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SYNTHESIS AND CRYSTAL STRUCTURE OF THE Ni(II) COMPLEX WITH (4Z)-4-[(2-DIETHYLAMINOETHYLAMINO)METHYLENE]- 5-METHYL-2-PHENYLPYRAZOLE-3-ONE

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Abstract

The Ni(II) complex based on (4Z)-4-[(2-diethylaminoethylamino)methylene]-5-methyl-2-phenylpyrazole-3-one (HL), being the condensation product of 5-hydroxy-3-methyl-1-phenylpyrazole-4-carbaldehyde with N,N-diethylethylenediamine, is synthesized. By the elemental analysis and IR spectroscopy it is found that the nickel complex has the composition Ni(L)CH3COO·CH3OH·H2O. The crystal and molecular structures of the complex are determined by single crystal Xray diffraction (XRD). From the XRD data it follows that the monochelate Ni(II) complex has a distorted octahedral structure due to bonds with a monodentate acetate anion and methanol and water molecules.

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Funding

The study was supported by the Ministry of Science and Higher Education of the Russian Federation (State Task in the Scientific Activity Area at the Southern Federal University, 2020) and RUDN Program “5-100”.

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Authors and Affiliations

  1. Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia

    A. S. Burlov, Yu. V. Koshchienko, A. I. Uraev, E. V. Korshunova & M. S. Milutka

  2. Research Institute of Physics, Southern Federal University, Rostov-on-Don, Russia

    V. G. Vlasenko

  3. Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia

    D. A. Garnovskii

  4. People’s Friendship University of Russia, Moscow, Russia

    I. V. Linko & V. N. Khrustalev

  5. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia

    V. N. Khrustalev

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  1. A. S. Burlov
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  2. V. G. Vlasenko
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  3. Yu. V. Koshchienko
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Correspondence to A. S. Burlov.

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Burlov, A.S., Vlasenko, V.G., Koshchienko, Y.V. et al. SYNTHESIS AND CRYSTAL STRUCTURE OF THE Ni(II) COMPLEX WITH (4Z)-4-[(2-DIETHYLAMINOETHYLAMINO)METHYLENE]- 5-METHYL-2-PHENYLPYRAZOLE-3-ONE. J Struct Chem 61, 1599–1605 (2020). https://doi.org/10.1134/S0022476620100121

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