Ternary alloys of the Ti–Nb–Mo system are obtained by the method of arc remelting with subsequent crystallization on a copper water-cooled hearth. In these alloys characterized by contents of alloying elements corresponding to the molybdenum equivalent (Moeqv) within the range 3.2–4.0, we observe the formation of hexagonal (α′) and orthorhombic (α′′ ) martensites. For higher Moeqv (4.6), we detect the appearance of a phase based on β -titanium instead of the orthorhombic martensite. In all analyzed alloys, we do not reveal the acicular microstructures characteristic of martensites. In these alloys, the (β -Ti) phase has higher hardness and Young’s modulus as compared with α′ and α′′. The Ti94Nb4Mo2 and Ti92.5Nb5Mo2.5 as-cast alloys are characterized by low Young’s moduli (∼ 70 GPa).
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References
R. Thull, “Naturwissenschaftliche Aspekte von Werkstoffen in der Medizin,” Naturwissenschaften, 81, No. 11, 481–488 (1994).
J. Kudrman, J. Fousek, V. Brezina, R. Mikova, and J. Vesely, “Titanium alloys for implants in medicine,” Kovove Mater., 45, 199–208 (2007).
L. J. Xu, Y. Y. Chen, Zh. G. Liu, and F. T. Kong, “The microstructure and properties of Ti–Mo–Nb alloys for biomedical application,” J. Alloys Comp., 453, No. 1–2, 320–324 (2008).
R. Chelariu, G. Bolat, J. Izquierdo, D. Mareci, D. M. Gordin, T. Gloriant, and R. M. Souto, “Metastable beta Ti–Nb–Mo alloys with improved corrosion resistance in saline solution,” Electrochim. Acta, 137, 280–289 (2014).
M. Niinomi, “Recent titanium R&D for biomedical applications in Japan,” J. Miner. Met. Mater. Soc. (JOM-US), 51, No. 6, 32–34 (1999).
V. Cheverikin, G. Ghosh, A. Makudera, and J.-C. Tedenac, Mo–Nb–Ti Ternary Phase Diagram Evaluation, in: G. Effenberg (editor),Mater. Sci. Int., Stuttgart (2015), Document ID 10.21856.1.1 http://www.msi-eureka.com/preview-html/10.21856.1.1/Mo-Nb-Ti_Ternary_ Phase_Diagram_Evaluation/
V. N. Eremenko and L. A. Tret’yachenko, Ternary Systems of Titanium with Transition Metals of the IV–VI Groups [in Russian], Naukova Dumka, Kiev (1987).
N. N. Sobolev, V. I. Levanov, O. P. Elyutin, and V. S. Mikheev, “Construction of the melting diagram of the Ti–V–Nb–Mo system by the simplex lattice method,” Izv. Akad. Nauk SSSR, Metally, 2, 217–221 (1974).
I. T. Kornilov and R. S. Polyakova, “Diagram of state for the titanium–niobium–molybdenum ternary system,” J. Neorg. Khim., 3, No. 4, 879–888 (1958).
V. A. Kuz’menko, Sonic and Ultrasonic Oscillations in Dynamic Testing of Materials [in Russian], Izd. Akad. Nauk Ukr. SSR, Kiev (1963).
S. A. Firstov, V. F. Gorban’, and E. P. Pechkovskii, “Determination of the ultimate values of hardness, elastic strains, and the corresponding stresses in materials by the method of automatic indentation,” Materialovedenie, No. 8, 15–21 (2008).
A. A. Il’in, B. A. Kolachev, and I. S. Pol’kin, Titanium Alloys. Composition, Structure, Properties: A Handbook [in Russian], VILSMATI, Moscow (2009).
Y. Al-Zain, H. Y. Kim, T. Koyano, H. Hosoda, T. H. Nam, and S. Miyazaki, “Anomalous temperature dependence of the superelastic behavior of Ti–Nb–Mo alloys,” Acta Mater., 59, 1464–1473 (2011).
W. H. Graft and W. Rostoker, “The measurement of elastic modulus of titanium alloys,” in: Symp. on Titanium, Second Pacific Area National Meeting, ASTM, Philadelphia (1957), pp. 130–144.
W. F. Ho, C. P. Ju, and J. H Lin, “Structure and properties of cast binary Ti–Mo alloys,” Biomaterials, 20, No. 22, 2115–2122 (1999).
V. F. Gorban’ and E. P. Pechkovskii, “Relationship between the parameters of elasticity obtained by the method of instrumental indentation and the structural state of the material,” Poroshk. Metallurgiya, No. 7–8, 54–62 (2010).
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Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 56, No. 2, pp. 81–87, March–April, 2020.
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Мyslyvchenko, О.М., Bondar, A.А., Horban, V.F. et al. Structure and Physicomechanical Properties of Cast Titanium Alloys of the Ti−Nb−Mo System. Mater Sci 56, 224–231 (2020). https://doi.org/10.1007/s11003-020-00420-2
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DOI: https://doi.org/10.1007/s11003-020-00420-2