, Ed. by N. S. Hosmane (CRC Press, Boca Raton, FL, 2012). https://doi.org/10.1201/b11199
A. V. Prikaznov, A. V. Shmal’ko, I. B. Sivaev, et al., Polyhedron 30, 1494 (2011). https://doi.org/10.1016/j.poly.2011.02.055
A. V. Prikaznov, Yu. N. Las’kova, A. A. Semioshkin, et al., Russ. Chem. Bull. 60, 2250 (2011). https://doi.org/10.1007/s11172-011-0392-4
A. S. Kubasov, E. Yu. Matveev, V. M. Retivov, et al., Russ. Chem. Bull. 63, 187 (2014). https://doi.org/10.1007/s11172-014-0412-2
D. Imperio, B. Muz, A. K. Azab, et al., Eur. J. Org. Chem, No. 43, 7228 (2019). https://doi.org/10.1002/ejoc.201901412
M. Yu. Stogniy, S. A. Erokhina, I. B. Sivaev, and V. I. Bregadze, Phosphorus, Sulfur Silicon Relat. Elem. 194, 983 (2019). https://doi.org/10.1080/10426507.2019.1631312
M. Yu. Stogniy, S. A. Erokhina, A. A. Anisimov, et al., Polyhedron 174, 114170 (2019). https://doi.org/10.1016/j.poly.2019.114170
M. Yu. Stogniy, S. A. Erokhina, K. Yu. Suponitsky, et al., J. Organomet. Chem. 909, 121111 (2020). https://doi.org/10.1016/j.jorganchem.2020.121111
A. P. Zhdanov, A. V. Nelyubin, I. N. Klyukin, et al., Russ. J. Inorg. Chem. 64, 841 (2019). https://doi.org/10.1134/S0036023619070180
A. V. Nelyubin, I. N. Klyukin, A. P. Zhdanov, et al., Russ. J. Inorg. Chem. 64, 1499 (2019). https://doi.org/10.1134/S003602361912012X
R. B. King, Chem. Rev. 101, 1119 (2001). https://doi.org/10.1021/cr000442t
Z. Chen and R. B. King, Chem. Rev. 105, 3613 (2005). https://doi.org/10.1021/cr0300892
C. J. Forsyth and T. J. Murray, Science of Synthesis: Hoyben–Weyl Methods of Molecular Transformations, Vol. 37: Compounds with One Saturated Carbon–Heteroatom Bond, Ed. by S. J. Forsyth (Georg Thieme, Stuttgart, 2008). https://doi.org/10.1055/b-0035-118648
T. van Dijk, J. C. Slootweg, and K. Lammertsm, Org. Biomol. Chem. 15, 10134 (2017). https://doi.org/10.1039/C7OB02533E
I. B. Sivaev, A. V. Prikaznov, and S. A. Anufriev, J. Organomet. Chem. 747, 254 (2013). https://doi.org/10.1016/j.jorganchem.2013.04.001
P. Kölle and H. Nöth, Chem. Rev. 85, 399 (1985). https://doi.org/10.1021/cr00069a004
W. E. Piers, S. C. Bourke, and K. D. Conroy, Angew. Chem., Int. Ed. Engl. 44, 5016 (2005). https://doi.org/10.1002/anie.200500402
I. B. Sivaev and V. I. Bregadze, Coord. Chem. Rev. 270–271, 75 (2014). https://doi.org/10.1016/j.ccr.2013.10.017
V. Gutmann, Coord. Chem. Rev. 18, 225 (1976). https://doi.org/10.1016/S0010-8545(00)82045-7
M. A. Beckett, G. C. Strickland, J. R. Holland, and K. S. Varma, Polym. Commun. 37, 4629 (1996). https://doi.org/10.1016/0032-3861(96)00323-0
A. L. Liberman-Martin, R. G. Bergman, and T. D. Tilley, J. Am. Chem. Soc. 137, 5328 (2015). https://doi.org/10.1021/jacs.5b02807
