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Some Analogies in Inorganic Chemistry (in memory of A. A. Pasynskii)

  • THEORETICAL INORGANIC CHEMISTRY
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Abstract

Based on a comparison of the spectral data of dimethylsulfonium derivatives of polyhedral boron hydrides and dimethylsulfide complexes of tantalum and niobium pentahalides, an analogy has been recognized between the Lewis acidity of quasiborinium cations formed upon the removal of the hydride ion from polyhedral boron hydrides, on the one hand, and tantalum and niobium pentahalides, on the other.

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  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    I. B. Sivaev

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I bring this fact with a radiant face As a valuable contribution to science. Sasha Chorny, “Koumiss Verses” (1909)

Translated by V. Avdeeva

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Sivaev, I.B. Some Analogies in Inorganic Chemistry (in memory of A. A. Pasynskii). Russ. J. Inorg. Chem. 65, 1854–1861 (2020). https://doi.org/10.1134/S0036023620120165

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