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Reversible Phase Transition in the MoO2Cl2(DME) Structure with the Retention of the Crystal System and Space Group

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Abstract

A completely reversible phase transition in the MoO2Cl2(DME) compound with the retention of the crystal system and space group is discovered and studied. The transition is also accompanied by the doubling of the unit cell parameter and occurs without single crystal destruction. The crystal structure of the MoO2Cl2(DME) complex are determined at 160 (modification I) and 150 K (modification II) (CIF files CCDC nos. 1997752 and 1997751, respectively).

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ACKNOWLEDGMENTS

The authors are grateful to Prof. J.A.K. Howard (Durham University, Great Britain) for the kindly presented opportunity to use the diffractometric equipment and O.V. Dolomanov (Moscow State University, Russia) for fruitful discussion.

Funding

The phase transition was studied in terms of state assignment of the Center for Collective Use of the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. V. Churakov

  2. Fachbereich Chemie der Philipps-Universität Marburg, Marburg/Lahn, Deutschland

    K. A. Rufanov

Authors
  1. A. V. Churakov
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  2. K. A. Rufanov
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Corresponding author

Correspondence to A. V. Churakov.

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The authors declare that they have no conflicts of interest.

Additional information

The authors congratulate Academician of the Russian Academy of Sciences I.L. Eremenko on his 70th jubilee

Translated by E. Yablonskaya

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Churakov, A.V., Rufanov, K.A. Reversible Phase Transition in the MoO2Cl2(DME) Structure with the Retention of the Crystal System and Space Group. Russ J Coord Chem 46, 812–816 (2020). https://doi.org/10.1134/S1070328420110020

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