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Volumetric Properties and Ion Interactions for Sodium Hypophosphite Aqueous Solution from 283.15 to 363.15 K at 101.325 kPa

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Abstract

Densities of sodium hypophosphite aqueous solution (NaH2PO2) with the molality varied from 1.019143 to 10.43887 mol kg–1 at temperature intervals of 5 K range from 283.15 to 363.15 K at 101.325 kPa were measured by a precise Anton Paar Digital vibrating-tube densimeter. From the density data, the thermal expansion coefficients, apparent volume and partial molar volumes were obtained. According to the Pitzer ion-interaction equation of the apparent molar volumes, the Pitzer single-salt parameters and their temperature-dependent correlation for NaH2PO2 were firstly obtained by the least-squares method. The model shown that apparent molar volumes agree well with the experimental values, which indicated the single salt parameters and the temperature-dependent formula are reliable.

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ACKNOWLEDGMENTS

Financial supports from the National Natural Science of China (U1607123 and 21773170), the Key Projects of Natural Science Foundation of Tianjin (18JCZDJC10040) and the Yangtze Scholars and Innovative Research Team in Chinese University (IRT_17R81) are acknowledged.

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Authors and Affiliations

  1. College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, 300457, Tianjin, China

    Umarbek Alimov, Kaiyu Zhao, Yafei Guo & Tianlong Deng

  2. Institute of General and Inorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan, 100170, Tashkent, Uzbekistan

    Umarbek Alimov

  3. School of Chemistry Engineering, Linyi University, 276000, Linyi, China

    Lingzong Meng

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  1. Umarbek Alimov
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  2. Kaiyu Zhao
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Correspondence to Tianlong Deng.

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Umarbek Alimov, Zhao, K., Guo, Y. et al. Volumetric Properties and Ion Interactions for Sodium Hypophosphite Aqueous Solution from 283.15 to 363.15 K at 101.325 kPa. Russ. J. Inorg. Chem. 65, 1913–1921 (2020). https://doi.org/10.1134/S0036023620120025

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