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TUNGSTEN PEROXOPOLYOXO COMPLEXES ARE PROSPECTIVE CATALYSTS FOR THE OXIDATION OF ORGANIC COMPOUNDS. I.  STRUCTURE OF COMPLEX [(BUn)4N]3{PO4[WO(O2)2]4} ACCORDING TO SMALL-ANGLE X-RAY SCATTERING

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Abstract

The structure of the H3PW12O40 oxometalate precursor and that of the [(Bun)4N]3{PO4[WO(O2)2]4} peroxo complex which was synthesized from it are studied by small-angle X-ray scattering (SAXS) in solutions. It is shown that the structure of H3PW12O40 is partially destroyed as a result of the interaction with hydrogen peroxide to form the {PO4[WO(O2)2]4}3– anion. The synthesized peroxo complex [(Bun)4N]3{PO4[WO(O2)2]4} in toluene occurs as individual molecules, whereas its molecules are partially aggregated to form 1.6 nm particles in acetonitrile solution.

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Funding

The reported study was funded by RFBR (project number № 19-03-00202а) and conducted within the Government Contract of Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences (projects АААА-А17-117041710081-1 and АААА-А17-117041710079-8).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    Yu. V. Larichev, N. V. Selivanova, P. V. Berdnikova, F. V. Tuzikov & Z. P. Pai

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  1. Yu. V. Larichev
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  2. N. V. Selivanova
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  3. P. V. Berdnikova
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  4. F. V. Tuzikov
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  5. Z. P. Pai
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Correspondence to Yu. V. Larichev.

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Larichev, Y.V., Selivanova, N.V., Berdnikova, P.V. et al. TUNGSTEN PEROXOPOLYOXO COMPLEXES ARE PROSPECTIVE CATALYSTS FOR THE OXIDATION OF ORGANIC COMPOUNDS. I.  STRUCTURE OF COMPLEX [(BUn)4N]3{PO4[WO(O2)2]4} ACCORDING TO SMALL-ANGLE X-RAY SCATTERING. J Struct Chem 61, 1568–1574 (2020). https://doi.org/10.1134/S002247662010008X

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