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Synthesis of chiral spirodiazafluorenes

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Chemistry of Heterocyclic Compounds Aims and scope

Reactions of chiral nopinane-annulated diazafluorenone with substituted phenols and naphthols by the action of trifluoromethanesulfonic acid led to spiro products. The structure of the resorcinol derivative was confirmed by X-ray structural analysis.

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Acknowledgement

This work was supported by the Russian Science Foundation (grant 18-73-00148).

The authors are grateful to the Information and Computing Center of Novosibirsk State University for access to the computer cluster, and also to the Chemical Research Center for Collective Use of the Siberian Branch of the Russian Academy of Sciences for spectral and analytical measurements.

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Authors and Affiliations

  1. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 Akademika Lavrentieva Ave., Novosibirsk, 630090, Russia

    Yulia P. Ustimenko, Eugene S. Vasilyev, Sergey N. Bizyaev, Tatyana V. Rybalova & Alexey V. Tkachev

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  1. Yulia P. Ustimenko
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  2. Eugene S. Vasilyev
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  3. Sergey N. Bizyaev
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  4. Tatyana V. Rybalova
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  5. Alexey V. Tkachev
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Corresponding author

Correspondence to Eugene S. Vasilyev.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2020, 56(11), 1429–1433

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Ustimenko, Y.P., Vasilyev, E.S., Bizyaev, S.N. et al. Synthesis of chiral spirodiazafluorenes. Chem Heterocycl Comp 56, 1429–1433 (2020). https://doi.org/10.1007/s10593-020-02833-y

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  • DOI: https://doi.org/10.1007/s10593-020-02833-y

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