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Investigation of Gas-Phase Processes of Obtaining Fiber-Reinforced Organomorphic Ceramic Composites with SiC-Matrix

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Refractories and Industrial Ceramics Aims and scope

The isothermal process of chemical vapor deposition for the densification with a SiC-matrix of organomorphic carbon-fiber preforms obtained by carbonization of compressed fibers of oxidized polyacrylonitrile is investigated. Such preforms are characterized by a high (up to 70%) porosity and uniform pore size (the reduced pore diameter ranges from several micrometers to tens of micrometers). Technological parameters of the process of obtaining ceramic-matrix composites (CMC) were optimized by a combination of experimental studies and numerical simulations. Experimental samples of CMC were obtained using a non-halogen precursor, methylsilane CH3SiH3, and their residual porosity was determined. For the numerical study of the gas-phase process of densification of preforms, a 1D model was used. The simulation results were compared with experimental observations.

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References

  1. E. A. Bogachev, “Design, structure and properties of organomorphic composites as new materials,” Ceram. Int., 45, 9537 – 9543 (2019).

    Article  CAS  Google Scholar 

  2. A. P. Garshin, V. I. Kulik, S. A. Matveev, and A. S. Nilov, “Contemporary technology for preparing fiber-reinforced composite materials with a ceramic refractory matrix (review),” Refract. Ind. Ceram., 58(2), 148 – 161 (2017).

    Article  Google Scholar 

  3. Hanbook of Ceramic Composites, ed. by Bansal P. Narottam, Kluver Academic Publishers, Boston, Dordrecht, London (2005).

  4. B. Heidenreich, “C/SiC and C/C–SiC composites,” in: Ceramic Matrix Composites: Materials, Modelling and Technology, ed. by Bansal P. Narottam and J. Lamon, John Wiley & Sons, Inc.; Hoboken, NJ, USA (2014) p. 147 – 216.

    Google Scholar 

  5. A. Timofeev; E. Bogachev, and A. Lahin, “Composites with silicon carbide matrix obtained from monomethylsilane by CVI method,” Proc. 5th Int. Conf. on High-Temperature Ceramic Matrix Composites, HTCMC-5, Seattle, WA, USA (2004) p. 87 – 90.

  6. E. A. Bogachev, A. V. Lahin, and A. N. Timofeev, “MMS Technology: first results and prospects,” Ceram. Trans., 248, 243 – 253 (2014).

    Article  CAS  Google Scholar 

  7. H.-C. Chang, T. F. Morse, and B. W. Sheldon, “Minimizing infiltration times during isothermal chemical vapor infiltration with methyltrichlorsilane,” J. Am. Ceram. Soc., 80, 1805 – 1811 (1997).

    Article  CAS  Google Scholar 

  8. V. I. Kulik, A. V. Kulik, M. S. Ramm, and Yu. N. Makarov, “Modelling of SiC-matrix composite formation by thermal gradient chemical vapour infiltration,” Mater. Sci. Forum., 457 – 460, 253 – 256 (2004).

  9. V. I. Kulik, A. V. Kulik, M. S. Ramm, and Yu. N. Makarov, “Modeling of SiC-matrix composite formation by isothermal chemical vapour infiltration,” J. Crystal Growth, 266, 333 – 339 (2004).

    Article  CAS  Google Scholar 

  10. Pat. 2620810 RF, “Method of manufacturing of porous preform—basis of a composite material,” E. A. Bogachev, A. B. Elakov, A. P. Beloglazov, Yu. A. Denisov, and A. N. Timofeev; appl. 05/06/16; dated 05/29/17, Bul. No. 16.

  11. E. V. Kogan, Yu. M. Volfkovich, V. V. Kulakov, et al., “Porous structure of carbon-carbon friction composites studied by gas adsorption and standard contact porosimetry techniques,” Inorg. Mater., 48, 676 – 679 (2012).

    Article  CAS  Google Scholar 

  12. V. I. Kulik, A. V. Kulik, and M. S. Ramm, “Investigation of thermogradient processes of gas-phase saturation of 3-dimentional complex porous fibrous scaffolds with SiC-matrix,” in: Coll. Works of the 1st Russian Sci.-Techn. Symposium “Intelligent Composite Materials and Structures” [in Russian], Bauman MSTU, Moscow (2004) p. 36 – 41.

    Google Scholar 

  13. Yu. V. Lapin and M. Kh. Strelets, Internal Flows of Gaseous Mixtures [in Russian], Nauka, Moscow (1989) 368 p.

    Google Scholar 

  14. E. S. Oran and J. P. Boris, Numerical Modeling of Reacting Flows [in Russian], Mir, Moscow (1990) 660 p.

  15. S. V. Patankar, Numerical Heat Transfer and Fluid Flow (Computational Methods in Mechanics & Thermal Sciences) [Russian translation], Energoatomizdat, Moscow (1984) 152 p.

    Google Scholar 

  16. A. D. Johnson, J. Perrin, J. A. Mucha, and D. E. Ibbotson, “Kinetics of SiC CVD: Surface Decomposition of Silacyclobutane and Methylsilane,” J. Phys. Chem., 97(49), 12937 – 12948 (1993).

    Article  CAS  Google Scholar 

  17. Y. Ohshita, “Reactants in SiC chemical vapor deposition using CH3SiH3 as a source gas,” J. Cryst. Growth., 147(1/2), 111 – 116 (1995).

    Article  CAS  Google Scholar 

  18. T. Tago, M. Kawase, Y. Ikuta, and K. Hashimoto, “Numerical simulation of the thermalgradient chemical vapor infiltration process for production of fiber-reinforced ceramic composite,” Chem. Eng. Sci., 56, 2161 – 2170 (2001).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. OAO “Kompozit”, Korolev, Moscow Region, Russia

    E. A. Bogachev

  2. FGBOU VPO St. Petersburg Baltic State Technical University VOENMEH named after D. F. Ustinov (BSTU VOENMEH named after D. F. Ustinov), St. Petersburg, Russia

    V. I. Kulik & A. S. Nilov

  3. JSC “Gruppa STR”, St. Petersburg, Russia

    A. V. Kulik

Authors
  1. E. A. Bogachev
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  2. V. I. Kulik
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  3. A. V. Kulik
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  4. A. S. Nilov
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Correspondence to V. I. Kulik.

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Translated from Novye Ogneupory, No. 8, pp. 23 – 30, August 2020.

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Bogachev, E.A., Kulik, V.I., Kulik, A.V. et al. Investigation of Gas-Phase Processes of Obtaining Fiber-Reinforced Organomorphic Ceramic Composites with SiC-Matrix. Refract Ind Ceram 61, 433–440 (2020). https://doi.org/10.1007/s11148-020-00499-9

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  • DOI: https://doi.org/10.1007/s11148-020-00499-9

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