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NEW γ-SUBSTITUTED β-DIKETONATES OF Al(III), Fe(III), AND Cu(II)

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Abstract

The structures of two Al(III) and Fe(III) β-diketonates with a γ-substituted ligand are studied by single crystal X-ray diffraction at 150(2) K. Crystallographic data for Al(γ-Me-hd)3 (I) are: space group \(P\bar{1}\), a = 10.855(1) Å, b = 11.129(1) Å, с = 11.894(1) Å, α = 85.634(3)°, F0200062 = 73.118(3)°, γ = 66.771(3)°, V = 1262.2(2) Å3, Z = 2, R1 = 0.0438. For Fe(γ-Me-hd)3 (II): space group P21/с, a = 10.0374(5) Å, b = 17.0798(7) Å, с = 15.7213(6) Å, F0200062 = 107.459(1)°, V = 2571.1(2) Å3, Z = 4, R1 = 0.0364. Compounds I and II are isotypical because their molecules have the same structure but crystallize in different crystal systems. The crystal structures of I and II are molecular and consist of discrete M(γ-Me-hd)3 (M = Al, Fe) molecules. Thermogravimetric studies show that complexes I and II are similarly volatile. For Cu(γ-Me-hd)2 complex (III) the saturated vapor pressure is measured by the Knudsen method in the temperature range 100-150 °C. Sublimation thermodynamic parameters are found and vapor thermolysis is investigated.

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REFERENCES

  1. Chemical Vapor Deposition: Precursors, Processes and Applications / Ed. I. C. Jones and M. L. Hitchman. RSC Publishing, 2009.

  2. The Chemistry of Metal CVD / Eds. T. Kodas and M. Hampden-Smith. VCH: Weinhem, 1994.

  3. I. K. Igumenov, Y. V. Chumachenko, S. V. Zemskov. In: Problemy Khimii i Primeneniya β-diketonatov Metallov (Problems of Chemistry and Application of Metal β-Diketonates) [in Russian] / Ed. V. I. Spitsyn. Nauka: Moscow, 1982, 100.

  4. S. F. Gromilov and I. A. Baidina. J. Struct. Chem., 2004, 45(6), 1031.

  5. R. W. Moshier and R. E. Sievers. Gas Chromotography of Metal Chelates. Pergamon Press: Oxford, UK, 1967.

  6. P. A. Stabnikov, A. I. Smolentsev, N. V. Pervukhina, O. S. Koscheeva, L. N. Komissarova, and S. V. Borisov. J. Struct. Chem., 2011, 52(1), 118.

  7. S. G. Konstantinov, G. P. Dudchik, and O. G. Poliachenok. Teoreticheskaya i Prikladnaya Khimiya β-Diketonatov Metallov (Theoretical and Applied Chemistry of Metal β-Diketonates) [in Russian]. Nauka; Moscow, 1985.

  8. G. I. Zharkova, P. A. Stabnikov, S. A. Sysoev, and I. K. Igumenov. J. Struct. Chem., 2005, 46(2), 320–327.

  9. V. A. Varnek, I. K. Igumenov, P. A. Stabnikov, and L. N. Mazalov. J. Struct. Chem., 2001, 42(5), 860–863

  10. I. K. Igumenov, V. R. Belosludov, and T. V. Basova. In: Application of Thermodynamics to Biological and Materials Science / Ed. T. Mizutani. InTech; Rijeka, Croatia, 2011.

  11. V. D. Vreshch, A. B. Lysenko, A. N. Chernega, J. A. K. Howard, H. Krautscheid, J. Sieler, and K. V. Domasevitch. Dalton Trans., 2004, 2899.

  12. B. F. Abrahams, B. F. Hoskins, D. W. McFadyen, and L. C. Perrin. Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1998, 54, 1807.

  13. J. W. Carmichael, L. K. Steinrauf, and R. L. Belford. J. Chem. Phys., 1965, 43, 3959.

  14. A. Dohring, R. Goddard, P. W. Jolly, C. Kruger, and V. R. Polyakov. Inorg. Chem., 1997, 36, 177.

  15. I. Robertson and M. R. Truter. J. Chem. Soc. A, 1967, 309.

  16. M. A. G. Berg, M. K. Ritchie, and J. S. Merola. Polyhedron, 2012, 38, 126.

  17. R. H. Holm, G. W. Everett, and A. Chakravorty. Prog. Inorg. Chem., 1966, 7, 83.

  18. I. A. Baidina, P. A. Stabnikov, A. D. Vasiliev, S. A. Gromilov, and I. K. Igumenov. J. Struct. Chem., 2004, 45(4), 671.

  19. APEX2 (Version 1.08), SAINT (Version 7.03), and SADABS (Version 2.11). Bruker Advanced X-ray Solutions: Madison, Wisconsin, USA, 2004.

  20. G. M. Sheldrick. Acta Crystallogr., Sect. A, 2008, 64, 112.

  21. V. Krisyuk, I. Baidina, A. Turgambaeva, S. Urkasym kyzy, I. Korolkov, T. Koretskaya, and I. Igumenov. J. Organomet. Chem., 2016, 819, 115.

  22. P. P. Semyannikov, I. К. Igumenov, S. V. Trubin, T. P. Chusova, and Z. I. Semenova. Thermochim. Acta, 2005, 432, 91.

  23. F. H. Allen, O. Kennard, D. G. Watson, L. Brammer, A. G. Orpen, and R. Taylor. J. Chem. Soc., Perkin Trans. 2, 1987, S1.

  24. S. P. Babailov and Ju. G. Kriger. J. Struct. Chem., 1998, 39(4), 714.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    P. A. Stabnikov, N. I. Alferova, I. V. Korolkov, N. V. Pervukhina, S. V. Trubin, S. P. Babailov & A. E. Turgambaeva

  2. Novosibirsk State University, Novosibirsk, Russia

    I. V. Korolkov & N. V. Pervukhina

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  1. P. A. Stabnikov
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  2. N. I. Alferova
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  3. I. V. Korolkov
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  4. N. V. Pervukhina
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  5. S. V. Trubin
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  6. S. P. Babailov
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  7. A. E. Turgambaeva
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Correspondence to P. A. Stabnikov.

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Stabnikov, P.A., Alferova, N.I., Korolkov, I.V. et al. NEW γ-SUBSTITUTED β-DIKETONATES OF Al(III), Fe(III), AND Cu(II). J Struct Chem 61, 1615–1623 (2020). https://doi.org/10.1134/S0022476620100145

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