R. Kannan, S. Kumar, A. P. Andrews, et al., Inorg. Chem. 56, 9391 (2017). https://doi.org/10.1021/acs.inorgchem.7b01243
J. J. Jennings, B. W. Wigman, B. M. Armstrong, and A. K. Franz, Org. Chem. 84, 15845 (2019). https://doi.org/10.1021/acs.joc.9b02107
I. D. Kosenko, I. A. Lobanova, I. A. Godovikov, et al., J. Organomet. Chem. 721–722, 70 (2012). https://doi.org/10.1016/j.jorganchem.2012.05.045
R. F. Childs, D. L. Mulholland, and A. Nixon, Can. J. Chem. 60, 801 (1982). https://doi.org/10.1139/v82-117
G. Hilt and A. Nodling, Eur. J. Org. Chem, No. 35, 7071 (2011). https://doi.org/10.1002/ejoc.201101307
G. Hilt, F. Punner, J. Mobus, et al., Eur. J. Org. Chem. No. 30, 5962 (2011). https://doi.org/10.1002/ejoc.201101029
A. V. Shmal’ko, M. Yu. Stogniy, G. S. Kazakov, et al., Dalton Trans. 44, 9860 (2015). https://doi.org/10.1039/C5DT01293G
J. Plesek, Z. Janousek, and S. Hermanek, Collect. Czech. Chem. Commun. 43, 2862 (1978). https://doi.org/10.1135/cccc19782862
B. Gruner, J. Holub, J. Plesek, et al., Dalton Trans., No. 42, 4859 (2007). https://doi.org/10.1039/B709526K
O. Tutusaus, F. Teixidor, R. Nunez, et al., J. Organomet. Chem. 657, 247 (2002). https://doi.org/10.1016/S0022-328X(02)01541-3
G. M. Rosair, A. J. Welch, A. S. Weller, and S. K. Zahn, J. Organomet. Chem. 536–537, 299 (1997). https://doi.org/10.1016/S0022-328X(96)06740-X
S. Dunn, R. M. Garrioch, G. M. Rosair, et al., Collect. Czech. Chem. Commun. 64, 1013 (1999). https://doi.org/10.1135/cccc19991013
A. R. Kudinov, P. V. Petrovskii, V. I. Meshcheryakov, and M. I. Rybinskaya, Russ. Chem. Bull. 48, 1356 (1999). https://doi.org/10.1007/BF02495304
A. R. Kudinov, V. I. Meshcheryakov, P. V. Petrovskii, and M. I. Rybinskaya, Russ. Chem. Bull. 48, 176 (1999). https://doi.org/10.1007/BF02494424
A. R. Kudinov, D. S. Perekalin, P. V. Petrovskii, and G. V. Grintselev-Knyazev, Russ. Chem. Bull. 51, 1928 (2002). https://doi.org/10.1023/A:1021373106780
J. G. Planas, C. Viñas, F. Teixidor, et al., Eur J. Inorg. Chem, No. 20, 4193 (2005). https://doi.org/10.1002/ejic.200500470
D. A. Loginov, M. M. Vinogradov, Z. A. Starikova, and A. R. Kudinov, Russ. Chem. Bull. 62, 1262 (2013). https://doi.org/10.1007/s11172-013-0174-2
M. Corsini, S. Losi, E. Grigiotti, et al., J. Solid State Electrochem. 11, 1643 (2007). https://doi.org/10.1007/s10008-007-0324-2
S. J. Lancaster and D. L. Hughes, Dalton Trans., No. 9, 1779 (2003). https://doi.org/10.1039/B300552F
C. K. Y. A. Okio, W. Levason, F. M. Monzittu, and G. Reid, J. Organomet. Chem. 848, 232 (2017). https://doi.org/10.1016/j.jorganchem.2017.08.004
M. I. Bruce, K. Costuas, T. Davin, et al., Organometallics 24, 3864 (2005). https://doi.org/10.1021/om050293a
