Abstract
The heats of dissolution of crystalline picolinic acid in water and in potassium hydroxide solutions at 298.15 K are measured via direct calorimetry. The standard enthalpies of formation of the acid and its dissociation products in an aqueous solution are calculated.
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REFERENCES
Z. Vargova, V. Zeleoak, I. Cisaova, and K. Gyoryova, Thermochim. Acta 423, 149 (2004).
J. L. York, in Textbook of Biochemistry with Clinical Correlations, Ed. by T. M. Delvin (Wiley, New York, 1992), p. 135.
K. Kiec-Kononowicz and E. Szymaska, Il Farmaco 57, 909 (2003).
W. Wang, A. Basinger, B. Shane, et al., Am. J. Physiol. Endocrinol. Metab. 280, 540 (2001).
I. Berg, B. V. L. Potter, G. W. Mayr, and A. H. Guse, J. Cell Biol. 150, 581 (2000).
M. Sulanc and I. Emre, J. Appl. Entomol. 124, 151 (2000).
B. Ahrén, Acta. Physiol. Scand. 171, 161 (2001).
P. Koczo, J. Cz. Dobrowolski, W. Lewandowski, and A. P. Mazurek, J. Mol. Struct. 655, 89 (2003).
T. Jakusch, K. Gajda-Schrantz, and T. Kiss, J. Inorg. Biochem. 100, 1521 (2006).
V. B. Spirichev, Fortification of Food with Vitamins and Minerals. Science and Technology (Sib. Univ., Novosibirsk, 2005) [in Russian].
M. Paula, M. Meier, and B. Szpoganicz, J. Coord. Chem. 46, 491 (1999).
J-C. Halle, J. Lelievre, and F. Nerrier, Can. J. Chem. 74, 613 (1996).
A. Asuero, M. Navas, A. Recamales, and M. Herrador, Microchim Acta, 395 (1986).
E. Chiacchieriuni, Ann. Chim. (Rome) 67, 547 (1977).
V. Lubes, J. Solution Chem. 34, 899 (2005).
E. Kiss, K. Petrohan, D. Sanna, and E. Garriba, Polyhedron 19, 55 (2000).
J. Loring, M. Karlsson, W. Fawcett, and W. Casey, Geochim. Cosmol. Acta 64, 4115 (2000).
R. Gelb and J. Alper, J. Chem. Eng. Data 43, 383 (1998).
M. Ignaczak and G. Andrijewski, Pol. J. Chem. 69, 716 (1995).
O. Jons and E. Johansen, Inorg. Chim. Acta 151, 129 (1988).
M. Seleim and K. Idriss, Analyst 112, 1685 (1987).
N. N. Kuranova, S. V. Dushina, and V. A. Sharnin, Russ. J. Phys. Chem. A 84, 792 (2010).
C. Davies, J. Chem. Soc., 2093 (1938).
V. P. Vasil’ev, Thermodynamic Properties of Electrolyte Solutions (Vysshaya Shkola, Moscow, 1982), pp. 200, 213 [in Russian].
A. N. Meshkov and G. A. Gamov, Talanta 198, 200 (2019).
P. P. Korostelev, Preparation of Solutions in Analytic Chemistry (Akad. Nauk SSSR, Moscow, 1962), p. 398 [in Russian].
A. I. Lytkin, V. V. Chernikov, O. N. Krutova, and D. K. Smirnova, Russ. J. Gen. Chem. 88, 954 (2018).
D. G. Archer, J. Phys. Chem. Ref. Data 28, 1 (1999).
A. I. Gubareva, I. A. Bukhtoyarova, P. A. Gerasimov, and S. N. Gadzhiev, Zh. Prikl. Khim. 63, 448 (1990).
M. D. M. C. Ribeiru da Silva, J. Chem. Thermodyn. 30, 869 (1998). https://doi.org/10.1006/jcht.1998.0353
Thermal Constants of Substances, Ed. by V. P. Glushko (VINITI, Moscow, 1965–1971), No. 3 [in Russian].
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This work was performed as part of a State Task for the Research Institute of Thermodynamics and Kinetics of Chemical Processes, Ivanovo State University of Chemical Technology, project no. FZZW-2020-0009.
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Lytkin, A.I., Chernikov, V.V., Krutova, O.N. et al. Standard Enthalpies of Formation of Picolinic Acid and the Products of Its Dissociation in an Aqueous Solution. Russ. J. Phys. Chem. 94, 2569–2573 (2020). https://doi.org/10.1134/S003602442012016X
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DOI: https://doi.org/10.1134/S003602442012016X