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Synthesis and characterization of the properties of perfluorinated copolymer of perfluoro-2-ethyl-2-methyldioxole and perfluoro-n-propyl vinyl ether

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Abstract

A copolymer of perfluoro-2-ethyl-2-methyldioxole and perfiuoropropyl vinyl ether was prepared by the method of high-pressure polymerization. The synthesized polymer has high optical transparency, a low refractive index, and a low material dispersion in the telecommunication wavelength ranges near 0.85, 1.3, and 1.5 µm. In addition, the polymer is predominantly amorphous and has high glass-transition and decomposition temperatures. The synthesized polymer is able to film formation and promising for the design and construction of high-speed optoelectronic printed circuit boards in which a metallic conductor-based electrical data bus is supplemented with an optical data bus based on a polymeric waveguide array. Films with a thickness of 4–8 µm were fabricated from the synthesized polymer by centrifuging. The polymer was characterized by DSC, DTGA, TMA, X-ray diffraction analysis (XRD), and IR spectroscopy.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    Yu. E. Pogodina, E. V. Polunin, A. A. Yarosh & I. V. Zavarzin

  2. Federal Scientific Research Center “Crystallography and Photonics,” Institute of Photonic Technologies, Russian Academy of Sciences, 2 ul. Pionerskaya, Troitsk, 108840, Moscow, Russian Federation

    S. I. Molchanova & V. I. Sokolov

Authors
  1. Yu. E. Pogodina
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  2. E. V. Polunin
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  3. S. I. Molchanova
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  4. V. I. Sokolov
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  5. A. A. Yarosh
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  6. I. V. Zavarzin
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Corresponding author

Correspondence to Yu. E. Pogodina.

Additional information

This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation in the framework of state assignment of the Federal Research Center “Crystallography and Photonics” of the Russian Academy of Sciences (development of methods enhancing the optical transparence of perfluorinated polymers) and by the Russian Foundation for Basic Research (Project No. 18-29-20102, synthesis of copolymers; Project No. 18-07-01284, fabrication of polymeric films).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2177—2182, November, 2020.

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Pogodina, Y.E., Polunin, E.V., Molchanova, S.I. et al. Synthesis and characterization of the properties of perfluorinated copolymer of perfluoro-2-ethyl-2-methyldioxole and perfluoro-n-propyl vinyl ether. Russ Chem Bull 69, 2177–2182 (2020). https://doi.org/10.1007/s11172-020-3019-9

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  • DOI: https://doi.org/10.1007/s11172-020-3019-9

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