J. Zhang, S.-Z. Guo, Y.-B. Dong, et al., Inorg. Chem. 56, 1001 (2017). https://doi.org/10.1021/acs.inorgchem.6b02809
L. Zhang and E. Meggers, Acc. Chem. Res. 50, 320 (2017). https://doi.org/10.1021/acs.accounts.6b00586
A. Merbach and J. C. Bunzli, Helv. Chim. Acta 55, 580 (1972). https://doi.org/10.1002/hlca.19720550231
R. Good and A. E. Merbach, Helv. Chim. Acta 57, 1192 (1974). https://doi.org/10.1002/hlca.19740570430
M. Jura, W. Levason, R. Ratnani, et al., Dalton Trans. 39, 883 (2010). https://doi.org/10.1039/B916336K
S. L. Benjamin, A. Hyslop, W. Levason, and G. Reid, J. Fluorine Chem. 137, 77 (2012). https://doi.org/10.1016/j.jfluchem.2012.02.014
F. Marchetti, G. Pampaloni, and S. Zacchini, Inorg. Chem. 47, 365 (2008). https://doi.org/10.1021/ic7012254
F. Marchetti, G. Pampaloni, and S. Zacchini, Eur. J. Inorg. Chem, No. 3, 453 (2008). https://doi.org/10.1002/ejic.200700911
V. I. Bregadze, I. D. Kosenko, I. A. Lobanova, et al., Organometallics 29, 5366 (2010). https://doi.org/10.1021/om100385m
F. Marchetti, G. Pampaloni, and S. Zacchini, J. Fluorine Chem. 131, 21 (2010). https://doi.org/10.1016/j.jfluchem.2009.09.014
R. Bernard, D. Cornu, M. Perrin, et al., J. Organomet. Chem. 689, 2581 (2004). https://doi.org/10.1016/j.jorganchem.2004.05.014
I. B. Sivaev, A. A. Semioshkin, B. Brellochs, et al., Polyhedron 19, 627 (2000). https://doi.org/10.1016/S0277-5387(00)00293-X
M. Tarrés, C. Viñas, A. M. Cioran, et al., Chem.-Eur. J. 20, 15808 (2014). https://doi.org/10.1002/chem.201403424
F. Marchetti and G. Pampaloni, Chem. Commun. 48, 635 (2012). https://doi.org/10.1039/C1CC14592D
M. F. Hawthorne, K. Shelly, and F. Li, Chem. Commun., No. 6, 547 (2002). https://doi.org/10.1039/B110076A
V. V. Avdeeva, E. A. Malinina, L. V. Goeva, and N. T. Kuznetsov, Doklady Chem. 474, 141 (2017). https://doi.org/10.1134/S0012500817060052
O. Volkov, C. Hu, U. Kolle, and P. Paetzold, Z. Anorg. Allg. Chem. 631, 1909 (2005). https://doi.org/10.1002/zaac.200500149
V. V. Avdeeva, E. A. Malinina, O. N. Belousova, et al., Russ. J. Inorg. Chem. 56, 524 (2011). https://doi.org/10.1134/S003602361104005X
A. N. Nesmeyanov, On the Swing of the Century (Moskvovedenie, Moscow, 2018) [in Russian].
Author information
Authors and Affiliations
Corresponding author
Additional information
I bring this fact with a radiant face As a valuable contribution to science. Sasha Chorny, “Koumiss Verses” (1909)
Translated by V. Avdeeva
Rights and permissions
About this article
Cite this article
Sivaev, I.B. Some Analogies in Inorganic Chemistry (in memory of A. A. Pasynskii). Russ. J. Inorg. Chem. 65, 1854–1861 (2020). https://doi.org/10.1134/S0036023620120165
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023620120165