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Adsorption Isotherms of Limonene Enantiomers on the Surfaces of Cyanuric Acid, Cytosine, Ionol, and Adenine Dinitrate Crystals

  • PHYSICAL CHEMISTRY OF SURFACE PHENOMENA
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Abstract

Adsorption isotherms are obtained for limonene enantiomers on the surfaces of ionol and adenine dinitrate crystals, and for the crystalline structures of cytosine and cyanuric acid deposited on surfaces of graphitized thermal carbon black. Viedma ripening conditions are used to induce chirality in the crystals. It is found that the isotherms of limonene enantiomers differ from one another during adsorption on all four samples. The shape of the adsorption isotherms also differs for cytosine and cyanuric acid, indicating different mechanisms of adsorption. It is assumed that one enantiomer is partially adsorbed in the cavity of the supramolecular structure of cytosine and cyanuric acid, while the second is not. The degree of surface filling at which different adsorption isotherms are observed shows that the stability of the layers of enantiomers on the topologically chiral surface of the crystals differs.

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Funding

This work was financially supported be the Russian Science Foundation, project no. 19-73-10079.

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Authors and Affiliations

  1. Bashkir State University, 450076, Ufa, Russia

    V. Yu. Guskov, G. A. Ramazanova, D. A. Allayarova, A. Z. Arslanova, G. R. Yakshibaeva, G. Kh. Khamzina & E. A. Dolbintseva

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  1. V. Yu. Guskov
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  2. G. A. Ramazanova
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  3. D. A. Allayarova
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  4. A. Z. Arslanova
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  5. G. R. Yakshibaeva
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  6. G. Kh. Khamzina
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  7. E. A. Dolbintseva
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Correspondence to D. A. Allayarova.

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Translated by A. Tulyabaev

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Guskov, V.Y., Ramazanova, G.A., Allayarova, D.A. et al. Adsorption Isotherms of Limonene Enantiomers on the Surfaces of Cyanuric Acid, Cytosine, Ionol, and Adenine Dinitrate Crystals. Russ. J. Phys. Chem. 94, 2331–2336 (2020). https://doi.org/10.1134/S0036024420110102

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